• Title/Summary/Keyword: FUNCTIONAL GROUPS

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Molecularly Imprinted Polymers Having Amidine and Imidazole Functional Groups As an Enzyme-Mimetic Catalyst for Ester Hydrolysis

  • Chen, Wen;Han, Dong-Keun;Ahn, Kwang-Duk
    • Macromolecular Research
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    • v.10 no.2
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    • pp.122-126
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    • 2002
  • A molecularly imprinted polymer (MIP) having both amidine and imidazole functional groups in the active site has been prepared using p-nitrophenyl phosphate as a transition state analogue (TSA). The imprinted polymer MIP with amidine and imidazole found to have the highest hydrolysis activity compared with other MIPs with either amidine or imidazole groups only. It is postulated a cooperative effect between amidine and imidazole in the hydrolysis of p-nitrophenyl methyl carbonate (NPMC) as a substrate when both groups were arranged in proximity by molecular imprinting. The rate enhancement of the hydrolysis by MIP was 60 folds over the uncatalyzed solution reaction and two folds compared with the control non-imprinted polymer CPI having both functional groups. The enzyme-mimetic catalytic hydrolysis of p-nitrophenyl acetate by MIP was evaluated in buffer at pH 7.0 with $K_{m}$ of 1.06 mM and $k_{cat}$ of 0.137 $h^{-1}$ . . .

Influence of Oxygen-/Nitrogen-containing Functional Groups on the Performance of Electrical Double-Layer Capacitor (전기이중층 커패시터의 성능에 미치는 산소/질소 함유 관능기들의 영향)

  • Kim, Jieun;Kwon, Young-Kab;Lee, Joong Kee;Choi, Ho-Suk
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.1043-1048
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    • 2012
  • In this study, activated carbons (ACs) were modified as electrode materials for an electric double layer capacitor (EDLC) by controlling oxygen- and nitrogen-containing functional groups. The morphological and chemical properties of ACs were analyzed through scanning electron microscopy (SEM), fourier transform infrared (FTIR) spectrometer, automatic elemental analyzer (EA) and Boehm titration. Also, charge/discharge tests were performed to investigate the EDLC performance. Oxygen- and nitrogen-containing functional groups were introduced on the surface of ACs through acid and urea treatments, respectively. ACs with nitrogen-containing functional groups showed 2 mA increase of gravimetric discharge capacity and quick achievement of maximum charge/discharge performance. However, ACs with oxygen-containing functional groups showed low discharge capacity and its gradual decrease during further cyclic test, since the functional groups interrupted adsorption/desorption of charges in the electrolyte on the surface of ACs.

A study on Recognition and Preference of Healthy and Functional Textile according to Psychological Comfort of the Silver Generation (실버세대의 심리적 안정감에 따른 건강 기능성 섬유 인지 및 선호에 관한 연구)

  • Seo, Min Nyoung;Koo, Young Seok
    • Fashion & Textile Research Journal
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    • v.16 no.5
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    • pp.811-821
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    • 2014
  • The purposes of this study were to investigate difference on recognition, preference, satisfaction and possession of functional textile clothing in psychological comfort groups according to gender and age of the elderly and suggest optimal physical, mental and healthy functional textiles for the elderly. The data was collected from 262 respondents in their age of over 55, who lived in Busan. SPSS 21.0 was used and t-test, cross tabulation analysis, frequency analysis, and descriptive analysis were performed for analysis. The results are as follows. First, high groups of psychological comfort for both gender and age of the elderly showed higher recognition and preference of functional textiles, especially in the high groups of the new silver generation and women. Second, the high groups of psychological comfort for both gender and age of the elderly showed higher satisfaction of functional textiles. However, it was lower than preference of functional textiles. Last, the possession of major clothing function over all the elderly was comfort, fitting motion adaptability, and health safety function in order. Low groups of psychological comfort possessed fitting motion adaptability textile clothing more than the high groups, and the high groups of psychological comfort possessed comfort and health safety textile clothing more than low groups. In conclusion, this research showed the importance of functional textiles for the elderly in terms of psychological comfort as well as the need for healthy comfort textiles for the advanced activities of daily life.

