• Economic and Environmental Geology
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• v.18 no.2
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• pp.139-150
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• 1985

Skarn at the Dielette formed largely in calc-silicate hornfels at the contact with the Flamanville granite. The skarn consists mainly of garnet and pyroxene, and less frequently vesuvianite. Traversing toward calc-silicate hornfels wall rock from a central zone of the skarn, the general sequence of formation of mineral assemblages is: (1) dark brown garnet (2) pale brown garnet-vesuvianite-pyroxene, and (3) pyroxene-prehnite-scapolite-wollastonite envelopes (designated as transition zone) developed between skarn and calc-silicate hornfels. The central zone of the skarn consists mainly of dark brown garnets (garnet I) that contain little or no pyroxene. The pale brown garnet (garnet II) is associated with pyroxene and vesuvianite. The sequence of these garnets results from the zonal growth outward. There is an abrupt discontinuity in composition between garnet I formed in early stage and garnet II in late stage, while each garnet shows relatively uniform composition. At the zone in contact with the granite, the iron contents of garnets decrease toward the marginal zone of the skarn, from an average value of 36 mole % andradite in garnet I to 18 mole % andradite in garnet II. At the zone distant from the granite, the andradite component decreases from 28 mole % in garnet 1 to 19 mole % in garnet II. The variation of the iron contents of pyroxenes is also similar to that of garnets. The sharp discontinuity in composition of garnets and pyroxenes suggests that the skarn of study area was formed by infiltration metasomatic process. The results of the analyses of mineral assemblages of the transition zone by chemical potential diagrams suggest that the transition zone was made by the diffusion of the elements Ca, K and Fe from the skarn to the calc-silicate hornfels contact zone. The estimated temperatures and $Xco_2$ for the formation of the transition zone show $300^{\circ}C$$440^{\circ}C$ and $0.07{\pm}0.05<Xco_2<0.02{\pm}0.01$ at 1 Kb respectively.

• Journal of the Korea Concrete Institute
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• v.11 no.3
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• pp.123-130
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• 1999

In a preceding study(1), the using method of garnet powder has been studies through the various investigation of basic material properties on garnet powder, industrial by-products generated in Yungju, Kyungpook. In this study, the various properties of concrete mixed with garnet powder are examined as following condition : Unit weight of water (170kg/㎥), water-binder ratio W/B (53, 55 and 58%), sand-aggregate ratio (S/A) (43, 45 and 48%), substitutional ratio of garnet powder of 0, 5, 10, 15 and 20%. Slump increased a little as the substitutional ratio of garnet increased. Air content decreased a little at the substitutional ratio of 10%. or more. Though there is a little difference in compressive strength according to the W/B and the substitutional ratio, compressive strength of concrete using garnet exceeded that of plain concrete a little in the range of the substitutional ration of 5 to 15%. Also, There is a similar tendency in the tensile and flexural strength. Therefore, the use of garnet powder with industrial by-products is expected to improve the workability and the strength of concrete.

• Journal of the Korean Magnetics Society
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• v.5 no.4
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• pp.287-293
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• 1995

자성물질의 자구를 관측하고, 표면의 자기전하를 측정하는 간단하면서도 정량적인 방법을 제시하였다. 관측방법은 자기 garnet film을 사용하며, 이 방법을 이용하여 {100} 철단결정 표면의 자구를 관측할 수 있었다. garnet film의 자구는 garnet 면과 수직한 자기장에 의해서만 변하고 임계 자기장에서는 사라진다. 그러나, 철단결정의 자구는 단결정 표면에 평행하게 걸어준 자기장에 대하여서는 영향을 받지만 수직하게 가한 자 기장에는 아무런 영향을 받지 않는다. 위와 같이 성질을 이용하여 철단결정과 평행한 자기장을 가할 때 철단결정의 자구에 유도된 전하에 인하여 garnet film의 자구가 변화하며, 이 garnet film의 자구는 편광된 빛을 이용하여 직접 관측할 수 있다. 이 방법으로 철단결정의 표면에 유도 되는 자기전하 분포를 측정할 수 있었고, 또한 단결정에 걸어준 전류가 변할때 단결정 자구의 움직임을 관측할 수 있었다. 이 관측한 결과 를 이용하여 철단결정에 전류를 가할 때의 비대칭적으로 유도되는 교류 자기감수율 실험의 결과를 설명할 수 있었다.

