• Title/Summary/Keyword: Galvanic cell

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Properties of CoGe thin film-based galvanic cells and their applications for IoT sensor networks (CoGe 박막 기반 galvanic cell의 특성 및 IoT 센서 네트워크에 대한 적용)

  • Jeon, Buil;Han, Dongsoo;Yoon, Giwan
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.26 no.9
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    • pp.1347-1356
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    • 2022
  • In this paper, we investigate the properties of CoGe thin film-based galvanic cells as a function of their dimension (cell length, width, etc.) and show their application as sensors to Arduino-based IoT sensor networks to detect water contact. Because these CoGe thin film-based galvanic cells do not require mechanical strains or temperature gradients unlike piezoelectric and thermoelectric energy harvesters, we think that these thin film-based galvanic cells are more suitable for self-powered sensor networks demanding sustainable and robust energy harvesters. In the past, a sputter-deposited CoGe thin film has not been intensively investigated for energy harvesting appilcations. Thus, in this study, we perform a feasibility study of galvanic cells composed of a sputter-deposited CoGe thin film to see if they can be applied as potential self-powered sensors. We believe that this paper will be of great help in developing even more enhanced sensor networks.

Galvanic Corrosion between Carbon Steel 1018 and Alloy 600 in Crevice with Boric Acid Solution

  • Kim, Dong Jin;Macdonald, Digby D.;Kim, Hong Pyo;Kim, Joung Soo
    • Corrosion Science and Technology
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    • v.4 no.3
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    • pp.75-80
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    • 2005
  • This work dealt with the evaluation of galvanic corrosion rate in a corrosion cell having annular gap of 0.5 mm between carbon steel 1018 and alloy 600 as a function of temperature and boron concentration. Temperature and boron concentration were ranged from 110 to 300 $^{\circ}C$ and 2000~10000 ppm, respectively. After the operating temperature of the corrosion cell where the electrolyte was injected was attained at setting temperature, galvanic coupling was made and at the same time galvanic current was measured. The galvanic corrosion rate decreased with time, which was described by corrosion product such as protective film as well as boric acid deposit formed on the carbon steel with time. From the galvanic current obtained as a function of temperature and boron concentration, it was found that the galvanic corrosion rate decreased with temperaturewhilethe corrosionrate increasedwith boronconcentration. The experimental resultsobtained from galvanic corrosion measurement were explained by adhesive property of corrosion product such as protective film, boric acid deposit formed on the carbon steel wall and dehydration of boric acid to be slightlysolubleboric acid phase.Moreoverthe galvaniccorrosionrate calculatedusing initialgalvaniccoupling current instead of steady state coupling current was remarked, which could give us relatively closer galvanic corrosion rate to real pressurized water reactor.

Recognition Investigation of Physics and Chemistry Teachers on Electrodes in Galvanic Cell (물리학과 화학 전공 교사들의 화학전지 전극에 대한 인식 조사)

  • Park, Hyun-Jung;Kim, Jung-Bog
    • Journal of The Korean Association For Science Education
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    • v.30 no.4
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    • pp.389-401
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    • 2010
  • This research investigated recognitions on outside and inside electrodes in an electric circuit supplied by a galvanic cell, through survey and interview of teachers studying in Departments of Physics Education and Chemistry Education at H University Graduate School. Physics majors' designations on outside or inside parts of electrodes in a galvanic cell were different from Chemistry majors'. Teachers who had majored in physics had difficulties on the inside electrode of a galvanic cell, while teachers who had majored in chemistry had difficulties on the outside electrode. Reasonings for designations of electrodes were attributed to direction of electric current in case of physics teachers and redox in case of chemistry teachers, respectively, which are strongly dependent on backgrounds performed in their undergraduate course.

