• Title/Summary/Keyword: Ge substitution

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Superconducting Properties of Ge Substitution for the Bi Site in the 2212 Phase of Bi-Sr-Ca-Cu-O Superconductors (Bi계 산화물 초전도체 2212상에 있어서 Bi 자리에 Ge 치환에 따른 초전도 특성)

  • 신재수;이민수;최봉수;송승용;송기영
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.787-791
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    • 2000
  • Samples with the nominal composition, Bi2-xGexSr2CaCu2O8+$\delta$ (x=0, 0.1, 0.2, 0.3, 0.4, 0.5) were prepared by the solid-state reaction method. We have studied the effect of substitution Ge for Bi and investigated the superconducting properties by changing oxygen content with Ge substitution. It was found that temperature difference, ΔK, between TCon and TCzero was considerably smaller in the samples prepared by the intermediate pressing method than that in the samples by the solid-state reaction method. We found the solubility limit of Ge to the 80 K single phase was around x=0.3. Within the solubility limit, lattice constant c decreased with the increase of x. In the region of the 80K single phase, the onset critical temperature TCon increased and excess oxygen content decreased with increase of x.

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Improvement of $^{4}I_{11/2}{\to}^{4}I_{13/2}$ Transition Rate and Thermal Stabilities in $Er^{3+}-Doped\;TeO_2-B_2O_3\;(GeO_2)-ZnO-K_2O$ Glasses

  • Cho, Doo-Hee;Choi, Yong-Gyu;Kim, Kyong-Hon
    • ETRI Journal
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    • v.23 no.4
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    • pp.151-157
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    • 2001
  • Spectroscopic and thermal analysis indicates that tellurite glasses doped with $B_2O_3$ and $GeO_2$ are promising candidate host materials for wide-band erbium doped fiber amplifier (EDFA) with a high 980 nm pump efficiency. In this study, we measured the thermal stabilities and the emission cross-sections for $Er^{3+}:^{4}I_{13/2}\;{\to}\;^{4}I_{15/2}$ transition in this tellurite glass system. We also determined the Judd-Ofelt parameters and calculated the radiative transition rates and the multiphonon relaxation rates in this glass system. The 15 mol% substitution of $B_2O_3$ for $TeO_2$ in the $Er^{3+}-doped\;75TeO_2-20ZnO-5K_2O$ glass raised the multiphonon relaxation rate for $^4I_{11/2}\;{\to}\;^4I_{13/2}$ transition from 4960 $s^{-1}$ to 24700 $s^{-1}$, but shortened the lifetime of the $^4I_{13/2}$ level by 14 % and reduced the emission cross-section for the $^4I_{13/2}\;{\to}\;^4I_{15/2}$ transition by 11%. The 15 mol% $GeO_2$ substitution in the same glass system also reduced the emission cross-section but increased the lifetime by 7%. However, the multiphonon relaxation rate for $^4I_{11/2}{\to}^4I_{13/2}$ transition was raised merely by 1000 $s^{-1}$. Therefore, a mixed substitution of $B_2O_3$ and $GeO_2$ for $TeO_2$ was concluded to be suitable for the 980 nm pump efficiency and the fluorescence efficiency of $^4I_{13/2}{\to}^4I_{15/2}$ transition in $Er^{3+}-doped$ tellurite glasses.

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Synthesis and Characterization of Langastie-type Materials

  • An, Jin-Ho;Yoon, Won-Ki;Kynug Joo;Auh, Keun-Ho
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.06a
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    • pp.115-119
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    • 1998
  • Possibilities of substitution was investigated in the Langadite({{{{ {La }_{3 } {Ga }_{ 5}{SiO }_{14 }}}}}) system.{{{{{TiO}_{2 }}}}} was substitutes for{{{{{SiO}_{2 }}}}} followed by the substitution of{{{{{Nd}_{2 }{O}_{3}}}}}fo{{{{{La}_{2 }{O}_{3}}}}}. An effort to replace GeO2, which is reported to have been substitution for{{{{{SiO}_{2 }}}}} in the Langasit e system, for{{{{{TiO}_{2 }}}}} i n{{{{{ Nd}_{ 3} {Ga }_{5 } {TiO }_{14 } }}}} was also undertaken. In another experiment,{{{{{ Y}_{ 2}{ O}_{3 } }}}} was substituted for{{{{{ La}_{2 } {O }_{ 3} }}}}. All of substitution possibilities were investigated through solid state reactions and analyzed with XRD. Further analysis was carried out with an SEM. Lastly, the dielectric constants of the sintered body were measured.

