• Journal of Korean Society of Water and Wastewater
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• v.24 no.5
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• pp.485-493
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• 2010

Chemical coagulation destabilizes colloidal particles so that particles grow to larger flocs. Solid particles are then removed by solid-liquid separation after typical precipitation. Rapid precipitation enhances the separation by reducing the precipitation time with larger and denser particles. Conventionally, polyelectolyte compounds (polymers) function as a flocculant aid by introducing a interparticle binding, which increases the particle size and density. And more recent ballasted flocculation adds a ballasting agent (microsand) to form denser particles with its high-density(sp gr=2.65). The current research was to evaluate the manner in which ballasted flocs are formed under different injection timings of microsand and to recognize the effects on floc formation. $FeCl_3$ as a coagulant, anionic polymer for a flocculation aid and microsand were used for the floc formation. Floc size (diameter) was widely ranged with the highest mean value when microsand was injected between $FeCl_3$ and polymer. Mean floc density was larger when the floc formed smaller. Settling velocity increased with larger floc size, whilst not significantly affected by the timing of microsand injection. The additional slow mixing on floc formation increased floc size to some extent.

• Journal of the Korean Society of Hazard Mitigation
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• v.9 no.4
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• pp.107-113
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• 2009

This paper considers the influence of floc on the sedimentation rate for the cohesive material. The effects of floc density and size changes were also taking into consideration during the experiment. The settling velocity of a discrete floc was measured in a quiescent water column. Floc diameter and density were investigated using a modified Stokes equation with some constants such as water density, viscosity, material density and the floc fractal dimension $n_f$ obtained from the relationship between the floc diameter and the floc settling. The floc diameter of quartz and alumina increased at increasing initial concentrations. The floc size of quartz with increasing NaCl concentration varied between approximately 0.8 um to $10{\mu}m$. Floc density decreased as floc size increased. The floc settling velocity and the floc diameter have a straight line relationship on a logarithm. The floc fractal dimension nf was 2.65 with increasing of initial concentration and 2.93 with increasing of NaCl. The exponent n to predict the settling velocity was proposed and varied from 1 to 1.93.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.3
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• pp.9-17
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• 2001

The floc characteristics of base paper stock for coating by the retention aid system consisting of polyacrylamide (high molecular weight low charge density, HMLC) and PEI without and with anionic inorganic oxide (IO) were investigated under various shear conditions of MDDA (modified dynamic drainage analyzer). The floc size was increased with cationic electrolytes dosage whatever inorganic oxide is applied or not. The effect of inorganic oxide on the floc size showed the different result between PAM and PEI. The smaller floc was obtained by PAM without inorganic oxide, but larger floc was obtained by PAM with inorganic oxide. However, the effect of shear force was not observed. Floc formation index was decreased by the addition of cationic electrolytes with or without inorganic oxide. Floc formation index had better correlation format formation index than floc size. The relationships between wet web permeability and mat air permeability showed the significant linear correlation ($R^2$=0.97~0.98) for HML PAM and PEI. Floc formation index gave more useful information than the retention measurement when the performance of retention aids is evaluated at the laboratory before applying at the paper mill.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.47 no.2
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• pp.53-60
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• 2015

The effects of stirring speed during filler modification by dual polymers on flocculation and reflocculation of PCC (precipitated calcium carbonate) particles and its effect on handsheet properties were elucidated. PCC surface was modified by adsorbing A-PAM (anionic polyacrylamide) and C-starch (cationic starch) in series at various stirring speeds. It was found that increasing stirring speed during filler modification decreased the initial floc size of PCC. Continuous stirring with the same speed for filler modification resulted in the decrease of a floc size, eventually reached a steady state. The variations in a floc size was influenced by the stirring speed during filler modification: the lower the stirring speed during filler modification, the larger the floc size variations. Conclusively, the stability of PCC floc could be improved by increasing the stirring speed. In addition, the stirring speed influenced the handsheet properties. The smaller the PCC floc, the lower the strength of handseet. However, too much larger floc size also deteriorated paper strength. There exists an optimum floc size in term of paper strength which shall be controlled by stirring speed during filler modification.

• Journal of Korean Society on Water Environment
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• v.36 no.3
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• pp.185-193
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• 2020

Bimodal flocculation describes the aggregation and breakage processes of the flocculi (or primary particles) and the flocs in the water environment. Bimodal flocculation causes bimodal size distribution with the two separate peaks of the flocculi and the flocs. Extracellular polymeric substances and ionic species common in the water environment increase the occurrence of bimodal flocculation and flocculi-floc size distribution, under the flocculation mechanisms of electrostatic attraction and polymeric bridging. This study investigated bimodal flocculation and flocculi-floc size distribution, with respect to the extracellular polymeric substance concentration and ionic strength in the kaolinite-containing suspension. The batch flocculation tests comprising 0.12 g/L of kaolinite showed that the highest flocculation potential occurred at the lowest xanthan gum (as extracellular polymeric substances) concentration, under all the ionic strengths of 0.001, 0.01, and 0.1 M NaCl. Also, it was important to note that the higher ionic strength resulted in the higher flocculation potential, at all the xanthan gum concentrations. The bimodal flocculation and flocculi-floc size distribution became apparent in the experimental conditions, which had low and intermediate flocculation potential. Besides the polymeric bridging flocculation, steric stabilization increased the flocculi mass fraction against the floc mass fraction, thereby developing the bimodal size distribution.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.7
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• pp.1263-1271
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• 2000