A Simple and Accurate Method for Determining Antioxidative Activity

  • Bae, Jin-Woo;Lee, Moo-Hong
    • The Korean Journal of Physiology and Pharmacology
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    • v.7 no.5
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    • pp.275-278
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    • 2003
  • Antioxidative activity is an important factor in inhibiting oxidative stress. The usual methods for determining antioxidative activity are time-consuming and cumbersome. They are also indirect processes that use biological material such as brain or liver microsome. This study therefore proposed a new method. Redoxpotential was determined using galvanic cell with or without the addition of various antioxidants or herbal extracts in zinc sulfate solution. The result was compared with the results from the TBA method and the peroxide value from sodium thiosulfate titration. All methods showed significant and dose-dependent enhancement of antioxidative activity by adding ascorbic acid, quercetin, ginseng, or gingko biloba extract. The result of redox potential using galvanic cell showed the smallest standard deviation and took the shortest time among the three methods. Therefore, the antioxidative potential of chemical substances and herbal extracts can be determined simply, directly and accurately in a short period of time using galvanic cell.

Application of Galvanic Oxidation and Pyrite Dissolution for Sustainable In-Situ Mine Tailings Treatment (갈바닉 산화와 황철석 용해를 이용한 친환경 원위치 광미 무해화 기술)

  • Ju, Won Jung;Jho, Eun Hea;Nam, Kyoungphile
    • Ecology and Resilient Infrastructure
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    • v.3 no.4
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    • pp.279-284
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    • 2016
  • Mine tailings generated during mining activity often contain high concentrations of heavy metals, with pyrite-containing mine tailings in particular being a major cause of environmental problems in mining areas. Chemical cell technology, or fuel cell technology, can be applied to leach heavy metals in pyrite-containing mine tailings. As pyrite dissolves through spontaneous oxidation (i.e. galvanic oxidation) in the anode compartment of the cell, $Fe^{3+}$, sulfuric acid are generated. A decrease in pH due to the generation of sulfuric acid allows heavy metals to be leached from pyrite-containing mine tailings. In this study, pyrite was dissolved for 4 weeks at $23^{\circ}C$ in an acidic solution (pH 2) and in a galvanic reactor, which induces galvanic oxidation, and total Fe leached from pyrite and pH were compared in order to investigate if galvanic oxidation can facilitate pyrite oxidation. The change in the pyrite surface was analyzed using a scanning electron microscope (SEM). Comparing the total Fe leached from the pyrite, there were 2.9 times more dissolution of pyrite in the galvanic reactor than in the acidic solution, and thus pH was lower in the galvanic reactor than in the acidic solution. Through SEM analysis of the pyrite that reacted in the galvanic reactor, linear-shaped cracks were observed on the surface of the pyrite. The study results show that pyrite dissolution was facilitated through the galvanic oxidation in the galvanic reactor, and also implied that the galvanic oxidation can be one remediation option for pyrite-containing mine tailings.

The Study on the Galvanic Corrosion of Al-alloy for Heat Exchanger (Al합금 열교환기의 전지작용부식에 관한 연구)

  • LIM, U-Jo;LEE, Eun-Jeong
    • Journal of Fisheries and Marine Sciences Education
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    • v.15 no.1
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    • pp.115-122
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    • 2003
  • Generally, material for radiator of automobile is composed of Al-alloy, but part of radiator material is still composed of Cu. Specially, Al-alloy replaces Cu and Cu-alloy as cooling and heating system material for light weight. Therefore, galvanic electronic cell is formed between Al-alloy and Cu for automobile radiator material, and Al-alloy corrosion is accelerated. So, in this study, galvanic corrosion test of Al-alloy coupling with Cu was carried out in distilled water, tap water, polluted environment and non-freezing solution. And thus corrosion potential and galvanic currrent density of Al-alloy coupling with Cu is investigated.

