• 환경영향평가
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• 제19권4호
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• pp.431-441
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• 2010

In this study, inter-comparison for PM-2.5 was undertaken. The PM-2.5 mass concentrations using the gravimetric and beta-attenuation methods were compared during the winter in 2007. Two different types of conventional filter-based measurements (Cyclone type and Impactor type) were also collocated and the measurement data was compared with each other. As a result, continuous PM-2.5 data using beta attenuation method show a comparable mass concentration with gravimetric measurement when the inlet of beta-gauge sampler is heated. The results also showed that the cyclone type shows a little high PM-2.5 concentration than Impactor type. In all the sampling cases, the correlations between measurement methods are high. Subsequently, this study suggests that highly correlated relationship between PM-2.5 measurement instruments can be obtained through the inter-comparison results based on filterb-ased gravimetric method and more intensive measurement and theoretical studies are needed in order to clarify the measurement errors for different sampler types.

• 대한기계학회논문집B
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• 제25권4호
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• pp.561-571
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• 2001

The standard uncertainty of flowrate measurement is obtained by combining that of independent variables. Gravimetric and volumetric method were applied to determine the flowrate and the standard uncertainties of flowrate measurement by both methods were evaluated in accordance with the procedure recommended by International Organization for Standardization. The combined standard uncertainties of determining the flowrate were estimated from the sensitivity coefficient and the standard uncertainty of independent variables. For practical application, the methods for evaluating and expressing uncertainty in flow measurement were discussed. It was found that the uncertainties of the weighing and time measurement in gravimetric method, the volume and time measurement in volumetric method have dominant influence on that of flowrate measurement. With the quantitative analysis of the sensitivity coefficient, the contribution of the each variable uncertainty to the combined standard uncertainty of flowrate measurement is shown clearly.

• Bulletin of the Korean Chemical Society
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• 제15권1호
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• pp.9-12
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• 1994

The gravimetric determination of scandium by di-(2-ethylhexyl)phosphate(DEHPA) as a precipitant and the mole ratio of Sc-DEHPA arecipitation obtained in ethanol medium have been investigated. Scandium can be determined by gravimetric method of precipitation of Sc-DEHPA and the mole ratio of Sc-DEHPA is found as 1 :2 in ethanol medium.

• 한국입자에어로졸학회지
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• 제5권2호
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• pp.53-62
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• 2009

In this study, the continuous monitoring of the concentration of PM-10 atmospheric particulate matter using beta ray attenuation method was compared with gravimetric method from September, 2006 to August, 2007. On the effects of the PM-10 concentration and mass difference by relative humidity and precipitation were considered. The result showed that the measurement error between beta ray method and gravimetric method are within -3~6% in average, which means PM-10 concentration data with beta ray method are relatively comparable. The current study also shows that the high PM-10 concentration events are mainly due to haze, Asian dust, and high relative humidity and the PM-10 mass concentration is closely related with relative humidity and precipitation events. Based on daily mean data, the PM-10 increases as relative humidity increases up to 70~80%, then decreases over 80% due to the precipitation. However, the distinct measurement discrepancy was not shown between beta ray method and gravimetric method based on current results. Consequently, this study shows that the collocated measurement in different instrument is essential in order to quantify the accuracy of PM-10. Furthermore, the more comprehensive and spatially distributed comparison is needed and this is remained for future study.

• 산업식품공학
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• 제15권1호
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• pp.41-47
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• 2011

쌀부산물인 탈지미강을 상업적으로 사용되는 8가지 protease를 최적화된 조건에서 단일 혹은 혼합 처리하여 수용성 단백질을 분리하였다. 이렇게 분리된 단백질을 Lowry, Kjeldahl 그리고 Gravimetric method 등 총 3가지 방법으로 분석을 한 결과 Protamex, Alcalase, Protease N이 가장 높은 분해율을 나타냈다. 3가지 방법에서 모두 Protamex, Alcalase, Protease N이 가장 높은 분해율을 나타내었고, Gravimetric method의 경우 다른 두 분석방법인 Lowry, Kjeldahl method에 비해 더 높은 단백질 함량을 보였다. 또한 위의 단일처리결과를 바탕으로 3가지 protease를 혼합하여 처리하였을 때 단일효소처리에 비해 상승효과가 나타나는 것을 알 수 있었는데, 이것은 protease의 경우 가수분해 할 수 있는 특정 peptide 혹은 amino acid가 있는데 각각의 protease가 분해하지 못하는 peptide 혹은 amino acid를 서로 분해해줌으로써 상승효과가 나타난 것으로 생각된다. 효소처리를 하여 얻어진 단백질의 사이즈를 알아보기 위해 SDS PAGE를 한 결과 어떠한 밴드도 형성이 되지 않았고 이는 분해된 단백질이 marker의 최소 사이즈인 15 kDa보다 작기때문인 것으로 생각된다. 따라서 일반 단백질보다 사이즈가 작은 polypeptide나 amino acid로써 분해된 것을 뜻하고 실제로 섭취하였을 때는 신체에서 생성되는 단백질 분해효소인 trypsin이나 chymotrypsin의 분해 없이도 쉽게 흡수 할 수 있을 것이라 판단된다. 또한 효소의 종류가 많을수록 총 아미노산의 함량이 높아짐으로써 식품첨가물로써 활용도가 높은 단백질가수분해물로 분해되었음을 확인할 수 있었다.

