• Journal of the Korean Chemical Society
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• v.22 no.2
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• pp.67-77
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• 1978

MO's of a complex are expanded in terms of the set of Shull-Lowdin functions based on a single point, the nucleus of central metal ion, and the result was interpreted from the viewpoint of perturbation theory. We find that even in the case of $[NiF_6]^{4-}$, which has relatively small covalency, excited configurations with high orbital angular momentum are considerably mixed into $e_g$ and $t_{2g}$, orbitals of central metal ion, and that the distortions in these orbitals differ from each other. Therefore it is concluded that the energy difference between $e^*_g$ and $t^*_{2g}$, orbitals evaluated in the MO scheme has little meaning of the unique parameter 10Dq in the crystal field theory, and that such a unique parameter cannot be defined in a rigorous sense in the MO scheme.

• Applied Chemistry for Engineering
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• v.20 no.5
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• pp.465-472
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• 2009

The technologies for improving the capacity of hydrogen storage were investigated and the recent data of hydrogen storage by using various porous carbon materials were summarized. As the media of hydrogen storage, activated carbon, carbon nanotube, expanded graphite and activated carbon fiber were mainly investigated. The hydrogen storage in the carbon materials increased with controlled pore size about 0.6~0.7 nm. In case of catalyst, transition metal and their metal oxide were mainly applied on the surface of carbon materials by doping. Activated carbon is relatively cheap because of its production on a large scale. Carbon nanotube has a space inside and outside of tube for hydrogen storage. In case of graphite, the distance between layers can be extended by intercalation of alkali metals providing the space for hydrogen adsorption. Activated carbon fiber has the high specific surface area and micro pore volume which are useful for hydrogen storage. Above consideration of research, porous carbon materials still can be one of the promising materials for reaching the DOE target of hydrogen storage.

• Journal of the Korean Institute of Telematics and Electronics
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• v.25 no.9
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• pp.1115-1124
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• 1988

A two-dimensional systolic array for fast Fourier transform, which has a regular and recursive VLSI architecture is presented. The array is constructed with identical processing elements (PE) in mesh type, and due to its modularity, it can be expanded to an arbitrary size. A processing element consists of two data routing units, a butterfly arithmetic unit and a simple control unit. The array computes FFT through three procedures` I/O pipelining, data shuffling and butterfly arithmetic. By utilizing parallelism, pipelining and local communication geometry during data movement, the two-dimensional systolic array eliminates global and irregular commutation problems, which have been a limiting factor in VLSI implementation of FFT processor. The systolic array executes a half butterfly arithmetic based on a distributed arithmetic that can carry out multiplication with only adders. Also, the systolic array provides 100% PE activity, i.e., none of the PEs are idle at any time. A chip for half butterfly arithmetic, which consists of two BLC adders and registers, has been fabricated using a 3-um single metal P-well CMOS technology. With the half butterfly arithmetic execution time of about 500 ns which has been obtained b critical path delay simulation, totla FFT execution time for 1024 points is estimated about 16.6 us at clock frequency of 20MHz. A one-PE chip expnsible to anly size of array is being fabricated using a 2-um, double metal, P-well CMOS process. The chip was layouted using standard cell library and macrocell of BLC adder with the aid of auto-routing software. It consists of around 6000 transistors and 68 I/O pads on 3.4x2.8mm\ulcornerarea. A built-i self-testing circuit, BILBO (Built-In Logic Block Observation), was employed at the expense of 3% hardware overhead.

• Nuclear Engineering and Technology
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• v.41 no.4
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• pp.427-446
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• 2009

In order to meet the increasing demand for electricity, Korea has to rely on nuclear energy due to its poor natural resources. In order for nuclear energy to be expanded in its utilization, issues with uranium supply and waste management issues have to be addressed. Fast reactor system is one of the most promising options for electricity generation with its efficient utilization of uranium resources and reduction of radioactive waste, thus contributing to sustainable development. The Korea Atomic Energy Research Institute (KAERI) has been performing R&Ds on Sodium-cooled Fast Reactors (SFRs) under the national nuclear R&D program. Based on the experiences gained from the development of KALIMER conceptual designs of a pool-type U-TRU-10%Zr metal fuel loaded reactor, KAERI is currently developing Advanced SFR design concepts that can better meet the Generation IV technology goals. This also includes developing, Advanced SFR technologies necessary for its commercialization and basic key technologies, aiming at the conceptual design of an Advanced SFR by 2011. KAERI is making R&D efforts to develop advanced design concepts including a passive decay heat removal system and a supercritical $CO_2$ Brayton cycle energy conversion system, as well as developing design methodologies, computational tools, and sodium technology. The long-term Advanced SFR development plan will be carried out toward the construction of an Advanced SFR demonstration plant by 2028.

