• Title/Summary/Keyword: Filler

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Effects of Strain-Induced Crystallization on Mechanical Properties of Elastomeric Composites Containing Carbon Nanotubes and Carbon Black (탄소나노튜브 및 카본블랙 강화 고무복합재료의 변형에 의한 결정화가 기계적 특성에 미치는 영향)

  • Sung, Jong-Hwan;Ryu, Sang-Ryeoul;Lee, Dong-Joo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.9
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    • pp.999-1005
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    • 2011
  • The effects of strain-induced crystallization (SIC) on the mechanical properties of elastomeric composites as functions of extension ratio (${\lambda}$), multiwalled carbon nanotube (CNT) content, and carbon black (CB) content are investigated. The differential scanning calorimetry (DSC) analysis shows that the degree of crystallinity increases with the increase in the CB and CNT content. As ${\lambda}$ increases, the glass transition temperature (Tg) of the composites increases, and the latent heat of crystallization (LHc) of the composites is maximum at ${\lambda}$=1.5. It is found that the mechanical properties have a linear relation with LHc, depending on the CNT content. According to the TGA (thermogravimetric analysis), the weight loss of the composite matrix is 94.3% and the weight of the composites decreases with the filler content. The ratio of tensile modulus ($E_{comp}/E_{matrix}$) is higher than that of tensile strength (${\sigma}_{comp}/{\sigma}_{matrix}$) because of the CNT orientation inside the elastomeric composites.

Development of Feature-based Encapsulation Process using Filler Material (충진재를 이용한 특징형상 가공용 RFPE 공정 개발)

  • Choe, Du-Seon;Lee, Su-Hong;Sin, Bo-Seong;Yun, Gyeong-Gu;Hwang, Gyeong-Hyeon;Lee, Ho-Yeong
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.1
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    • pp.98-103
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    • 2001
  • Machining is the commonly used process in the manufacturing of prototypes. This process offers several advantages, such as rigidity of the machine, precision of the machine, precision of the operation and specially a quick delivery. The weight and immobility of the machine support and immobilize the part during the operation. However, despite these advantages it shows, machining still presents several limitations. The immobilization, location and support of the part are referred to as fixturing or workholding and present the biggest challenge for time efficient machining. So it is important to select and design the appropriate fixturing assembly. This assembly depends on the complexity of the part and the tool paths and may require the construction of dedicated fixtures. With traditional techniques, the range of fixturable shapes is limited and the identification of suitable fixtures in a given setup involves complex reasoning. To solve this limitation and to apply the automation, this paper presents the Reference Free Part Encapsulation(RFPE) and implementation of the encapsulation system. The feature-based modeling system and the encapsulation system are implemented. The small part of which it is difficult to find out the appropriate fixturing assembly is made by this system.

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The effect of resin thickness on polymerization characteristics of silorane-based composite resin

  • Son, Sung-Ae;Roh, Hyoung-Mee;Hur, Bock;Kwon, Yong-Hoon;Park, Jeong-Kil
    • Restorative Dentistry and Endodontics
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    • v.39 no.4
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    • pp.310-318
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    • 2014
  • Objectives: This study examined the influence of the resin thickness on the polymerization of silorane- and methacrylate-based composites. Materials and Methods: One silorane-based (Filtek P90, 3M ESPE) and two methacrylate-based (Filtek Z250 and Z350, 3M ESPE) composite resins were used. The number of photons were detected using a photodiode detector at the different thicknesses (thickness, 1, 2 and 3 mm) specimens. The microhardness of the top and bottom surfaces was measured (n = 15) using a Vickers hardness with 200 gf load and 15 sec dwell time conditions. The degree of conversion (DC) of the specimens was determined using Fourier transform infrared spectroscopy (FTIR). Scratched powder of each top and bottom surface of the specimen dissolved in ethanol for transmission FTIR spectroscopy. The refractive index was measured using a Abbe-type refractometer. To measure the polymerization shrinkage, a linometer was used. The results were analyzed using two-way ANOVA and Tukey's test at p < 0.05 level. Results: The silorane-based resin composite showed the lowest filler content and light attenuation among the specimens. P90 showed the highest values in the DC and the lowest microhardness at all depth. In the polymerization shrinkage, P90 showed a significantly lower shrinkage than the rest two resin products (p < 0.05). P90 showed a significantly lower refractive index than the remaining two resin products (p < 0.05). Conclusions: DC, microhardness, polymerization rate and refractive index linearly decreased as specimen thickness linearly increased. P90 showed much less polymerization shrinkage compared to other specimens. P90, even though achieved the highest DC, showed the lowest microhardness and refractive index.

