• Journal of the Korean Ceramic Society
• /
• v.26 no.6
• /
• pp.771-782
• /
• 1989

Synthesis of $\beta$-Sialon powder was attempted with carbothermal reduction of porous glass. The porous glass was prepared by heat and hydrothermal treatments of 9.32 Li2O.46.5B2O3.37.2SiO2.6.98Al2O3 glass. Carbon pyrolyzed from propane gas was deposited on the porous glass, thereafter activated carbon was added as reducing agents. The synthesized $\beta$-Sialon powder was pressureless sintered at 175$0^{\circ}C$ for 1hr in N2 atmosphere. The characterization of the $\beta$-Sialon powder was performed with XRD, BET, SEM and particle size analysis. The sinterability and mechanical properties of the sintered bodies were investigated in terms of bulk density, M.O.R., fracture toughness, morphology of microstructure and etc. The reduction effect of deposited carbon was better than that of activated carbon mechanically added. The formation of SiC was precominant over that of Si2ON2 and $\beta$-Sialon owing to low partial pressure of N2 inside the pore, wehreas on the surface of porous glass the formation of Si2ON2 and $\beta$-Sialon were predominant. Thereafter, SiC reduced unreacted glass to be $\beta$-Sialon. Single phase of $\beta$-Sialon(Z=1.92) was obtained from PGA porous glass having the largest pore radius by the simultaneous reduction and nitridation method at 145$0^{\circ}C$ for 5hrs. The bulk density, M.O.R., and KIC of the sitered body are 3.17g/cc, 434.4MPa and 4.1MPa.m1/2, respectively.

• The Transactions of the Korean Institute of Electrical Engineers C
• /
• v.52 no.8
• /
• pp.335-341
• /
• 2003

The composites were fabricated respectively 61vo1.% $\beta$ -SiC and 39vo1.% Ti $B_2$ spray-dried powders with the liquid forming additives of l2wt% $Al_2$ $O_3$＋ $Y_2$ $O_3$ by pressureless annealing at 1$700^{\circ}C$, 175$0^{\circ}C$, 180$0^{\circ}C$ for 4 hours. The result of phase analysis of composites by XRD revealed $\alpha$ -SiC(6H), Ti $B_2$, and YAG(A $l_{5}$ $Y_3$ $O_{12}$ ) crystal phase. The relative density, the Young's modulus and fracture toughness showed respectively the highest value of 92.97%, 92.88Gpa and 4.4Mpaㆍ $m^{\frac{1}{2}}$ for composites by pressureless annealing temperature 1$700^{\circ}C$ at room temperature. The electrical resistivity showed the lowest value of 8.09${\times}$10$^{-3}$ ㆍcm for composite by pressureless annealing temperature 1$700^{\circ}C$ at $25^{\circ}C$. The electrical resistivity of the SiC-Ti $B_2$ composites was all positive temperature cofficient resistance(PTCR) in the temperature ranges from $25^{\circ}C$ to $700^{\circ}C$.

• The Transactions of the Korean Institute of Electrical Engineers C
• /
• v.52 no.8
• /
• pp.348-353
• /
• 2003

This paper was the research of high voltage suspension insulator (400 [kN]) including pottery stone, feldspar, clay and alumina of 17 [wt%]. The slurry was fabricated after ball milling mixed raw materials. Green compacts were made by the extrusion of jiggering method and were sintered at 1300[$^{\circ}C$] for 50 [min.] in the tunnel kiln. The sintered density was reached to 97% of theoretical density, and the bending strength was 1658 [k $g_{f}$/$\textrm{cm}^2$] and hardness and fracture toughness which was measured by ICL( indentation crack length ) method were 1658 (kgf/$\textrm{cm}^2$) and 27.5 [Gpa], respectively. In measurement of tana and insulation break voltage of 400 (kN) porcelain, tan$\delta$ took some numerical value between 17${\times}$10$_{-3}$ and 61${\times}$10$_{-3}$ and insulation break voltage value was 19.9$\pm$1.4 [㎸/mm]. The test was performed to research whether the shape of pin affect a overvoltage break load or not As a consequence, when a pin was designed a pin diameter 51 [mm] with the bottom form of two-step constructed with straight in the suspension insulator, Insulator showed overvoltage break load 52 [ton] of the highest value and reflected a fine characteristic in aged deterioration test which is one of the accelerated aging test. Also it could be confirmed a fine characteristic through performing the test that electrical property of insulator was established correctly in accordance with IEC 60383-1 standards.s.

