• Title/Summary/Keyword: Filler

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A Study on the Manufacturing and Physical Properties of Conducting Rubber (II) -Barium ferrite System Conducting Rubber- (전도성(導電性)고무의 제조(製造) 및 물성(物性)에 관한(關)한 연구(硏究) (II) -Barium Ferrite 혼합계(混合系) 도전성(導電性)고무-)

  • Lee, Young-Man;Yun, Ju-Ho;Choi, Sei-Young
    • Elastomers and Composites
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    • v.30 no.3
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    • pp.218-228
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    • 1995
  • To make filler loaded conducting rubber which has excellent electronical and physical properties, CR and NBR were mixed with barium ferrite(BaO.6Fe2O3). From the result of this study, vulcanization characteristics shows that curve is upgraded as the filler concentration increases and CR has higher torque than NBR. In physical properties, elongation being higher, modulus comes to decrease. Tear strength gradually decrease after showing the maximum point when is in the 100phr in CR. Resilience is not good to cause the increase in filler concentration. In electrical properties, conductivity becomes low when filler concentration increase. The increase of voltage makes a conductivity grown, but the rate change is weak. The influence of temperature hardly changes on increasing temperature. The morphology and the dispersion of a conductivity filler in vulcanizates through SEM were good. The more filler concentration increases, the shorter the particle interval is.

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Effects of Inorganic Fillers on Mechanical Properties of Silicone Rubber

  • Kim, Gyu Tae;Lee, Young Seok;Ha, KiRyong
    • Elastomers and Composites
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    • v.54 no.2
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    • pp.142-148
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    • 2019
  • In this study, the effects of filler particle size and shape on the physical properties of silicone rubber composites were investigated using inorganic fillers (Minusil 5, Celite 219, and Nyad 400) except silica, which was already present as a reinforcing filler of silicone rubber. Fillers with small particle sizes are known to facilitate the formation of the bound rubber by increasing the contact area with the polymer. However, in this experiment, the bound rubber content of Celite 219-added silicone composite was higher than that of Minusil 5-added silicone composite. This was attributed to the porous structure of Celite 219, which led to an increase in the internal surface area of the filler. When the inorganic fillers were added, both thermal decomposition temperature and thermal stability were improved. The bound rubber formed between the silicone rubber and inorganic filler affected the degree of crosslinking of the silicone composite. It is well-known that as the size of the reinforcing filler decreases, the reinforcing effect increases. However, in this experiment, the hardness of the composite material filled with Celite 219 was the highest compared to the other three composites. Furthermore, the highest value of 2.19 MPa was observed for 100% modulus, and the fracture elongation was the lowest at 469%. This was a result of excellent interaction between Celite 219 filler and silicone rubber.

EFFECT OF SPHERICAL SILICA FILLER ON THE PHYSICAL PROPERTIES OF EXPERIMENTAL COMPOSITES (구상형 실리카 필러가 실험적 복합레진의 물성에 미치는 효과)

  • Kang, Seung-Hoon;Park, Sang-Jin;Min, Byung-Soon;Choi, Ho-Young;Choi, Gi-Woon
    • Restorative Dentistry and Endodontics
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    • v.24 no.1
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    • pp.88-99
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    • 1999
  • The purpose of this study was to investigate the physical properties of experimental composite resins made with the spherical and crushed fillers. The 14 experimental composite resins containing 0, 5, 10, 15, 20 and 25%(w/w) in spherical filler group and 0, 10, 20, 30, 40, 50, 60 and 70%(w/w) in crushed filler group, incorporated in a Bis-GMA matrix (Aldrich Co., USA), were made with 1% ${\gamma}$-methoxy silane treated fillers. The polymer matrix was made by dissolving 0.7%(w/w) of benzoyl peroxide(Janssen Chemical Co. Japan) in methacrylate monomer, whereupon 0.7%(v/v) N,N-dimethyl-p-toluidine(Tokyo Kasei Co. Japan) was added to the monomer. The weight percentage of each specific particle size distribution could be determined from a knowledge of the specific gravity, the weight(w/w), and corresponding volume %(v/v) of the filler sample in resin monomer. In crushed silica group and spherical silica group, the diametral tensile strengths and compressive strengths were measured with Instron Testing Machine(No.4467), and analyzed in 14 experimental composite resins made by filler fractions. The shear bond strength of 14 experimental composite resins to bovine enamel was measured with universal testing machine(Instron No.4467). The fracture surfaces were sputter-coated with a gold film and investigated by SEM. The results were as follows; 1. The diametral tensile strength was tendency to increase in crushed silica group, but not in spherical silica group. The highest diametral tensile strength was found in 20% filler fractions of two groups. 2. The compressive strength was higher in 15%(w/w) and 20%(w/w) in spherical silica group than in crushed silica group, but not in spherical silica group. 3. The significant correlation was noticed in increase in shear bond strength in crushed silica group, but not in spherical silica group. 4. The significantly highest shear bond strength was noticed in 50% filler concentration in crushed silica group, and in 15% filler concentration in spherical silica group, it was not significant in relation. 5. In crushed silica group, cut surface of resin matrix and the interface between resin and filler is obvious. In spherical silica group, fractures that occurred through the filler particles were round in shape.