An Experimental Study on Developing Ultra-High Strength Powder Concrete Using Low-heat Portland Cement (저열 포틀랜드 시멘트를 사용한 초고강도 분체 콘크리트 개발에 관한 실험적 연구)

  • Jo, Byung-Wan;Yoon, Kwang-Won;Kim, Heoun;Park, Jin-Mo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.6 s.58
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    • pp.135-147
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    • 2009
  • In order to develop the ultra high strength concrete over 400Mpa at 28 day, Low-heat portland cement, ferro-silicon, silica-fume and steel fiber were mixed and tested under the special autoclave curing conditions. Considering the influence of Ultra high strength concrete. normal concrete is used as a comparison with low water-cement ratio possible Low-heat portland cement. Additionally, as a substitution of aggregates, we analyzed the compressive strength of Ferro Silicon by making the states of mixed and curing conditions differently. In addition, SEM films testified the development of C-S-H hydrates of Type III & Type IV, and tobermolite, zonolite due to the high temperature, high pressure of autoclave curing. Fineness of aggregate, filler and reactive materials in concrete caused 420Mpa compressive strength at 28day successfully.

Reduction of Tractive Force by Revetment Mattress/Filter (호안 Mattress/Filter에 의한 소류력 저감)

  • Seo Young-Min;Lee Seung-Yun;Heo Chang-Hwan;Jee Hong-Kee
    • Journal of Environmental Science International
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    • v.15 no.1
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    • pp.33-43
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    • 2006
  • Revetment Mattress/Filter is the porous structure filled fillers in meshed structure so that it cail use the fillers of various sizes and form various pores. The porous structure of the Mattress/Filter increases drainage so that it decreases the energy and erosion of flow therefore the tractive force is decreased and the erosion of revetment is mitigated. The filler of Mattress/Filter uses gravels, waste concretes and slags so that the surface is rough and the roughness coefficient increases and the increase of the roughness coefficient decreases flow velocity and tractive force. On the other hand Mattress/Filter and vegetation are combined so that the increase of roughness coefficient and flow velocity still more progress therefore the effect of decrease of tractive force is increased after a few months have passed since the Mattress/Filter is constructed so that the vegetation is developed and be stabilized. The vegetation channel of Mattress/Filter is set tip and the inspection comes into operation by varing flowrate and vegetation spacing to examine these characters of the Mattress/Filter The coefficient of flow velocity U/U*' is decreased exponentially as vegetation esity aH' or $\lambda$ is increased and the coefficient of friction f is increased as vegetation desity aH' is increased but decreased as the coefficient of flow velocity U/U*' is increased. The effective tractive force $F_0$ is decreased exponentially as the vegetation desity aH' is increased. From the inspection the results are obtained that the porous and vegetation structure of the revetment Mattress/Filter system increases the coefficient of friction of revetment so that flow velocity and effective are decreased therefore greatly contributes the stability of the revetment.

Micro Joining Process Using Solderable Anisotropic Conductive Adhesive (Solderable 이방성 도전성 접착제를 이용한 마이크로 접합 프로세스)

  • Yim, Byung-Seung;Jeon, Sung-Ho;Song, Yong;Kim, Yeon-Hee;Kim, Joo-Heon;Kim, Jong-Min
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.73-73
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    • 2009
  • In this sutdy, a new class ACA(Anisotropic Conductive Adhesive) with low-melting-point alloy(LMPA) and self-organized interconnection method were developed. This developed self-organized interconnection method are achieved by the flow, melting, coalescence and wetting characteristics of the LMPA fillers in ACA. In order to observe self-interconnection characteristic, the QFP($14{\times}14{\times}2.7mm$ size and 1mm lead pitch) was used. Thermal characteristic of the ACA and temperature-dependant viscosity characteristics of the polymer were observed by differential scanning calorimetry(DSC) and torsional parallel rheometer, respectively. A electrical and mechanical characteristics of QFP bonding were measured using multimeter and pull tester, respectively. Wetting and coalescence characteristics of LMPA filler particles and morphology of conduction path were observed by microfocus X-ray inspection systems and cross-sectional optical microscope. As a result, the developed self-organized interconnection method has a good electrical characteristic($2.41m{\Omega}$) and bonding strength(17.19N) by metallurgical interconnection of molten solder particles in ACA.

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Evaluations of Microstructure and Electrochemical Anodic Polarization of AISI 304L and AISI 316L Stainless Steel Weld Metals with Creq/Nieq Ratio (Creq/Nieq비에 따른 AISI 304L 및 AISI 316L 스테인리스강 용접부의 미세조직 및 전기화학적 양극분극 평가)

