• Title/Summary/Keyword: Electrothermal Chemical

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Study on Performance Analysis of Interior Ballistics According to ETC(Electrothermal chemical) Effect (ETC 효과를 고려한 강내탄도의 성능해석 연구)

  • Sung, Hyung-Gun;Jang, Jin-Sung;Lee, Sang-Bok;Roh, Tae-Seong;Choi, Dong-Whan
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.145-148
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    • 2009
  • A study on ETC(Electrothermal chemical) Guns has been conducted. The existing code of the numerical analysis for the interior ballistics has been extended for ETC Guns. Using this code, the performance analysis of interior ballistics according to the injection patterns of the plasma energy has been fulfilled.

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A Study on Air Emission Spectra Observed by Using Electrothermal-Hollow Cathode Glow Discharge Spectrometry (Et-HCGDS) (Electrothermal-Hollow Cathode Glow Discharge Spectrometry(Et-HCGDS)를 이용하여 살펴본 Air Emission에 관한 연구)

  • Lee, Sang Chun;Shin, Jung-Sook;Kang, Mi-Ra
    • Journal of the Korean Chemical Society
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    • v.39 no.5
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    • pp.399-407
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    • 1995
  • Electrothermal-Hollow Cathode Glow Discharge Spectrometry (Et-HCGDS) has been constructed in our laboratory for in-situ monitoring of traceble amounts of rare earth elements and actinides. Et-HCGDS is the portable glow discharge system that can perform the trace analysis of elements. The main structural design of Et-HCGDS was based upon the electrothermal heating and glow discharge techniques. More details on Et-HCGDS are available elsewhere. In this study, air was used as a flow gas for the glow discharge system. As a result, the emission spectra of air were collected and the assignment of air emission lines was performed with helps of pure nitrogen and oxygen emission spectra and previously published results. We found that the emission lines of air plasma were mainly due to nitrogen molecules. This paper includes the complete assignments of the air emission lines observed by using Et-HCGDS. Also, this study will be an useful reference for spectrochemical anaysis including air analysis.

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Electric Propulsion (전기 추진)

  • Moon, Hee-Jang
    • Journal of the Korean Society of Propulsion Engineers
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    • v.12 no.3
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    • pp.76-86
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    • 2008
  • The EP(electric propulsion) is unique in that several energy sources can be utilized to produce the electric energy and that high exhaust velocity can be achieved compared to the conventional chemical propulsion. Though a lot of variety of non chemical propulsion are under study, the fact that the EP's specific impulse ranges widely from 200s to 5000s led most research to concentrate on the electric propulsion research. This paper, therefore, is aimed to introduce the up-todate existing EP family such as electrothermal, electrostatic and electromagnetic thrusters where its operating concepts, characteristics and possible variants are presented for future applications.

Polymer (Polydimethylsiloxane (pdms)) Microchip Plasma with Electrothermal Vaporization for the Determination of Metal Ions in Aqueous Solution

  • Ryu, Won-Kyung;Kim, Dong-Hoon;Lim, H.B.;Houk, R.S.
    • Bulletin of the Korean Chemical Society
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    • v.28 no.4
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    • pp.553-556
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    • 2007
  • We previously reported a 27.12 MHz inductively coupled plasma source at atmospheric pressure for atomic emission spectrometry based on polymer microchip plasma technology. For the PDMS polymer microchip plasma, molecular emission was observed, but no metallic detection was done. In this experiment, a lab-made electrothermal vaporizer (ETV) with tantalum coil was connected to the microchip plasma for aqueous sample introduction to detect metal ions. The electrode geometry of this microchip plasma was redesigned for better stability and easy monitoring of emission. The plasma was operated at an rf power of 30-70 W using argon gas at 300 mL/min. Gas kinetic temperatures between 800-3200 K were obtained by measuring OH emission band. Limits of detection of about 20 ng/mL, 96.1 ng/mL, and 1.01 μ g/mL were obtained for alkali metals, Zn, and Pb, respectively, when 10 μ L samples in 0.1% nitric acid were injected into the ETV.

