• Title/Summary/Keyword: Heavymetal

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Electrochemical Precipitation Treatment of Copper from an Heavymetal Wastewater (중금속폐수에서 구리의 전기화학적 침전처리)

  • 김재우;이재동;이우식;지은상
    • Journal of Environmental Health Sciences
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    • v.23 no.3
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    • pp.1-6
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    • 1997
  • This research was conducted in the laboratory to investigate an alternative of Copper(Cu) removal from an heavymetal wastewater using the electrochemical precipitation(ECP) process. The ECP unit consisted of an electrolytic cell made of Titanium plate and Steel plate representing anode and cathode. The DC power source applied to the ECP unit had electrical potential(E) of 50$\pm$ 1V, respectively. The synthetic wastewater used in the experiments contained Cu in the 10 mg/l concentration and the electrode separation were 2, 3, 4 cm and the initial pH were 3, 6, 9, 12, and electrolytic concentration were 0.005, 0.0125, 0.025, 0.0375 mole, and the real heavymetal wastewater used in the experiments. From the experiment for removal efficiency according to pH variation, the low pH area doesn't give the coagulation effect by Ti(OH)$_4$ because process interfere with the coagulation and oxidation reaction, therefore the optimum pH was 4-7. The removal rate was 97.75% after the lapse of 30 minutes when copper concentration and electrolytic concentration were respectively 10 mg/l and 0.025 mole. The removal rate was 96.41% after the lapse of 30minutes when the real heavymetal wastewater used. The optimum consumption of power showed 27KWh/m$^3$ when copper concentration, electrolyte concentration and cell potential were respectively 10 mg/l, 0.025 mole and 50$\pm$ 1 Volt.

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Heavy-Metal Adsorption by Recombinant Saccharomyces cerevisiae Harboring Multiple Copies of the CUP1 Gene (구리흡착 단백질 유전자를 함유하는 재조합 효모의 중금속 흡착)

  • 서진호;박상옥;김명동;한기철;전영석;안장우;한남수
    • KSBB Journal
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    • v.17 no.1
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    • pp.38-43
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    • 2002
  • Characteristics of cell growth and heavymetal adsorption by recombinant Saccharomyus cerevisiae strains harboring multiple copies of the CUP1 gene encoding metallothione (MT) protein were studied in batch cultures. Recombinant S. cerevisiae strains harboring multiple copies of the CUP1 gene were superior to the host and wild-type yeast strains in terms of cell growth and heavy metal removal, indicating that the copy number of the CUP1 gene for MT expression played an important role in the adsorption of heavy metals. It was suggested that the CUP1 promoter for the MT expression is induced by manganese and zinc as well as copper An optimum copper concentration for MT expression and concomitant adsorption of heavy metals by recombinant S. cerevisiae was found to be 0.31 mM. A nonionic surfactant Triton X-100 enhanced cell growth by 17.7% and removal of zinc by 6.1% compared with the control case.

An Assessment of the Heavy Metal Contamination of Sediment in Main Stream and Tributaries of the Han River in the Vicinity of Seoul (서울시 인근의 한강 본류 및 지류에 대한 하상 저질의 중금속오염 평가)

  • 노수미;이홍근
    • Journal of Environmental Health Sciences
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    • v.20 no.4
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    • pp.17-35
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    • 1994
  • This study was performed to investigate and assess the heavy metal contamination of sediment in main stream and tributaries of the Han-river in the vicinity of Seoul. Sediment were sampled at eight locations of main stream and eighteen locations of tributaries in the spring, summer, and fall in 1993. Six heavy metals of Cd, Cu, Pb, Zn, Cr, and Hg, were assessed. For an assessment of heavy metal contamination in sediment, the assessment method of Hakanson was modified to estimate for Han-river, then classification method of Muller in sediment quality was applied. For an assessment of contamination in each heavy metal, Contamination factor C$_f^i$ which was defined the ratio of concentration of i heavy metal in investigated location to background concentration of i heavy metal in uncontaminated upper area was used. The sediment quality in each heavymetal was classified as follows if C$_f^i$<1, Class I for Non contamination, if 1 < C$_f^i$ < 3, Class II for Low contamination, if 3< C$_f^i$ <6, Class III for Moderate contamination, if 6< C$_f^i$ <12, Class IV for Considerable contamination, and if C$_f^i$ > 12, Class V for High contamination.(abbreviation)

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Pollution Level of Heavy Metals of Asian Dust in Daejeon Area, 2008 (2008년 대전지역에서 발생한 황사의 중금속 오염도)

  • Lee, Pyeong-Koo;Bae, Beob-Geun
    • Journal of Soil and Groundwater Environment
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    • v.19 no.1
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    • pp.8-25
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    • 2014
  • The aims of this study were to determine concentrations of selected metals in Asian and non-Asian dust collected in Daejeon, Korea between February 2008 and December 2008 and to estimate the pollution level. The geochemical analyses of Asian dust (AD) and Non Asian dust (NAD) show that the mean concentrations of As, Cd, Cu, Pb, Zn, Zr, Sb, Mo and S reached levels up to 16, 209, 31, 43, 81, 28, 31, 122 and 302 times higher, respectively, than those in uncontaminated Chinese desert soils. These results indicate that both AD and NAD serve as an atmospheric repository for trace and heavymetal accumulation. The the enrichment factor (EF) and pollution index (PI) show that AD and NAD were severely contaminated by S, Mo, Zr, Cd, Pb, Zn, Sb, Cu, and As. All indices for these metals showed either strong or notably high level of pollution relative to Chinese desert soil, principally due to the severe atmospheric pollution derived from anthropogenic activities in heavily industrial Chinese cities. Therefore, Mo, Cd, Zr, As, Cu, Sb, Pb, and Zn are the ones most strongly affected by anthropogenic inputs such as airborne pollutants.