• 한국식품과학회지
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• 제29권2호
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• pp.383-386
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• 1997

아밀로오스 함량이 다른 옥수수 전분을 고압 가열-냉각 사이클을 4회까지 반복한 후, 효소 중량법과 ${\alpha}-amylase$ 처리로 효소저항전분을 분리하여 그 수율을 비교하였다. 분리방법에 상관없이 아밀로오스 함량이 높을수록 효소저항전분의 수율이 증가하였고, 가열-냉각 횟수를 증가시키면 효소저항전분의 수율도 증가하였다. 효소저항전분의 분리는 효소 중량법이 ${\alpha}-amylase$ 처리로 효소저항전분을 분리할 때보다 순도가 높았다.

• Mass Spectrometry Letters
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• 제5권2호
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• pp.57-61
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• 2014

A gravimetric standard addition method combined with internal standard calibration has been successfully developed for the accurate analysis of total arsenic in a laver candidate reference material. A model equation for the gravimetric standard addition approach using an internal standard was derived to determine arsenic content in samples. Handlings of samples, As standard and internal standard were carried out gravimetrically to avoid larger uncertainty and variability involved in the volumetric preparation. Germanium was selected as the internal standard because of its close mass to the arsenic to minimize mass-dependent bias in mass spectrometer. The ion signal ratios of $^{75}As^+$ to $^{72}Ge^+$ (or $^{73}Ge^+$) were measured in high resolution mode ($R{\geq}10,000$) to separate potential isobaric interferences by high resolution ICP/MS. For method validation, the developed method was applied to the analysis of arsenic content in the NMIJ 7402-a codfish certified reference material (CRM) and the result was $37.07mg{\cdot}kg^{-1}{\pm}0.45mg{\cdot}kg^{-1}$ which is in good agreement with the certified value, $36.7mg{\cdot}kg^{-1}{\pm}1.8mg{\cdot}kg^{-1}$. Finally, the certified value of the total arsenic in the candidate laver CRM was determined to be $47.15mg{\cdot}kg^{-1}{\pm}1.32mg{\cdot}kg^{-1}$ (k = 2.8 for 95% confidence level) which is an excellent result for arsenic measurement with only 2.8 % of relative expanded uncertainty.

• 대한토목학회논문집
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• 제28권5D호
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• pp.741-747
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• 2008

오늘날 미국, 일본과 같은 선진국에서는 전통적인 방법의 중력지오이드에 GPS/Leveling데이터에 의한 기하학적 지오이드를 합성한 합성지오이드를 개발하여 지오이드모델의 정확도를 높이고 있다. 따라서 하이브리드지오이드라 불리우는 합성지오이드모델을 개발하는 것이 세계적으로 지오이드모델 개발의 최신 방법이 되고 있다. 본 연구에서는 우리나라의 하이브리드지오이드 모델을 개발하기 위한 기초연구로 Remove and restore 방법에 의하여 중력지오이드를 결정하고 498점의 GPS/Leveling 데이터에 의한 기하학적 지오이드를 합성하여 우리나라의 합성지오이드모델을 개발하였다. 지구중력장모델은 EIGEN-CG03C 모델을 사용하였고 중력자료와 우리나라의 DEM을 이용하여 중력지오이드 모델을 개발하였다. 지형효과 계산을 위하여 3가지의 중력학적 환산방법(Helmert 응축 방법, RTM 방법, Airy-isostatic 방법)을 이용하여 지형효과를 산출하였고, 산출된 지형효과를 적용하여 개발되는 중력지오이드의 정확도를 분석하여 가장 적합한 중력학적 환산방법을 결정하였다. 아울러 산출된 중력지오이드에 총 498개의 GPS/Leveling 자료를 이용한 LSC 적합을 수행하여 우리나라의 수직기준에 적합한 합성지오이드를 결정하고 정확도 분석을 수행하였으며, 그 결과 RTM 환산방법을 적용하여 결정된 합성지오이드의 정확도가 $0.001{\pm}0.053m$로서 가장 높게 나타났음을 알 수 있었다.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 하계학술발표대회 논문집
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• pp.1042-1046
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• 2008

Both the weighing bridge and the diverter system is a important component in achieving a high accuracy liquid flow rate standard using a static gravimetric method. The weighing bridge is a tank which weighing collected flow with a load cells. The diverter is a moving device used to direct flow alternately along its normal course(by pass) or towards the weighing tank. The time needed for collection into the weighing tank is measured using a timer. So it is important to the diversion period is sufficiently fast and triggering point of timer which is determined the filling time. On this studies show that the measurement deviation of load cell and uncertainty of diverter system for changing diversion speed and triggering point was estimated in accordance with Guide to The Expression of Uncertainty in Measurement(ISO).

• 한국유체기계학회 논문집
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• 제20권1호
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• pp.59-64
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• 2017

Diverter is an essential element in gravimetric calibration method of flowmeter. Error of diverter are influenced by flow velocity profile of nozzle outlet, motion velocity of diverter and detecting location. That's why, time detection position of diverter is tuned through repetitive test for minimizing error of diverter. Further the diverter must be compared with the other institutions test since the influence on the accuracy of the flow meter used in the test. In this paper, errors (flow velocity profile of nozzle outlet, motion velocity of diverter and detecting location) of diverter are decreased by produced uni-direction diverter and error of gravimetric calibration system is decreased. Uni-direction diverter is calibrated by gravimetric calibration system with precision flowmeter, the flowmeter is calibrated by pipe prover and other institutions and uni-direction diverter is evaluated. Uni-direction diverter is not influenced by flow velocity profile of nozzle outlet, motion velocity of diverter and detecting location. As a result, Uni-direction diverter can calibrate in wider scope since increasing ratio of maximum and minimum flow rate of uni-direction diverter.