• Journal of Conservation Science
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• v.28 no.4
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• pp.367-376
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• 2012

The ironware production technology is a measure to fathom the society's level of development in time. To understand iron-manufacure methods in the past, various investigations on the fine structures and additions of ironware remains and Iron ingot have been conducted in a way of natural science. This study metallurgically reclassifies remains excavated in iron-manufacture remains located in Beokje, Goyang, which are thought to be in time of Goryeo Dynasty, and draws an inference from the element analysis on the iron-manufacture and smelting technology. Iron ingot samples with a cast iron structure are divided into those with a white cast iron structure and those with a grey cast iron rich in P. The P content of grey cast iron appeared to be the result of adding a flux agent like lime, iron ingot and carbon steel iron ingot with a cast iron structure excavated in the area is regarded as pig iron which was made without a refining process. In this study it seems that two methods of making ironware were used in the area; one is the method of making ironware by pouring cast iron to the casting, and the other is the method of making carbon steel through the refinement of pig iron. It appears that highly even steel structure of carbon steel and a small amount of MnS inclusion are very similar with that of the modern steel to which Mn is artificially added. Nevertheless, these data alone cannot be used to determine the source of Mn in the carbon steel of the excavated from the iron-manufacture remains, which raises the need for further studies on the source and the possibility of carbon steel via the iron-manufacture process of cast iron.

• Journal of Conservation Science
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• v.26 no.4
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• pp.407-416
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• 2010

Bacteria with ability for iron reduction in the soil can use corrosion products of iron remains as energy source. The activities of this bacteria cause the change of corrosion products. As a result, it can be difficult to identify corrosion products promoting corrosion of iron remains. The purpose of this study, is to investigate the change in corrosion products that bacteria causes and to improve understanding about the corrosion of iron remains. To simulate corroded condition of excavated iron remains, carbon steel corroded by solution of NaCl and $Na_2SO_4$ was prepared. Then the prepared carbon steel was immersed in a liquid medium with bacteria. The incubation period was 42days. After experiment, the carbon steel was analyzed by SEM-EDS, X-ray diffraction method. The result is that the carbon was changed to green because of activity of bacteria and that the plate crystal and lozenge crystal were generated on the corrosion specimen. Also, we confirmed that the activities of bacteria differenciated colors and forms of corrosion products.

• Journal of Conservation Science
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• v.38 no.3
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• pp.217-233
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• 2022

The remains found in Geumcheok-ri, Gyeongju are located in close proximity to the Ancient Tombs in Geumcheok-ri, Gyeongju (Historic Site) which were built between the late 5th and early 6th centuries, and these tombs are known to belong to the powerful rulers of that area. Using metallurgical techniques, this study was conducted on the iron objects obtained from the excavated remains in Geumcheok-ri, Gyeongju which are presumed to have a close relation to the nearby ruins that played an important role in the growth of Silla. To identify differences in manufacturing techniques based on the purpose of the iron objects, eight objects were selected after classifying them by use and the microstructure and non-metallic inclusions were investigated. The analyses results confirmed that the manufacturing process involved forging iron with a high or low carbon content to produce a particular shape, and that the carburization process was applied to iron post forging a shape to increase its strength when necessary. The mechanical properties were improved by selectively applying the steelmaking method and the heat treatment technique considering the functions of the parts, and the low temperature reduction was applied to the smelting process. Furthermore, in comparison with the iron objects excavated from the remains located in the center of Gyeongju and its outskirts, it is confirmed that there is similarity in the smelting and manufacturing techniques between these objects.

• Korean Journal of Metals and Materials
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• v.50 no.8
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• pp.599-603
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• 2012

The microstructure of a hammer scale excavated from the Bogam-ri was examined in an effort to understand the iron technologies applied in the manufacturing of an iron forging process technology. The microstructures of oxide layer in the hammer scale were found to have crucial information about the ancient iron forging process treatment. The microstructure observed in the hammer scale can be distinguished by the forging process. First, the microstructure of the oxide layer in the hammer scale created by the forging process is Wstite (FeO) in the form of leaves. Latterly, the microstructure of the $W{\ddot{u}}stite$(FeO) in the hammer scale is observed to be in the form of a flat shape formed by a repeating forging process.