Pilot-test for the Restoratoin of Contaminated Farmland using Industrial By-products (산업부산물을 이용한 오염농경지 복원을 위한 현장실증시험 적용)

  • Yu, Chan;Baek, Seung-Hwan;Yun, Sung-Wook;Park, Jin-Chul;Lee, Jung-Hoon;Lim, Young-Cheol;Choi, Seung-Jin;Jang, Min
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.914-919
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    • 2008
  • This present was carried out to evaluate the adaptability of stabilization method which was used industrial byproducts as the stabilization agency in the abandoned mine site. In order to investigate stabilization effect on As-contaminated soils treated by industrial by-products, batch tests and column tests were carried out with As-contaminated soils collected from farmland around the abandoned mine site. ZVI(zero valent iron) and SRS(steel refining slag) was shown a good treatment effect. After the column test, sequential extraction test and simple bioavailability extraction test(SBET) were carried out to analysis of the soil, and scanning electron micrograph(SEM) analysis was carried out to compare the morphology and structure of ZVI and SRS before and after reacting with arsenic in the soil. As a result, ZVI and SRS were shown 93%, 62% reduction of As concentration respectively by comparison with untreated soils. Therefore, if ZVI and SRS are used as treatment materials in As-contaminated soils, it is expected that the As leaching from soils is reduced effectively.

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Investigation of Stabilization Effect on Arsenic Contamination Soils using Zerovalent Iron and Industrial by-products (영가철 및 산업폐기물을 활용한 비소오염토양의 안정화 효과조사)

  • Yu, Chan;Yun, Sung-Wook;Baek, Seung-Hwan;Park, Jin-Chul;Lee, Jung-Hoon;Lim, Young-Cheol;Choi, Seung-Jin;Jang, Min
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.229-241
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    • 2008
  • In order to investigate stabilization effect on As-contaminated soils treated by zero-valent iron(ZVI) and industrial by-products, batch tests and column tests were carried out with As-contaminated soils collected from farmland around the abandoned mine site. In batch tests, ZVI and industrial by-products(blast furnace slag, steel refining slag and oyster shell powder) were used as treatment materials to reduce As. Industrial by-products were mixed with As-contaminated soils, in the ratio of 1%, 3%, 5% and 7% on the weight base of dried soil. After incubation, all samples showed the reduction of As concentration and it was expected that ZVI and steel refining slag were effective treatment materials to remove As among treatment materials used in batch test. In column tests, columns were made by acrylic with the dimension of diameter=10cm, height=100cm, thickness=1cm and these columns were filled with untreated soils and treated soils mixed with ZVI and steel refining slag(mixing ratio=3%). Distilled water was discharged into the columns with the velocity of 1 pore-volume/day. During test, pH, EC, Eh and As concentration were measured in the regular term(1 pore-volume). As a result, ZVI and steel refining slag were shown 93%, 62% reduction of As concentration respectively by comparison with untreated soils. Therefore, if ZVI and steel refining slag are used as treatment materials in As-contaminated soils, it is expected that the As concentration in soils is reduced effectively.

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Ethanol Production from Red, Brown and Green Seaweeds and Biosorption of Heavy Metals by Waste Seaweed Slurry from Ethanol Production (홍조류, 갈조류, 녹조류를 이용한 바이오에탄올 생산 및 폐 해조류 슬러리의 중금속 생물흡착)

  • Sunwoo, InYung;Ra, ChaeHun;Kwon, SeongJin;Heo, JiHee;Kim, Ye-Jin;Kim, JiWoo;Shin, JiHo;Ahn, En-Ju;Cho, YuKyeong;Kim, Sung-Koo
    • KSBB Journal
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    • v.29 no.6
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    • pp.414-420
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    • 2014
  • The seaweeds with high carbohydrate ratio Gelidium amansii, Saccharina japonica and Enteromorpha intestinalis were used as red, brown, and green seaweeds, respectively. Thermal acid hydrolysis, enzymatic saccharification and fermentation were carried out using those seaweeds to produce ethanol. The ethanol concentrations from red, brown and green seaweed were 14.8 g/L, 11.6 g/L and 9.9 g/L, respectively. After the production of ethanol, the seaweeds were reused to absorb heavy metal. The maximum biosorption ratio was Cu(II) (89.6%), Cr(III) (82.9%), Ni(II) (66.1%). Cu(II) had the highest affinity with 3 waste seaweeds. Red seaweed was verified the most effective substrates to both process.