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Effect of Inorganic fillers in Newsprint Papermaking (신문용지 제조에 있어서 무기 충전제들의 영향)

  • Chai, Kyu-Yoon;Lee, Joon-Koo;Kim, Sung-Kwon
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.961-967
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    • 1998
  • In order to improve the optical properties and printability of paper, various fillers are used in papermaking. This study was performed to investigate several fillers-precipitated calcium carbonate(PCC), ground calcium carbonate(GCC), and blends(PCC/talc or micro-talc(MVP) and GCC/talc or micro-talc(MVP)-for their effects on various newsprint properties. Results obtained from the study were summarized as follows ; 1) PCC treatment gave about 16.8% higher retention than GCC treatment at the filler level of 5% and the retention of filler in the handsheet increased as average particle size of mixed filler was increasing($PCC{\leq}GCC<MVP<talc$). 2) PCC treatment kept opacity more highly than no filler treatment and opacity decreased as average particle size of mixed filler was increasing. 3) Independent treatment of PCC kept tear strength more effectively than GeC did, and tear strength increased as average particle size of mixed filler was increasing. 4) Independent treatment of pee kept tensile strength more highly than other treatments and Gee treatment kept tensile strength highly than pee treatment under mixed filler treatment. 5) Burst strength under PCC treatments decreased linearly as average particle size of mixed filler was increasing. 6) Compared "With non-filler treatment, filler treatment gave much better printability.

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Processing of syntactic dependency in Korean relative clauses: Evidence from an eye-tracking study (안구이동추적을 통해 살펴본 관계절의 통사처리 과정)

  • Lee, Mi-Seon;Yong, Nam-Seok
    • Korean Journal of Cognitive Science
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    • v.20 no.4
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    • pp.507-533
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    • 2009
  • This paper examines the time course and processing patterns of filler-gap dependencies in Korean relative clauses, using an eyetracking method. Participants listened to a short story while viewing four pictures of entities mentioned in the story. Each story is followed by an auditorily presented question involving a relative clause (subject relative or dative relative). Participants' eye movements in response to the question were recorded. Results showed that the proportion of looks to the picture corresponding to a filler noun significantly increased at the relative verb affixed with a relativizer, and was largest at the filler where the fixation duration on the filler picture significantly increased. These results suggest that online resolution of the filler-gap dependency only starts at the relative verb marked with a relativiser and is finally completed at the filler position. Accordingly, they partly support the filler-driven parsing strategy for Korean, as for head-initial languages. In addition, the different patterns of eye movements between subject relatives and dative relatives indicate the role of case markers in parsing Korean sentences.

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The Destruction of Bacterial Spores Upon Compressional Pressure (타정 압력에 의한 세균포자의 파괴현상)

  • Lee, Cherl-Ho;Kim, Young-Man;Lee, Jung-Chi;Jung, Pil-Keun
    • Korean Journal of Food Science and Technology
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    • v.12 no.4
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    • pp.272-277
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    • 1980
  • The tolerance of useful bacterial spores to the conditions of tablet making, specifically, the destruction of bacterial spores upon compressional pressure was investigated. The damage of bacterial spores occurred mainly during the tabletting. The bacterial spores obeyed a logarithmic destruction rate upon compressional pressure. The spore destruction rate was dependent upon the strains of microorganism. The Decimal Reduction Pressure, designated as P-value, were $2.9\;ton/cm^2$, $2.6\;ton/cm^2$ and $2.1\;ton/cm^2$ for the spores of Bacillus subtilis, Bacilus coagulans and Clostridium butyricum, respectively, and $1.7\;ton/cm^2$ for the vegetative cell of Streptococcus faecalis. The spore destruction upon compressional pressure was influenced by the type of filler. The P-value of the spore of B. coagulans was $2.8\;ton/cm^2$ in the lactose filler, but $2.0\;ton/cm^2$ in the starch filler. The number of viable spores was inversely proportional to the hardness and density of tablet, in case that the same type of filler was used. The starch filler, which resulted in the lower hardness and lower density of tablet, caused higher spore destruction rate compared with the lactose filler.