• Korean Journal of Heritage: History & Science
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• v.35
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• pp.138-158
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• 2002

To compare and analyze technical system related to manufacturing of ironware during the period of the Three Kingdoms, an analysis was conducted on the minute system of metalwork, as study objects, of the remains of the Mt. Wolpyeong fortress wall in Daejeon in the period of capital during the era of the Three Kingdoms in the 5th century, the Sanwol-ri remains in the 6th century in Gunsan and the remains of ironware excavated from the great ancient tomb of Hwangnam of the Silla dynasty in the 5th century. The result of analysis shows that in the most of the casting products, the minute system of white cast iron were contained. While the iron part of decarbonization was in the system by casting as white cast iron in the central part, on the surface layer it was turned out that comparatively uniform 100% pearlite system of about 1~2mm degree was existing. The part of pearlite on the surface layer was caused by decarbonization, which appears in all the parts of blade front end and handle. Therefore, it was found that the iron part of decarbonization was manufactured by casting, and then was processed at the high temperature by decarbonization. For the products of forging, after processing the products on the basis of pure iron for materials, they manufactured the ironware that raises the strength by carbonizing that keeps carbon infiltrated on the necessary part, by the method of black smith welding that add pure iron to steel, or by varying the method of heat processing onto the part required of strength. Though limited, we could understand that the technical systems for manufacturing skill of ironware in the areas of Baekje and Silla were different each other. In the technical system for Hwangnam great ancient tomb in the Silla area, it is found that they had raised the strength on the necessary part by applying the steelmaking method of carbonizing in the last stage of production of products, in the meantime in Baekje area, it appears that they had produced steel in advance in the first stage of production of the products, and used the produced steel only to the necessary part.

• 보존과학연구
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• s.30
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• pp.203-215
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• 2009

In the conservation treatment of wood remains, polymers, treatment methods, and treatment period can be varied, depending on the percentage of moisture content and species of trees. Thus, in order to apply the appropriate conservation treatment, a lot of information from the wood remains are required. Despite the information from the wood remains, testing a part of the wood remains is necessary to get information about the polymers. When the wooden coffin made of camphor trees was excavated, it was cracked in the section of radiation, and there were hairlines cracks. Therefore, without any conservation treatment, it is impossible to restore it. This experiment is for the conservation treatment of the wooden coffin excavated from Songhyun-dong tombs No 7, Changnyeong. For this experiment, I used camphor trees from Jejudo. The purpose of this experiment is to asses the possibility of preliminary testing materials before the conservation treatment on the wooden coffin. After the camphor trees from Jejudo are artificially aged by Fenton's reagent, they are As a result of oxidation by Fenton, the degree of oxidation is high in proportion to the amount of peroxide and iron sulfate. Among several samples, the sample 'na' made the most similar result to the wooden coffin from Songhyun-dong. If I use this condition to make the sample in polymer tests, it is very helpful to find the most suitable polymer for the conservation treatment of wooden coffin. After the same species of trees are oxidized by Fenton and they become the similar condition, we are able to find suitable methods of conservation treatment. The suitable methods reduce the demage of the remains and make us to get more information. Thus, we are able to carry out conservation treatment more exactly.

• Journal of Conservation Science
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• v.2 no.2 s.2
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• pp.3-14
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• 1993