Combined effect of nitrogen- and oxygen functional groups on electrochemical performance of surface treated multi-walled carbon nanotubes (표면처리된 탄소나노튜브의 질소 및 산소관능기 도입에 따른 전기화학적 특성)

  • Kim, Ji-Il;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.214.1-214.1
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    • 2011
  • In this work, the electrochemical properties of the surface treated multi-walled carbon nanotubes (MWNTs) are investigated for supercapacitors. Nitrogen- and oxygen functional groups containing MWNTs are prepared by nitrogen precursors and acidic treatment, respectively. The surface properties of the MWNTs are confirmed by X-ray photoelectron spectroscopy (XPS) and Zeta-potential measurements. The electrochemical properties of the MWNTs are investigated by cyclic voltammetry, impedance spectra, and charge-discharge cycling performance in 1 M $H_2SO_4$ at room temperature. As a result, these functionalized MWNTs lead to an increase in the specific capacitance as compared with the pristine MWNTs. It proposes that the pyridinic and pyridinic-N-oxides nitrogen species influence on the specific capacitance due to their positive charges, and thus an improved electron transfer at high current loads, since they are the most important functional groups affecting capacitive behaviors.

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The Effect of Functional Independence in Long Term Care Elderly People on the Mental and Health factor (정신 및 건강요인이 장기요양 노인의 기능적 독립성에 미치는 영향)

  • Shin, Hong-Cheul;Kang, Jeong-Il;Lee, Kyoung-Hwa
    • Journal of Korean Physical Therapy Science
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    • v.15 no.1
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    • pp.47-56
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    • 2008
  • The purpose of this study was to seek for a performance level of functional independence of the long term care elderly people. This study questionnaires 160 elders with 80 in a large city and 80 in small-to-medium sized city in order to find out the functional independence of elderly people. The results of this study were as follows. 1. Functional independence level following health factor; The comparison of degrees of functional independence level between two groups showed significant difference in sanitation, drinking and smoking, eating habit, chronic disease, physical activities, and regular physical examination(P<.05). But the comparison between two groups was not showed significant difference in present treatment, regular exercise. 2. Functional independence level following Psychological factor; The comparison of degrees of functional independence level between two groups showed significant difference in health evaluation(P<.05). But the comparison between two groups was not showed significant difference in quality of life. In conclusion it is needed that stable housing, much physical activities, and diversified family members should be realized and stable livelihood security recipients to maintain and improve health of the aged and to be socially satisfied.

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The Effect on Forming Functional Concept by Teaching Function Based on Variable (변수에 의한 함수 지도가 함수개념의 형성에 미치는 효과)

  • 이덕호;길영순
    • Journal of the Korean School Mathematics Society
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    • v.4 no.1
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    • pp.103-114
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    • 2001
  • The purpose of this study is to develop learning materials for functional concept on variable and to verify the effect of how well students could learn functional concept after they studied with those materials. To accomplish the purpose of this study, I developed learning materials and after teaching students with them. I have concluded the followings : First, there was little effect in teaching functional concept on variable between two experimental groups, whereas teaching functional concept had greater effect on forming functional concept in high level groups in those two experimental groups. Second, teaching functional concept on variable had little effect on students' understanding of functional concept and perfecting tables in Black box, graph, and mathematical problems, whereas there was much effect in students' understanding functional concept and solving relation formula, image, and range problems related to everyday life or general things. On the basis of the problems which appeared in the process of this study, the following can be suggested : First, we should develop learning materials fit for low level students so that they could understand functional concept. Second, we should continue to teach the basic problems like solving relation formula, image, and range, and understanding functional concept in graph until students are able to understand them exactly. Third, since the goals of Unit Function in a middle school textbook is to solve problems related to everyday life through functional thinking, there should be change in constructing systematic contents of Unit Function in a middle school textbook.

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A VARIANT OF THE QUADRATIC FUNCTIONAL EQUATION ON GROUPS AND AN APPLICATION

  • Elfen, Heather Hunt;Riedel, Thomas;Sahoo, Prasanna K.
    • Bulletin of the Korean Mathematical Society
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    • v.54 no.6
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    • pp.2165-2182
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    • 2017
  • Let G be a group and $\mathbb{C}$ the field of complex numbers. Suppose ${\sigma}:G{\rightarrow}G$ is an endomorphism satisfying ${{\sigma}}({{\sigma}}(x))=x$ for all x in G. In this paper, we first determine the central solution, f : G or $G{\times}G{\rightarrow}\mathbb{C}$, of the functional equation $f(xy)+f({\sigma}(y)x)=2f(x)+2f(y)$ for all $x,y{\in}G$, which is a variant of the quadratic functional equation. Using the central solution of this functional equation, we determine the general solution of the functional equation f(pr, qs) + f(sp, rq) = 2f(p, q) + 2f(r, s) for all $p,q,r,s{\in}G$, which is a variant of the equation f(pr, qs) + f(ps, qr) = 2f(p, q) + 2f(r, s) studied by Chung, Kannappan, Ng and Sahoo in [3] (see also [16]). Finally, we determine the solutions of this equation on the free groups generated by one element, the cyclic groups of order m, the symmetric groups of order m, and the dihedral groups of order 2m for $m{\geq}2$.