Preconcentration of Ultra Trace Amounts Bismuth in Water Samples Using Cloud Point Extraction with Na-DDTC and Determination by Electrothermal Atomic Absorption Spectrometry (ET-AAS) (Na-DDTC로 흐림점 추출을 사용한 물시료에서 초미량 비스머스의 예비농축)

  • Moghimi, Ali
    • Journal of the Korean Chemical Society
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    • v.52 no.2
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    • pp.140-147
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    • 2008
  • .A new approach for a cloud point extraction-electrothermal atomic absorption spectrometric method was used for determining bismuth. The aqueous analyte was acidified with sulfuric acid (pH 3.0-3.5). Triton X-114 was added as a surfactant and natriumdiethyldithiocarbaminat (Na-DDTC) was used as a complexing agent. After phase separation at 50oC based on the cloud point separation of the mixture, the surfactant-rich phasen was diluted using tetrahydrofuran (THF). Twenty microliters (20 L) of the enriched solution and 10 l of 0.1% (w/v) Pd(NO3)2 as chemical modifier were dispersed into the graphite tube and the analyte determined by electrothermal atomic absorption spectrometry. After optimizing extraction conditions and instrumental parameters, a preconcentration factor of 195 was obtained for a sample of only 10 mL. The detection limit was 0.04 ng ml-1 and the analytical curve was linear for the concentration range of 0.04-0.70 ng mL-1. Relative standard deviations were <5%. The method was successfully applied for the extraction and determination of bismuth in water samples.

The Fundamental Studies and Development of Modified Electrothermal Vaporization Hollow Cathode Glow Discharge Cell (개선된 전열증기화 속빈음극관 글로우 방전셀의 기초연구 및 개발)

  • Lee, Seong-Hun;Cho, Won-Bo;Jeong, Jong-Pil;Choi, Woo-Chang;Kim, Kyu-Whan;Woo, Jeong-Su;Lee, Chang-Su;Kang, Dong-Hyun;Lee, Sang-Chun
    • Analytical Science and Technology
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    • v.15 no.6
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    • pp.514-520
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    • 2002
  • The electrothermal vaporization (ETV) hollow cathode glow discharge atomic emission spectrometer for analysis of liquid sample has been developed and characterized. This system has improved the sample introduction method of electrothermal vaporization and the hollow cathode glow discharge. The sample introduction method was possible to provide high analyte transport efficiency to the plasma by helix coil made of tungsten material. In addition, small volume samples (<$30{\mu}{\ell}$) could be used. The system has glow discharge cell with special design for improvement of precision. The effect of discharge parameters such as discharge power, gas flow rate has been studied to find optimum condition. The emitted light was effectively carried into detector by fiber optic cable in UV region. The calibration curve of Pb, Cd were obtained with 3 samples.

Design and Operation Characteristics of 2.4MJ Pulse Power System for Electrothermal-Chemical (ETC) Propulsion (II) (전열화학추진용 2.4MJ 펄스파워전원의 설계와 동작특성(II))

  • Jin, Y.S.;Lee, H.S.;Kim, J.S.;Whang, D.W.;Kim, J.S.;Chu, J.H.;Jung, J.W.;Moon, H.J.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1603-1605
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    • 2001
  • Eight 300kJ modularized capacitor-banks have been constructed. These modules have been installed and assembled to make a 2.4MJ pulse power system (PPS). This 2.4MJ PPS was developed to be used as a driver of an electrothermal-chemical (ETC) gun. Each capacitor bank has six 22kV, 50kJ capacitors connected in parallel. A triggered vacuum switch (TVS-43) was adopted as a main pulse power-closing switch in each module. The module also contains a crowbar circuit made of three high-voltage diode-stacks, a multi-tap inductor and an energy-dumping resistor. Various current shapes have been formed by a sequential firing of multiple capacitor banks. Resistive dummy load has been used and various combinations of experimental parameters, such as charging voltage, trigger time and inductance, were tested to make flexible current shapes.

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150 kJ Compact Capacitive Pulsed Power System for an Electrothermal Chemical Gun

  • Lee, Byung-Ha;Kim, Jin-Sung;Kim, Seong-Ho;Lee, Young-Hyun;Yang, Kyung-Seung
    • Journal of Electrical Engineering and Technology
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    • v.7 no.6
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    • pp.971-976
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    • 2012
  • A 150 kJ compact capacitive pulsed power system (CCPPS) capable of delivering electrical energy into an electrothermal chemical (ETC) gun on a vehicle has been studied. The CCPPS provides pulsed electrical energy into a capillary plasma injector which generates plasma of tens of thousands $^{\circ}K$ in temperature and has a nonlinear resistance depending on the current. The design requirements of the CCPPS are as follows: the maximum power of 250 MW, the pulse width of about 0.6 ms, the volume of no more than 0.5 cubic meter, the efficiency of energy transfer over 80 % and the repetition rate of 4~5 times per minute. The constructed CCPPS is composed of four 37.5 kJ capacitor bank modules in parallel to make a trapezoid pulse shape and to satisfy the design requirements. Each module is designed to achieve high reliability, safety, efficiency and energy density to endure severe operating conditions. The results of the performance test on the CCPPS using a 120 mm ETC gun are described.