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Properties and Crystallization Characteristics of Ge-Se-Te Glasses (Ge-Se-Te계 칼코지나이드 유리의 결정 생성 현상 및 특성)

  • Lee, Yong-Woo;Heo, Jong
    • Journal of the Korean Ceramic Society
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    • v.32 no.2
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    • pp.239-247
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    • 1995
  • Chalcogenide glasses with compositions of Ge10Se90-xTex(X=0~50 at.%) were prepared in order to investigate the effects of Te substitution on the transmission characteristics of Ge-Se glasses in the 8~12 ${\mu}{\textrm}{m}$ wavelength region. Absorption coefficients were observed to decrease with Te addition, indicating the improved transmission capabilities of Ge-Se-Te glasses as compared to binary Ge-Se glasses. XRD analysis of crystallized glasses suggested the formation of weaker Se-Te and/or Te-Te bonds with addition of Te substituting for Se in stronger Se-Se bonds. Incorporation of Te in excess of 20at% resulted in the formation of hexagonal Te phases when crystallized. It is speculated that the presence of Te-Te bonds with highly metallic bond character resulted in the enhanced crystallization tendencies of glasses. Fromation of Te-rich chains through gradual replacement of Se-Se with Se-Te and/or Te-Te bonds was further supported by decreases in glass transition and crystallization temperatures.

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The Effect of Cr doping on the Magnetic and Magnetocaloric Properties of MnCoGe Alloys

  • Emre, S. Yuce
    • Journal of Magnetics
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    • v.18 no.4
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    • pp.405-411
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    • 2013
  • The structural, magnetic and magnetocaloric properties of $CoMn_{1-x}Cr_xGe$ (x=0.05-0.125) have been investigated by using electron microscopy, x-ray diffraction, calorimetric and magnetic measurements. In this study, our aim is to justify the magnetocaloric effect by tuning the structural and magnetic transition temperature with Cr doping on CoMnGe pure system. The substitution of Cr for Mn leads to a decrease of both structural and magnetic transition temperatures. However, structural and magnetic transition temperatures do not close to each other. From magnetization measurement, we calculate that isothermal entropy change associated with magnetic transition can be as high as 3.82 J $kg^{-1}K^{-1}$ at 302 K in a field of 7 T. Meanwhile, structural phase transition contribution to isothermal entropy change is calculated as 5.85 J $kg^{-1}K^{-1}$ at 322 K for 7 T.

Dependence of the lithium ionic conductivity on the B-siteion substitution in $(Li_{0.5}La_{0.5})Ti_{1-x}M_xO_3$

  • Kim, Jin-Gyun;Kim, Ho-Gi
    • Electrical & Electronic Materials
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    • v.11 no.11
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    • pp.9-17
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    • 1998
  • The dependence of the ionic conductivity on the B-site ion substitution in (Li0.5La0.5)Ti1-xMxO3 (M=Sn, Zr, Mn, Ge) system has been studied. Same valence state and various electronic configuration and ionic radius of Sn4+, Zr4+, Mn4+ and Ge4+(4d10(0.69$\AA$), 4p6(0.72$\AA$), 3d10(0.54$\AA$) and 3d3(0.54$\AA$), respectively) induced the various crystallographic variaton with substitutions. So it was possibleto investigate the crystallographic factor which influence the ionic conduction by observing the dependence of the conductivity on the crystallographic factor which influence the ionic conduction by observing the dependence of the conductivity on the crystallographic variations. We found that the conductivity increased with decreasing the radii of B-site ions or vice versa and octahedron distortion disturb the ion conduction. The reason for this reciprocal proportion of conductivity on the radius of B-site ions has been examined on the base of the interatomic bond strength change due to the cation substitutions. The results were good in agreement with the experimental results. Therefore it could be concluded that the interatomic bond strength change due to the cation substitutions may be the one of major factors influencing the lithium ion conductivity in perovskite(Li0.5La0.5) TiO3system.