Effect of Herb Medicine Treatment for Functional Dyspepsia: A Randomized Placebo-Controlled and Compared Standard Treatment Trial (기능성 소화불량증 환자에 대한 한약복합제의 치료 효과: 무작위배정 표준치료제 위약 대조군 연구)

  • Kim, Yeon-Mi;Park, Yang-Chun;Jo, Jeong-Hyo;Kang, Wee-Chang;Son, Mi-Won;Hong, Kwon-Eui
    • The Journal of Korean Medicine
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    • v.31 no.1
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    • pp.1-13
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    • 2010
  • Objective: Functional dyspepsia is a prevalent disease. It impedes subjective quality of life. The purpose of this study was to examine the equivalent effect of herb medicine treatment (DA-9701) for functional dyspepsia. Methods: In this randomized, single-blinded, placebo-controlled study, we compared a herb medicine (DA-9701) with standard treatment (mosapride) and placebo for the treatment of functional dyspepsia. 42 volunteers who satisfied the requirements were enrolled in study. Severity of dyspepsia was measured by Nepean Dyspepsia Index (NDI) and Functional Dyspepsia Quality of Life (FD-QOL) before and after treatments. Results: 1. In the DA-9701 group, total key symptoms score was significantly lower and improve rate of key symptoms was higher than in the mosapride and placebo groups, but there were no statistically significant differences between three groups. 2. In the DA-9701 and mosapride groups, "nausea" and "bad breath" were significantly lower compared with the placebo group. 3. In the DA-9701 group, NDI Quality of Life scores were significantly higher, but there were no [other] statistically significant differences between the three groups. 4. In the DA-9701 and mosapride groups, FD-QOL scores were higher compared with the placebo group, but there were no statistically significant differences between the three groups. Conclusion: Herb medicine treatment (DA-9701) is effective to improve the symptoms and quality of life in patients with functional dyspepsia.

Effects of Mobilization with Movement Combined with Exercise(EMWM) on ADH, ROM and Functional Performance in Patients with Impingement Syndrome of the Shoulder (운동과 MWM을 혼합한 중재(EMWM)가 어깨관절 충돌증후군 환자의 AHD, ROM, 기능수행정도에 미치는 효과)

  • Choo, Yeonki
    • Journal of The Korean Society of Integrative Medicine
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    • v.7 no.2
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    • pp.153-163
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    • 2019
  • Purpose : This study was to identify the effects of Mobilization with Movement combined with exercise (EMWM) on acromio-humeral distance (AHD), range of motion (ROM), pain intensity, and functional performance in patients with impingement syndrome of the shoulder. Methods : The subjects were 40 patients diagnosed with impingement syndrome of the shoulder. Twenty subjects are randomly assigned to each 2 different groups; Group 1. (exercise group), Group 2. (EMWM group). Three weekly interventions were given for 4 weeks. The main outcome measures were ultrasound, goniometer, visual analogue scale (VAS), and Korean Constant shoulder score (K-CSS). The ultrasound (AHD), ROM (flexion, abduction), pain intensity (for shoulder flexion) and functional performance (K-CSS) were compared between the groups. Results : The AHD was significantly increased in Group 2 compared to Groups 1. No significant difference was observed between the groups in the range of abduction of the shoulder, but the range of flexion was significantly increased in Group 2 compared to Groups 1. Pain intensity was significantly lower in Group 2 than in Group 1, and functional performance was significantly increased in Group 2 compared to Group 1. Conclusion : An intervention that combined mobilization with movement with exercise was more effective than exercise alone for rapid recovery from shoulder injury and improvement in functional performance.

EFFECT OF CARBON FIBER SURFACE PROPERTIES ON FIBER-MATRIX ADHESION OF THE COMPOSITES

  • Kim Mun-Han;Park Su-Jin;Lee Jae-Rak;Choe Seon-Ung
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.40-43
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    • 1999
  • Electrochemical surface treatment of PAN-based carbon fibers in acidic electrolyte has been studied in increasing the surface functional groups on fiber surfaces for the improvement of fiber-matrix adhesion of the resulting composites. According to the FT-IR and XPS measurements, it reveals that the oxygen functional groups on fibers are largely influence on the composite mechanical behaviors, whereas the nitrogen functional groups are not affected in the system. In this work, a good correlation between surface functionality and mechanical properties is established.

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