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Development of Filler Type Mechanical Splice for High Strength Re-bar (고강도 철근용 충전형 기계적 이음장치 개발 연구)

  • Lee, Seongsoo;Chun, Homin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.12
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    • pp.686-693
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    • 2018
  • Various types of re-bar splicing methods have been developed and applied to reinforced concrete (RC) structures in the field. According to previous studies, the coupler splice is relatively superior to the lap splice in terms of cost efficiency when the diameter or strength of the re-bar is larger or higher. This study was performed to develop a filler type mechanical splice for a high-strength re-bar (SD600) in reinforced concrete structures. The deformed re-bars were inserted into a circular steel tube coupler and high-strength epoxy filler was then injected into the coupler. The splice system was completed by hardened filler in a coupler. The epoxy filler was used as the manufactured production epoxy to conduct experiments of filler type mechanical splice specimens, and to observe the failure loads and failure aspects of the specimens. For this goal, the experiment of one-way tensile test was conducted for the epoxy filler type mechanical splices specimens according to the compressive strength of epoxy, length of coupler, and diameter of re-bar. The shape of failure of the re-bar coupler splice showed that the re-bars were pulled between the lugs of the re-bars as a result of the shear fracture of the hardened epoxy. The actual failure load of the experiment specimen was approximately 2 times higher than the expected failure load of the epoxy filler, which greatly improves the failure load of the hardening epoxy filler due to the restraint of the steel coupler.

Effect of New Organic Filler Made From Oil Palm Biomass on Paperboard Properties (오일팜 부산물을 이용한 유기충전제 제조 가능성 평가)

  • Lee, Ji Young;Kim, Chul Hwan;Sung, Yong Joo;Park, Jong-Hea;Kim, Eun Hea
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.61-67
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    • 2015
  • As the production of palm oil has been increased, the generation of oil palm biomass is also increased and the utilization of the oil palm biomass become more significant topic. One third of the oil palm biomass is empty fruit bunch (EFB) and the other two thirds are oil palm trunks and fronds. However, the effective use of oil palm biomass has not been developed and most of it is discarded near oil palm plants. In this study, we investigated the applicability of EFB to the paperboard mills, as an organic filler. The new organic filler was manufactured in a laboratory by grinding and fractionating dried EFB powder, and its properties were analyzed. The particles of EFB organic filler were larger and more spherical than those of the commercial wood powder. The use of EFB organic filler resulted in a higher bulk of the handsheets with similar trends of physical strength, compared to those made with wood powder. It was concluded that EFB could be used as a raw material to manufacture organic filler for paperboard production.

Effect of Mixing Shear on Flocculation of Anionic PAM and Cationic Starch Adsorbed PCC and Its Effect on Paper Properties (교반 속도가 음이온성 PAM과 양이온성 전분으로 도포된 경질탄산칼슘의 응집과 종이 물성에 미치는 영향)

  • Choi, Do-Chim;Won, Jong Myoung;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.2
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    • pp.53-60
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    • 2015
  • The effects of stirring speed during filler modification by dual polymers on flocculation and reflocculation of PCC (precipitated calcium carbonate) particles and its effect on handsheet properties were elucidated. PCC surface was modified by adsorbing A-PAM (anionic polyacrylamide) and C-starch (cationic starch) in series at various stirring speeds. It was found that increasing stirring speed during filler modification decreased the initial floc size of PCC. Continuous stirring with the same speed for filler modification resulted in the decrease of a floc size, eventually reached a steady state. The variations in a floc size was influenced by the stirring speed during filler modification: the lower the stirring speed during filler modification, the larger the floc size variations. Conclusively, the stability of PCC floc could be improved by increasing the stirring speed. In addition, the stirring speed influenced the handsheet properties. The smaller the PCC floc, the lower the strength of handseet. However, too much larger floc size also deteriorated paper strength. There exists an optimum floc size in term of paper strength which shall be controlled by stirring speed during filler modification.

Effect of Heating Rates on Microstructures in Brazing Joints of STS304 Compact Heat Exchanger using MBF 20 (MBF 20으로 브레이징한 STS304 콤팩트 열교환기 접합부의 미세조직에 미치는 가열속도의 영향)

  • Kim, Jun-Tae;Heo, Hoe-jun;Kim, Hyeon-Jun;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.34 no.2
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    • pp.46-53
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    • 2016
  • Effect of heating rate on microstructure of brazed joints with STS 304 Printed Circuit Heat Exchanger (PCHE),which was manufactured as large-scale($1170(L){\times}520(W)){\times}100(T)$, mm), have been studied to compare bonding phenomenon. The specimens using MBF 20 was bonded at $1080^{\circ}C$ for 1hr with $0.38^{\circ}C/min$ and $20^{\circ}C/min$ heating rate, respectively. In case of a heating rate of $20^{\circ}C/min$, overflow of filler metal was observed at the edge of a brazed joints showing the height of filler metal was decreased from $100{\mu}m$ to $68{\mu}m$. At the center of the joints, CrB and high Ni contents of ${\gamma}$-Ni was existed. For the joints brazed at a heating rate of $0.38^{\circ}C/min$, the height of filler was decreased from $100{\mu}m$ to $86{\mu}m$ showing the overflow of filler was not appeared. At the center of the joints, only ${\gamma}$-Ni was detected gradating the Ni contents from center. This phenomenon was driven from a diffusion amount of Boron in filler metal. With a fast heating rate $20^{\circ}C/min$, diffusion amount of B was so small that liquid state of filler metal and base metal were reacted. But, for a slow heating rate $0.38^{\circ}C/min$, solid state of filler metal due to low diffusion amount of B reacted with base metal as a solid diffusion bonding.