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LCB: Light Cipher Block An Ultrafast Lightweight Block Cipher For Resource Constrained IOT Security Applications

  • Roy, Siddhartha;Roy, Saptarshi;Biswas, Arpita;Baishnab, Krishna Lal
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.15 no.11
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    • pp.4122-4144
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    • 2021
  • In this fast-paced technological world, the Internet of Things is a ground breaking technology which finds an immense role in the present electronic world which includes different embedded sensors, devices and most other things which are connected to the Internet. The IoT devices are designed in a way that it helps to collect various forms of data from varied sources and transmit them in digitalized form. In modern era of IoT technology data security is a trending issue which greatly affects the confidentiality of important information. Keeping the issue in mind a novel light encryption strategy known as LCB is designed for IoT devices for optimal security. LCB exploits the benefits of Feistel structure and the architectural benefits of substitution permutation network both to give more security. Moreover, this newly designed technique is tested on (Virtex-7) XC7VX330T FPGA board and it takes much little area of 224 GE (Gate Equivalent) and is extremely fast with very less combinational path delay of 0.877 ns. An in-depth screening confirms the proposed work to promise more security to counter cryptographic attacks. Lastly the Avalanche Effect (AE) of LCB showed as 63.125% and 63.875% when key and plaintext (PT) are taken into consideration respectively.

Concurrent Bioassay of Energy and Protein Utilization of Protein Sources in Layer Diets (채란계 단백질 급원의 단백질과 에너지 이용성의 동시 생물검정)

  • 고태송;주양돈;우경목;최철림;박병석
    • Korean Journal of Poultry Science
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    • v.21 no.2
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    • pp.133-138
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    • 1994
  • A study of concurrent bioassay for protein quality and energy level in protein sources was rnade by determining urinary nitrogenous compounds in excreta. The carry over effect of previous feeding was eliminated by 48 h of feeding the experimental diets prior to the determination of for protein digestibility and utilizability, and energy digestibility and metabolizability at 24 h interval during 3 days. Then, protein qualities and energy levels for soybean meal, rapeseed meal and fish meal were calculated by a substitution method. Apparent protein utilization (NB/NI) was affected by the increased fecal nitrogen excretion in soybean meal and by the increased urinary nitrogen excretion in rapeseed meal and fish meal. The apparent metabolizability of energy (ME/GE) was affected by the fecal energy excretion in soybean meal and rapeseed meal and by urinary energy excretion in fishmeal. The results indicated that the concurrent bioassay of protein quality and energy levels in ingredients appears to be applicable to chickens of other age, sex, breeds and environmental conditions.

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An Efficient Implementation of ARIA-AES Block Cipher (ARIA-AES 블록암호의 효율적인 구현)

  • Kim, Ki-Bbeum;Shin, Kyung-Wook
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2016.10a
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    • pp.155-157
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    • 2016
  • 한국 표준 블록암호 알고리듬 ARIA(Academy, Research Institute, Agency)와 미국 표준인 AES(Advanced Encryption Standard) 알고리듬은 128-비트 블록 길이를 지원하고 SPN(substitution permutation network) 구조를 특징으로 가져 서로 유사한 형태를 지닌다. 본 논문에서는 ARIA와 AES를 선택적으로 수행하는 ARIA-AES 통합 프로세서를 효율적으로 구현하였다. Verilog HDL로 설계된 ARIA-AES 통합 프로세서를 Virtex5 FPGA로 구현하여 정상 동작함을 확인하였고, $0.18{\mu}m$ 공정의 CMOS 셀 라이브러리로 100KHz의 동작주파수에서 합성한 결과 39,498 GE로 구현되었다.

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