Free Energy of Formation of BaThO3 from E.M.F. Measurement

  • Park, S. H.;H. D. Baek;J. S. Hwang;Park, C. O.
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.204-206
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    • 1998
  • The Gibbs free energy of formation of $BaThO_3$ from elemental oxides has been measured at temperatures between 853 and 903 K using a $CaF_2$ solid electrolyte galvanic cell. The galvanic cell consisted of Pt, $O_2, CaO+CaF_2 \parallel CaF_2 \parallelBaThO_3+ThO_2+BaF_2, O_2$, Pt EMF gave the standard Gibbs free energy for the reaction $CaF_2+BaThO_3=CaO+BaF_2+ThO_3$ as $\DeltaG^o$,/TEX>=124111.031-117.597 T(J/mol).

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Evaluation of effect of galvanic corrosion between nickel-chromium metal and titanium on ion release and cell toxicity

  • Lee, Jung-Jin;Song, Kwang-Yeob;Ahn, Seung-Geun;Choi, Jung-Yun;Seo, Jae-Min;Park, Ju-Mi
    • The Journal of Advanced Prosthodontics
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    • v.7 no.2
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    • pp.172-177
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    • 2015
  • PURPOSE. The purpose of this study was to evaluate cell toxicity due to ion release caused by galvanic corrosion as a result of contact between base metal and titanium. MATERIALS AND METHODS. It was hypothesized that Nickel (Ni)-Chromium (Cr) alloys with different compositions possess different corrosion resistances when contacted with titanium abutment, and therefore in this study, specimens ($10{\times}10{\times}1.5mm$) were fabricated using commercial pure titanium and 3 different types of Ni-Cr alloys (T3, Tilite, Bella bond plus) commonly used for metal ceramic restorations. The specimens were divided into 6 groups according to the composition of Ni-Cr alloy and contact with titanium. The experimental groups were in direct contact with titanium and the control groups were not. After the samples were immersed in the culture medium - Dulbecco's modified Eagle's medium[DMEM] for 48 hours, the released metal ions were detected using inductively coupled plasma mass spectrometer (ICP-MS) and analyzed by the Kruskal-Wallis and Mann-Whitney test (P<.05). Mouse L-929 fibroblast cells were used for cell toxicity evaluation. The cell toxicity of specimens was measured by the 3-{4,5-dimethylthiazol-2yl}-2,5-diphenyltetrazolium bromide (MTT) test. Results of MTT assay were statistically analyzed by the two-way ANOVA test (P<.05). Post-hoc multiple comparisons were conducted using Tukey's tests. RESULTS. The amount of metal ions released by galvanic corrosion due to contact between the base metal alloy and titanium was increased in all of the specimens. In the cytotoxicity test, the two-way ANOVA showed a significant effect of the alloy type and galvanic corrosion for cytotoxicity (P<.001). The relative cell growth rate (RGR) was decreased further on the groups in contact with titanium (P<.05). CONCLUSION. The release of metal ions was increased by galvanic corrosion due to contact between base metal and titanium, and it can cause adverse effects on the tissue around the implant by inducing cytotoxicity.

Electric Conduction Properties of NaCl Electrolyte as a Function of Electrode Materials (전극재료에 따른 NaCl 전해질의 전기전도특성)

  • Kim, Yong-Hyuk
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.11
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    • pp.2026-2031
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    • 2010
  • The electrical characteristics of galvanic cell which is composed of the cathode electrode(graphite, carbon and copper) and the anode electrode(Zn and Mg) were investigated. For this research as electrolyte 2~12 wt% NaCl aqueous solution were used. At graphite cathode electrodes which use Zn and Mg with the anode electrode, the open circuit voltage was 1.3V most highly. The maximum output power increased as the electrolyte concentration increased, due to a increase in ion density. When Zn and Mg with the anode electrode, the maximum output power respectively was evaluated as 2.2mW and 5.5mW about the graphite cathode electrode in the NaCl 4wt%. The research results indicated that the output power of cell which is composed with graphite with the cathode and Mg with the anode was most excellent and the efficiency of the cell could be enhanced by increasing the electrolyte concentration.