• Journal of computational fluids engineering
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• v.19 no.4
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• pp.68-74
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• 2014

This computational study features the transient compressible and inviscid flow analysis on a metallic plasma discharge from the opposing composite electrodes which is subjected to pulsed electric power. The computations have been performed using the flux corrected transport algorithm on the axisymmetric two-dimensional domain of electrode gap and outer space along with the calculation of plasma compositions and thermophysical properties such as plasma electrical conductivity. The mass ablation from aluminum electrode surfaces are modeled with radiative flux from plasma column experiencing intense Joule heating. The computational results shows the highly ionized and highly under-expanded supersonic plasma discharge with strong shock structure of Mach disk and blast wave propagation, which is very similar to muzzle blast or axial plasma jet flows. Also, the geometrical effects of composite electrodes are investigated to compare the amount of mass ablation and penetration depth of plasma discharge.

• Journal of the Korean Society for Precision Engineering
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• v.26 no.8
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• pp.96-103
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• 2009

The roll forming process is commonly used for the conventional 'Fe' metal products such as a furniture drawer guide or an up-down slide guide. Recently its applications are variously expanded to the sanitary facilities or electronic devices. It is essentially required the cleanness for the high technology application and any corrosion or rust are not allowed. Therefore, in those applications the stainless steel materials are strongly demanded as the substitution of 'Fe' steel. However the mechanical properties of stainless steel are not suitable for forming process compared with those of 'Fe' steel. Up to now, the conventional F.E.M.(Finite Element Method) has been used to analyze and design the roll forming process. The purpose of this research is to obtain the proper production process and the shape of rolls to manufacture the high precision slide rails made of stainless steel material. The commercial program, SHARPE-RF, is used to analyze the entire roll forming process. The results show that the rolling process and the roll design by F.E.M. are useful from the good agreement between the shapes of products estimated by F.E.M. and those of the actual products.

• Journal of the Korean Society for Nondestructive Testing
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• v.35 no.3
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• pp.215-220
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• 2015

As a nondestructive inspection technology currently in use, infrared thermography has gradually expanded its application range to industry. The method detects only defect areas by grafting ultrasound on a technique of detecting infrared energy emitted from all objects with absolute temperature of 0 K and converting this energy into thermography for inspection. Ultrasound infrared thermography has merits including the ability to inspect a wide area in a short time without contacting the target object. This study investigated the applicability of the technique for defect detection using variable ultrasound excitation inspection methods on samples of Terfenol-D, a magnetostrictive material with a tunable natural resonant frequency.

• Journal of Sensor Science and Technology
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• v.26 no.3
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• pp.155-159
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• 2017

The analog-to-digital converter (ADC) is an important component in various fields of sensor signal processing. This paper presents an expandable flash analog-to-digital converter (E-flash ADC) for sensor signal processing using a comparator, a subtractor, and a multiplexer (MUX). The E-flash ADC was simulated and designed in $0.35-{\mu}m$ standard complementary metal-oxide semiconductor (CMOS) technology. For operating the E-flash ADC, input voltage is supplied to the inputs of the comparator and subtractor. When the input voltage is lower than the reference voltage, it is outputted through the MUX in its original form. When it is higher than the reference voltage, the reference voltage is subtracted from the input value and the resulting voltage is outputted through the MUX. Operation of the MUX is determined by the output of the comparator. Further, the output of the comparator is a digital code. The E-flash ADC can be expanded easily.

• Korean Journal of Materials Research
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• v.13 no.7
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• pp.442-446
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• 2003

Tin dioxide ($SnO _2$) thin films were deposited at $375^{\circ}C$ on alumina substrate by metal-organic chemical vapor deposition. A few hillocks like a cauliflower were observed and the number of hillock on thin film surface increased with annealing temperature in air atmosphere. The oxygen content and the binding energy during air annealing at$ 500^{\circ}C$ came to close the stoichiometric $SnO_2$. The cauliflower hillocks seem to be the result of the continuous migration of the tiny grains to release the stress of an expanded grain. Sensitivity of CO gas depended on annealing temperature and increased with increasing annealing temperature.

• Nuclear Engineering and Technology
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• v.41 no.8
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• pp.1005-1014
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• 2009

The Dual Unit Optimizer 2000 MWe (DUO2000) is put forward as a new design concept for large power nuclear plants to cope with economic and safety challenges facing the $21^{st}$ century green and sustainable energy industry. DUO2000 is home to two nuclear steam supply systems (NSSSs) of the Optimized Power Reactor 1000 MWe (OPR1000)-like pressurized water reactor (PWR) in single containment so as to double the capacity of the plant. The idea behind DUO may as well be extended to combining any number of NSSSs of PWRs or pressurized heavy water reactors (PHWRs), or even boiling water reactors (BWRs). Once proven in water reactors, the technology may even be expanded to gas cooled, liquid metal cooled, and molten salt cooled reactors. With its in-vessel retention external reactor vessel cooling (IVR-ERVC) as severe accident management strategy, DUO can not only put the single most querulous PWR safety issue to an end, but also pave the way to very promising large power capacity while dispensing with the huge redesigning cost for Generation III+ nuclear systems. Five prototypes are presented for the DUO2000, and their respective advantages and drawbacks are considered. The strengths include, but are not necessarily limited to, reducing the cost of construction by decreasing the number of containment buildings from two to one, minimizing the cost of NSSS and control systems by sharing between the dual units, and lessening the maintenance cost by uniting the NSSS, just to name the few. The latent threats are discussed as well.