This study investigated the floc structure and removal of turbidity and organic matter by alum coagulation. Results of this study indicated that sweep floc and charge neutralization area were shifted to more acidic region than that in the Amirtharajah's diagram. This was caused by organic matter present in the raw water. Removal regions of turbidity and organic matter were generally overlapped. However, organic matters was removed better at lower pH than turbidity. Floc structure was characterized by measuring fractal dimension and volume diameter using AIA and SALLS. SALLS method was found to be more reliable than AIA method. Floes in sweep floc region had larger size and fractal dimension than flocs in charge neutralization region. As pollutant removal increased, larger fractal dimension and size of floc were measured.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.12
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• pp.7438-7442
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• 2014

An assessment of flocculation was performed by measuring the distribution of the floc size during sedimentation in water works. The size and number of flocs have a greater effect on an evaluation of the efficiency of flocculation rather than the turbidity. The data was collected in situ using particle image velocimetry and image analysis. The measurements were carried out at a water depth of 1m. The removal efficiency of the total organic compounds, UV absorbance and turbidity depended on the size and floc size distribution in flocculation as the G value. The G value of 50 sec-1, 30 sec-1 and 10 sec-1 showed the highest degree of efficiency in the case of an inlet water turbidity of 5 NTU, and the highest degree of efficiency was observed at a G value of 65 sec-1, 40 sec-1 and 10 sec-1 when the inlet water turbidity was 263 NTU. The number of flocs with a distribution of above $1,200{\mu}m$ was 14. The dynamics between two important growth mechanisms were investigated as the energy input changed. This is a certain method that makes use of the size and number of flocs as an efficiency assessment.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.18 no.3
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• pp.122-130
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• 2013

To examine floc characteristics of cohesive bed sediment of the Yeongsan River estuary, a floc camera system has been developed and utilized to observe flocs under varying conditions. In order to validate the floc camera system, sand particles were passed through 88-125 and $63-88{\mu}m$ sieves and observed within the laboratory. Mean grain size and settling velocities were found to be 102 and $56.2{\mu}m$ and 6.7 and 5.9 mm/s, respectively. Artifacts of particles estimated outside of the sieve range are attributed to being imaged out of the depth of focus. However, as mean grain size and settling velocity of each size class were within the confidence interval, the floc camera system was confidently used to examine cohesive bed sediments of Yeongsan River estuary. The bed sediment sample was prepared with a concentration of 0.1 g/L in 0 psu deionized water. The mean grain size, settling velocity and fractal dimension of flocs were $40.6{\pm}0.66{\mu}m$, 14 mm/s, and 2.86, respectively. Experiments were also conducted using different salinities (10 and 34 psu) and sediment concentrations (0.1 and 0.3 g/L). Despite changing these parameters, the mean observed grain size and settling velocities were found to be the same within the error range of the system. The relatively higher values of settling velocity and fractal dimension are considered a result of the sediment containing relatively small concentrations of organic matter. Moreover, consistent floc size over various grain sizes and concentrations may be the result of insufficient turbulence to aggregate flocs.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.2
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• pp.235-241
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• 2004

The dissolved air flotation (DAF) process has been widely used for removing suspended solids with low density in water. It has been known as measuring the size of microbubbles precisely which move upward rapidly in contact zone is difficult. In this study particle counter monitoring (PCM) method is used to measure the rising microbubble after injection from a nozzle. Size and distribution curve of microbubbles are evaluated at different conditions such as pressure drop at intermediate valve, length of pipeline between saturation tank and nozzle and low pressure. And the efficiency is also checked when it collides with different size floc. The experimental results show the following fact. As the final pressure drop occurred closer to a nozzle, the bubble size became smaller. And small bubble collides with large floc as well as small one because of its physical characteristic. However large bubble collides well with large floc rather than small one since hydrodynamic flow in streamline interferes to collide between two. With performing computational process by mathematical model we have analyzed and verified the size effect between bubble and floc. Collision efficiency is the highest when P/B ratio shows in the range of 0.75 < P/B ratio ($R_{particle/Rbubble}$) < 2.0.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.36 no.2
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• pp.10-16
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• 2004

Structures and strengths of paper have been studied by analyzing fibers characteristics depending on refining methods. Mixing ratio of softwood and hardwood fibers and fibers characteristics have been analyzed for paper quality improvement. In this study flocculation and drainage of fibers were analyzed to improve the production efficiency and paper product's quality. Floc size and drainage rate depending on stock consistency and fines content were analyzed. Total amount of drainage during drainage process was measured quantitatively by using DI(drainage index). Floc size, viscosity of floc and dewatering times were also measured. In the case of refining load $2.8 kg_f$ , drainage was occurred by filtration mechanism rather than thickening mechanism because drainage resistance increased by fibrillation of fibers. Therefore, the drainage rate of $2.8 kg_f$ refining load stock was slower than that of $5.6 kg_f$.