• Journal of the Korean Ceramic Society
• /
• v.36 no.12
• /
• pp.1356-1363
• /
• 1999

Self-reinforced silicon carbide was prepared by hot pressing and the control of starting phases of raw materials and its microstructural characteristics was investigated. The specimens with self-reinforced microstructure were obtained from the compacts with mixed compositions of ${\alpha}$-and ${\beta}$-SiC powders. Self-reinforced microstructure which is composed of large dispersed grains with rod-like shape and matrix with small equiaxed grains was formed by the transformation to the ${\alpha}$-SiC with 4H polytype for ${\beta}$-SiC and anisotropic grain growth during the heat treatment. Of all speimens the values of volume fraction maximum length and aspect ratio for large grains with rode-like types were the highest at the specimen with 50 vol% ${\beta}$-SiC in the starting SiC powder and therefore this specimen showed the highest fracture toughness due to the crack deflection by rod-like grains during crack propagation.

• Korean Journal of Materials Research
• /
• v.17 no.2
• /
• pp.100-106
• /
• 2007

The effects of $MgO-P_2O_5$ based sintering additive on the microstructure and material and biological properties of hydroxyapatite $(HAp,\;Ca_{10}(PO_4)_6(OH)_2)$ ceramic were investigated using XRD, SEM and TEM techniques. The $MgO-P_2O_5$ sintering additive improved the material properties and increased the grain size in the sintered HAp bodies. As the content of sintering additive increased over 4 wt%, a small amount of the HAp phase was decomposed and transformed to ${\beta}-TCP$. In the 2 wt% $MgO-P_2O_5$ content HAp sintered body, the maximum values of density and hardness were respectively about 3.10 gm/cc and 657 HV. However, the maximum fracture toughness in the HAp body containing 8 wt% $MgO-P_{2}O_{5}$ was about $1.02MPa{\cdot}m^{1/2}$ due to the crack deflection effect. Human osteoblast like MG-63 cells and osteoclast like raw 264.7 cells were well grown and fully covered all of the HAp sintered bodies. The osteoblast cells were grown with spindle-shaped and the osteoclast cells had a grape-like round shape.

• Korean Journal of Materials Research
• /
• v.20 no.8
• /
• pp.444-449
• /
• 2010

Transparent ceramics are used in new technology because of their excellent mechanical properties over glasses. Transparent ceramics are nowadays widely used in armor, laser windows, and in high temperature applications. Silicon nitride ceramics have excellent mechanical properties and if transparent silicon nitride is fabricated, it can be widely used. h-BN has a lubricating property and is ductile. Therefore, adding h-BN to silicon nitride ceramics gives a lubricating property and is also machinable. Translucent silicon nitride was fabricated by hot-press sintering (HPS) and 57% transmittance was observed in the near infrared region. A higher wt. % of h-BN in silicon nitride ceramics does not favor transparency. The optical, mechanical, and tribological properties of BN dispersed polycrystalline $Si_3N_4$ ceramics were affected by the density, ${\alpha}:{\beta}$-phase ratio, and content of h-BN in sintered ceramics. The hot pressed samples were prepared from the mixture of $\alpha-Si_3N_4$, AlN, MgO, and h-BN at $1850^{\circ}C$. The composite contained from 0.25 to 2 wt. % BN powder with sintering aids (9% AlN + 3% MgO). A maximum transmittance of 57% was achieved for the 0.25 wt. % BN doped $Si_3N_4$ ceramics. Fracture toughness increased and wear volume and the friction coefficient decreased with an increase in BN content. The properties such as transmittance, density, hardness, and flexural strength decreased with an increase in content of h-BN in silicon nitride ceramics.