• Economic and Environmental Geology
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• v.45 no.1
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• pp.1-8
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• 2012

Copper-zinc-bearing skarns of the Kasihan area developed at limestone layers in the sedimentary facies of the Late Oligocene Arjosari Formation. The skarns consist mainly of fine-grained, massive clinopyroxene-garnet, garnet, garnet-epidote, and epidote skarns. Most copper and zinc(-lead) ore mineralization occur in the clinopyroxene-garnet and garnetepidote skarn, respectively. Clinopyroxene occurs as a continuous solid solution of diopside and hedenbergite (from nearly pure diopside up to ${\approx}34$ mole percent hedenbergite), with a maximum 28.2 mole percent johannsenite component. The early and late pyroxenes of Kasihan skarns are diopsidic and salitic, respectively. They fall in the fields typical Cu- and Zn-dominated skarns, respectively. Garnet displays a relatively wide range of solid solution between grossular and andradite with up to ${\approx}2.0$ weight percent MnO. Garnet in early pyroxene-garnet skarn ranges from 49.1 to 91.5 mole percent grossular (mainly ${\geq}78$ mole % grossular). Garnets in late garnet and garnet-epidote skarns range from 2.8 to 91.4 mole percent grossular (mainly ${\geq}70$ mole % for garnet skarn). Epidote compositions indicate solid solutions of clinozoisite and pistacite varying from 65.8 to 76.2 mole percent clinozoisite. Phase equilibria indicate that skarn evolution was the result of interaction of water-rich fluids ($X_{CO_2}{\leq}0.1$) with original lithologies at ${\approx}0.5$ kb with declining temperature (early clinopyroxene-garnet and garnet skarn, ${\approx}450$ to $370^{\circ}C$; late garnet-epidote and epidote skarn, ${\approx}370$ to $300^{\circ}C$).

• Journal of the Korean Magnetics Society
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• v.3 no.2
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• pp.101-107
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• 1993

The crystallographic properties of the polycrystalline materials $Fe_{1+X}Eu_{1-X}O_{3}$(X = -0.06, 0.0, 0.1, 0.2, 0.3, 0.4) have been studied by the methods of X-ray diffraction and $M\"{o}ssbauer$ spectroscopy. The results showed that the samples with the composition range of $0.2{\leq}x{\leq}0.3$ had the garnet crystal phase, while those with $-0.06{\leq}x{\leq}0.0$ had the orthoferrite phase. However, with the tendency for the orthoferrite phase to convert into the trigonal phase via garnet phase as increasing the composition x, the orthoferrite-garnet and garnet-trigonal phase coexisted dominantly in the range of 0.0 < x < 0.2 and $0.4{\geq}x$, respectively. The analyzed results of $M\"{o}ssbauer$ spectrum indicated existence of some vacancies in the d-site of garnet phase, which can be related to the change of intensity in X-ray diffraction patterns.

• Journal of the Korean earth science society
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• v.25 no.1
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• pp.39-47
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• 2004

In the FMAS system the effect of iron on alumina solubility in orthopyroxene has been determined by experiments with crystalline starting mixtures of garnet and orthopyroxene of known initial compositions at 20 kb, 975$^{\circ}C$ and 25 kb, 1,200$^{\circ}C$. These data have been modeled to develop a thermodynamic method for the calculation of Al$_{2}$O$_{3}$ in orthopyroxene as a function of P, T and composition. The direct application of the alumina solubility data in the MAS system to natural assemblages could lead to significant overestimation of pressure, probably by about 5kb for the relatively common garnet-lherzolites with abot 25 mol per cent Ca + Fe$^{2+}$ in garnet and about 1 wt. per cent Al$_{2}$O$_{3}$ in orthopyroxene since the effect of Fe is similar to that of Ca and Cr$^{3+}$in reducing the alumina solubility in orthopyroxene in equilibrum with garnet relative to that in the MAS system.

• Geosciences Journal
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• v.22 no.6
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• pp.939-953
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• 2018

We examined the microfabrics of omphacite and garnet in foliated eclogite to determine the influence of the layered structure on seismic observations in subduction zone. The analyzed eclogite, from the Lanterman Range, northern Victoria Land, Antarctica, is characterized by layering in which the modal abundances of garnet and omphacite vary. For garnet, the low aspect ratios, similar angular distribution of long axes relative to the foliation in both layers, uniform grain size distribution, near-random crystallographic preferred orientations (CPOs), and misorientation angle distributions are indicative of passive behavior during deformation. In contrast, omphacite shows relatively high aspect ratios, a low angle between the long axes of crystals and the foliation, a wide grain-size distribution, and distinctive CPOs, suggesting dislocation creep as the main deformation mechanism. The results of fabric analyses are consistent with strain localization into omphacite or omphacite-rich layers rather than garnet or garnet-rich layers. The single-crystal seismic anisotropy of garnet is very weak ($AV_P=0.2%$, $AV_S=0.5-0.6%$), whereas that of omphacite is much stronger ($AV_P=3.7-5.9%$ and $AV_S=2.9-3.8%$). Seismic anisotropy of the omphacite-rich layers shows an increase of 329% for $AV_P$ and 146% for $AV_S$ relative to the garnet-rich layers. Our results demonstrate the importance of the layered structure in strain localization and in the development of the seismic anisotropies of subducting oceanic crust.