This study was carried out to identify the species of wooden coffins excavated from ancient kings' tombs of Nakrang and Pro-Three-Kingdoms to the beginning period of the Three Kingdoms, and the private tombs of the middle stage at the Yi dynasty. The species of wooden coffins were identified as three softwoods(Thxus cuspidata, Sciodopitys verticillata, Pinus densiflora) and six hardswoods(Quercus acutissima, Quercus serrata, Zelkova serrata, Platycarya strobilarea, Alnus japonica and Morns spp.). Thxus cuspidata, wooden coffins of Nakrang kings' tombs, is distributed through Korea. However in previous examination it was known as Cunninghania lanceolata, native species in south China. Sciodopitys verticillata used as a wooden coffin of King Muryung's tomb was native to Japan. It was a material evidence proving the cultural exchange between Paekche Kingdoms and Japan in those days. Pinus densiflora was the species of wooden coffins excavated from private tombs in Yi dynasty, which was not found out from Pro-Three-Kingdoms and Three-Kingdoms. Quercus accutissima was used for making a trough shape wooden coffins at Daho-ri ancient tombs and Quercus serrata was used a outer wooden coffin of Nakrang kings' tombs. An adamant iron mongery might be used to manufacturing a trough shape wooden coffin. This indicates that a developed iron-manufacturing technics existed in Korea at that time. Zelkova serrata was used for making wooden coffins of Imdang and Kaya ancient tombs, Chunma and Hwangnam king tombs. Platycarya strobizacea was used for making wooden coffin of Daegok-ri, Alnus japonica for Daho-ri coffins and Morus spp. for Imdang coffins.

• Journal of Conservation Science
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• v.35 no.1
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• pp.91-98
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• 2019

The fragments of a wall painting excavated from among the historical remains of Jeseoksa Temple in Iksan. The extent of the damage to the fragments was examined and an analysis of the components of the pigment was conducted. The results of the component analysis of the pigment confirmed that the white pigment consisted of alkali feldspar and mullite. Although the results of the visual inspection revealed differences in color in the red and black pigments, the main component of the two colors was confirmed to be iron oxide. Red and black pigments are found at the same position. Although differences of color is obvious, those are identified as hematite and magnetite of oxidized steel's affiliation. It is judged that Differences of ingredients happened by external environment's factors.

• Korean Journal of Heritage: History & Science
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• v.50 no.1
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• pp.4-17
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• 2017

In this research, the chemical composition of the iron artifacts from the late 6th-century to early 7thcentury Baekje remains in Gwanbuk-ri, Buyeo, specifically of the nine iron artifacts including slags, furnace walls and ingot iron excavated in the District "Na", were examined by observing their chemical compounds and microstructures. As a result, GB1 and GB6 were determined to be proto-reduction lumps whereas GB2, GB3, GB4 and GB5 were determined to be tempered slags, respectively. Also, he furnace wall GB7 were containing mullite and cristobalite, which are high temperature index minerals, The extrusion temperature was found out to be about $1200{\sim}1300^{\circ}C$, and it is most likely that the smelting temperature in the furnace was in that temperature range. GB8 ingot iron was determined to be a forged ironware. This ingot iron was an intermediary product for making ironware and its nonmetallic inclusions displayed similar microstructure and contents compared to the forged iron. Because of the existence of proto-reduction lumps and forged iron, the iron making facility located in District "Na" most likely had a small-scale iron making facility that handled iron bloom smelting and refining processes.

• Journal of Conservation Science
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• v.35 no.4
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• pp.373-383
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• 2019

We characterized the smelting process and smelting furnace through scanning electron microscopy-energy dispersive spectroscopy, wavelength dispersive X-ray fluorescence, X-ray diffraction, and raman micro-spectroscopy with 13 relics including slags and furnace walls excavated from square-shaped building sites and pits of the Three Kingdoms site at the Ungyo site section I. Our results revealed that the principal components were FeO and SiO₂; and CuO, PbO, and ZnO were contained in small quantities. Furthermore, fayalite, magnetite, augite, copper, and cuprite were found. High contents of FeO or SiO₂ components seem to have been added to form fayalite to remove gangue in the smelting process. The relatively low content of S detected in the copper prills suggests that roasting was performed well. Cristobalite and mullite, which are minerals that indicate high-temperature found in the furnace wall, show that the smelting temperature was higher than 1,250℃. The findings of this study show a high possibility that the Wanju Ungyo site is smelting remains of copper ores, which are nonferrous metals, rather than iron. Various smelting byproducts excavated in this area in the future will help us better understand the copper smelting process that may have been performed since ancient times.