• Polymer(Korea)
• /
• v.26 no.6
• /
• pp.767-777
• /
• 2002

In this work, biodegradable modified aliphatic polyester (MAP) in tetrafunctional epoxy (4EP) resin was investigated in terms of cure kinetics, thermal stabilities, rheological properties, and mechanical interfacial properties. DSC results of the blends show that the cure activation energies (E$\_$a/) were increased in 10 wt% of MAP compared with neat 4EP, due to the increasing intermolecular interaction between 4EP and MAP. The decomposed activation energies (E$\_$t/) derived from Coats-Redfern method, were increased within the 10∼30 wt% composition range of MAP contents, resulting from increasing the cross-linking density of the blend system. Rheological properties of the blend system were investigated under isothermal condition using a rheometer. Cross-linking activation energies (E$\_$c/) were determined from the Arrhenius equation based on gel time and curing temperature. As a result, the E$\_$c/ showed a similar behavior with E$\_$a/. The fracture toughness (K$\_$IC/) of the mechanical interfacial properties was discussed in semi-IPN behaviors of the casting specimen.

• Land and Housing Review
• /
• v.2 no.1
• /
• pp.47-52
• /
• 2011

Recent advances of technology in materials science have made it easy to respond to user's needs on high performance steel in civil and building structures. The high-performance and high-strength steel are required for large scale structure and high-rise building to have high-strength, high fracture toughness and better weldability etc. Therefore development of 600MPa class steel for mega structure is necessary. high strength steels, however, may have mechanical properties that are significantly different from those of the conventional steels. The application of high-strength steels to building structures should be reviewed as to whether inelastic behavior equivalent to that of conventional steels can be attained or not. This study researched the structural behavior of high strength circular tubes compression and under flexure. Three column tests and three flexural tests were carried out. The suitability of existing design formulae(KBC 2009) and the structural behavior were investigated through these columns and beams with various types.

• Composites Research
• /
• v.18 no.3
• /
• pp.31-37
• /
• 2005

In this work, poly(ethylene oxide) (PEO) nanofibers were fabricated by electrospinning to prepare the nanofibers-reinforced composites. And the PEO powders-impregnated composites were also prepared to compare the mechanical interfacial behaviors of the composites. Morphology and fiber diameter of PEO nanofibers were determined by SEM observation. Mechanical interfacial properties of the composites were investigated in fracture toughness $(K_{IC})$ and interlaminar shea. strength (ILSS) tests. As a result, the fiber diameter was decreased with increasing the applied voltage. And optimum condition for the fiber formation was 15 kV, resulting from increasing of jet instability at high voltage. The PEO-based nanofibers-reinforced epoxy composites showed the improvements of both $K_{IC}$ and ILSS, compared to the composites impregnated with PEO powders. These results indicated that the nanofibers had higher specific surface area and larger aspect ratio than those of the powders, which played an important role in improving the mechanical interfacial properties of the composites.

• Composites Research
• /
• v.26 no.2
• /
• pp.129-134
• /
• 2013

The strength of adhesive joints employed in composite structures under cryogenic environments, such as LNG tanks, is affected by thermal residual stress generated from the large temperature difference between the bonding process and the operating temperature. Aramid fibers are noted for their low coefficient of thermal expansion (CTE) and have been used to control the CTE of thermosetting resins. However, aramid composites exhibit poor adhesion between the fibers and the resin because the aramid fibers are chemically inert and contain insufficient functional groups. In this work, electrospun meta-aramid nanofiber-reinforced epoxy adhesive was fabricated to improve the interfacial bonding between the adhesive and the fibers under cryogenic temperatures. The CTE of the nanofiber-reinforced adhesives were measured, and the effect on the adhesion strength was investigated at single-lap joints under cryogenic temperatures. The fracture toughness of the adhesive joints was measured using a Double Cantilever Beam (DCB) test.