• Journal of Integrative Natural Science
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• v.4 no.1
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• pp.58-71
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• 2011

The precambrian gneisses are widely distributed in the Jangsu area. This study focuses on the metamorphic mineral assemblages and metamorphic P-T conditions of the gneiss. We have analyzed garnet, biotite and plagioclase among the gneiss through the EPMA analysis, and calculated the metamorphic temperature and pressure accordingly. The metamorphic temperature was estimated by the average of values from the garnet and biotite formulas, and the metamorphic pressure by value of the Hoisch(1990) geopressured on garnet-biotite-plagioclase. The mineral sample we examined shows garnet-biotite-plagioclase-quartz composite and garnet-plagioclase-orthoclase-quartz composite. Garnet shows almandine-pyrope solid solution in general, while porphyroblastic gneiss shows almandine-grossluar solid solution. The fact that the abundances, observed by garnet profile, are almost identical in both the central region and the outer egion indicates that the crystal was developed uniformly. There is almost negligible variance in biotite on metamorphic grade, and andesine is observed in plagioclase. The metamorphic temperature and pressure from EPMA analysis and its indications are as follows: the middle-temperature, high-pressure metamorphism ($500-650^{\circ}C$, 6.9-10 kbar) ensued in the beginning, and then was followed by the high-temperature, middle-pressure($600-740^{\circ}C$, 2.7-5.9 kbar) to ($500-540^{\circ}C$, 3.1 kbar) retrograde metamorphism.

• Journal of the Korean Magnetics Society
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• v.13 no.1
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• pp.1-5
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• 2003

Magnetic and structural properties of $(CoFe_2O_4)_{1-x}(Y_3Fe_5O_{12})_x$ powders (0 $\leq$ x $\leq$ 1) grown by a conventional ceramic method were investigated using X-ray diffractormeter (XRD), scanning electron microscopy (SEM), Mossbauer spectroscopy and vibrating sample magnetometer (VSM). The XRD results for the powders annealed at 120$0^{\circ}C$ indicated that no other peak was observed except for the ones from cobalt ferrite and the garnet powder. SEM micrographs indicated that cobalt ferrite and garnet powders were aggregated and completely formed together. It was hard to identify which part of the powders was the garnet or the cobalt ferrite. Mossbauer spectra for powders grown separately and mixed mechanically consisted of sub-spectra of cobalt ferrite and garnet, however, powders annealed together had an extra sub-spectrum, which was related with the interaction between iron ions at the grain surfaces of cobalt ferrite and the garnet: cobalt ferrite and garnet particles were located very closely. The value of the saturation magnetization measured by a VSM as a function of composition ratio agreed very well with the ones based on the theoretical calculation.

• Journal of the Korean Magnetics Society
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• v.8 no.6
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• pp.350-356
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• 1998

$Y_{3-x}La_xFe_5O_{12}$ (x=0.0, 0.25, 0.5, 0.75, 1.0) powders and thin films were fabricated by a sol-gel method and their magnetic properties and crystal structure were investigated by using X-ray diffraction (XRD), atomic force microscopy (AFM), scanning electron microscopy (SEM), vibrating sample magnetometer (VSM), and Mossbauer spectroscopy. XRD and Mossbauer spectroscopy measurements show that garnet powders annealed at 900 $^{\circ}C$ for 8 hours were single-phased and that thin films fired at 800 $^{\circ}C$ for 2 hours were crystallized without any preferred direction. X-ray diffraction patterns of $Y_{3-x}La_xFe_5O_{12}$ powders annealed at 1000 $^{\circ}C$ had only peaks of the garnet structure in case of x$\leq$0.75 but those of $Y_2LaFe_5O_{12}$ powders consisted of peaks from garnets and $LaFeO_3$. Mossbauer sepectra of garnet powders grown by the sol-gel method had a similar shape of those of powders grown by a conventional ceramic method. Grain sizes of garnet powders were 200~300 nm and the averaged surface roughness was 3.17 nm. Results of VSM measurements show the powders and thin films had soft magnetic properties and that the garnet powders had the largest saturation magnetization, 30 emu/g, and the lowest coercivity, 52 Oe.