  • Kim, Yeon Hee;Jang, Ah Young;Kang, Dong Hoon;Ko, Dae Eun;Shin, Yong Taek;Lee, Hae Woo
    • Korean Journal of Metals and Materials
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    • v.48 no.12
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    • pp.1090-1096
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    • 2010
  • This pitting corrosion study of welded joints of austenitic stainless steels (AISI 304L and 316L) has addressed the differentiating solidification mode using three newly introduced filler wires with a flux-cored arc welding process (FCAW). The delta ferrite (${\delta}$-ferrite) content in the welded metals increased with an increasing equivalent weight ratio of chromium/nickel ($Cr_{eq}/Ni_{eq}$). Ductility dip cracking (DDC) was observed in the welded metal containing ferrite with none of AISI 304L and 0.1% of AISI 316L. The potentiodynamic anodic polarization results revealed that the $Cr_{eq}/Ni_{eq}$ ratio in a 3.5% NaCl solution didn't much affect the pitting potential ($E_{pit}$). The AISI 316L welded metals with ${\ddot{a}}$-ferrite content of over 10% had a superior $E_{pit}$ value. Though the AISI 316L welded metal with 0.1% ferrite had larger molybdenum contents than AISI 304L specimens, it showed a similar $E_{pit}$ value because the concentration of chloride ions and the corrosion product induced severe damage near the DDC.

Effects of Sintering Additives on the Thermal and Mechanical Properties of AlN by Pressureless Sintering (상압소결 질화알루미늄의 소결 첨가제 변화에 따른 열적 및 기계적 특성)

  • Hwang, Jin Uk;Mun, So Youn;Nam, Sang Yong;Dow, Hwan Soo
    • Journal of Powder Materials
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    • v.26 no.5
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    • pp.395-404
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    • 2019
  • Aluminum nitride (AlN) has excellent electrical insulation property, high thermal conductivity, and a low thermal expansion coefficient; therefore, it is widely used as a heat sink, heat-conductive filler, and heat dissipation substrate. However, it is well known that the AlN-based materials have disadvantages such as low sinterability and poor mechanical properties. In this study, the effects of addition of various amounts (1-6 wt.%) of sintering additives $Y_2O_3$ and $Sm_2O_3$ on the thermal and mechanical properties of AlN samples pressureless sintered at $1850^{\circ}C$ in an $N_2$ atmosphere for a holding time of 2 h are examined. All AlN samples exhibit relative densities of more than 97%. It showed that the higher thermal conductivity as the $Y_2O_3$ content increased than the $Sm_2O_3$ additive, whereas all AlN samples exhibited higher mechanical properties as $Sm_2O_3$ content increased. The formation of secondary phases by reaction of $Y_2O_3$, $Sm_2O_3$ with oxygen from AlN lattice influenced the thermal and mechanical properties of AlN samples due to the reaction of the oxygen contents in AlN lattice.

Filler-Elastomer Interactions. 11. Influence of Atmospheric Pressure Plasma on Surface Properties of Nanoscaled Silicas (충전재-탄성체 상호작용. 11. 상압플라즈마 처리가 나노구조의 실리카 표면특성에 미치는 영향)

  • Park, Soo-Jin;Jin, Sung-Yeol;Kaang, Shin-Young
    • Elastomers and Composites
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    • v.40 no.1
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    • pp.22-28
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    • 2005
  • In this work, the effect of oxygen plasma treatment of nano-scaled silica on the mechanical interfacial properties and thermal stabilities of the silica/rubber composites was investigated. The surface properties of the silica were studied in X-ray photoelectron spectroscopy (XPS) and contact angles. And, their mechanical interfacial properties and thermal stabilities of the composites were characterized by tearing energy ($G_{IIIC}$) and thermogravimetric analysis (TGA), respectively. As a result, it was found that the introduction rate of oxygen-containing polar functional groups onto the silica surfaces was increased by increasing the plasma treatment time, resulting in improving the tearing energy. Also, the thermal stabilities of the composites were increased by increasing the treatment time. These results could be explained that the polar rubber, such as acrylonitrile butadiene rubber (NBR), showed relatively a high degree of interaction with oxygen-containing functional groups of the silica surfaces in a compounding system.

Improvement of Properties of Silica-Filled SBR Compounds Using NBR: Influence of Separate Load of SBR and NBR (NBR를 이용한 실리카로 보강된 SBR 배합물의 특성 향상 : SBR과 NBR의 분리 첨가 배합의 영향)

  • Choi, Sung-Seen;Kim, Beom-Tae
    • Elastomers and Composites
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    • v.40 no.1
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    • pp.29-36
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    • 2005
  • Mixing condition and procedure affect properties or a filled rubber compound such as filler dispersion, viscosity, and bound rubber formation. Influence of separate load of styrene-butadiene rubber (SBR) and acrylonitrile-butadiene rubber (NBR) on properties or silica-filled SBR compounds containing NBR was studied. Cure time and cure rate became faster as NBR content increased. The crosslink density increased with increase in the NBR content. The bound rubber content also increased as the NBR content increased. NBR content of the bound rubber was higher than that of the compounded rubber. The bound rubber content was higher when SBR and NBR were loaded separately than when loading simultaneously. The cure time and cure rate were slower for the separate load than for the simultaneous one. The crosslink density was also lower for the former case than for the latter one.