• Journal of the Korean Crystal Growth and Crystal Technology
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• v.12 no.3
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• pp.115-119
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• 2002

An adsorption isotherm on the heterogeneous surface which has spatially periodic adsorption heat distribution was formalized. Usefulness of the formalized adsorption isotherm is discussed with the help of a model calculation. Statistical thermodynamics is used throughout.

• Atmosphere
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• v.25 no.2
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• pp.193-203
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• 2015

A large aperture scintillometer (LAS) was deployed with an optical path length of 2.1 km to estimate turbulent sensible heat flux (${\mathcal{Q}}_H$) over a highly heterogeneous urban area. Scintillation measurements were conducted during cold season in November and December 2013, and the daytime data of 14 days were used in the analysis after quality control processes. The LAS-derived ${\mathcal{Q}}_H$ show reasonable temporal variation ranging $20{\sim}160W\;m^{-2}$ in unstable atmospheric conditions, and well compare with the measured net radiation. The LAS footprint analysis suggests that ${\mathcal{Q}}_H$ can be relatively high when the newly built-up urban area has high source contribution of the turbulent flux in the study area ('northwesterly winds'). Sensitivity tests show that the LAS-derived ${\mathcal{Q}}_H$ are highly sensitive to non-dimensional similarity function for temperature structure function parameter, but relatively less sensitive to surface aerodynamic parameters and meteorological variables (temperature and wind speed). A lower Bowen ratio also has a significant influence on the flux estimation. Overall uncertainty of the estimated daytime ${\mathcal{Q}}_H$ is expected within about 20% at an upper limit for the analysis data. It is also found that stable atmospheric conditions can be poorly determined when the scintillometry technique is applied over the highly heterogeneous urban area.

• Textile Coloration and Finishing
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• v.35 no.4
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• pp.214-220
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• 2023

Poly(vinyl alcohol) (PVA) is a common hydrophilic polymer that is synthesized through the saponification reaction of poly(vinyl ester)-based polymers, mostly using poly(vinyl acetate) (PVAc) as a precursor. The heterogeneous saponification reaction of poly(vinyl ester)-based films leads to PVA films with new surface properties. Cellulose acetate (CA), in which the hydroxyl group of cellulose is replaced by an acetyl group, is a typical cellulose derivative capable of overcoming the low processability of cellulose due to strong hydrogen bonding. In this study, P(VAc/VPi)/CA blended films were prepared by the solvent casting, and then PVA/Cellulose blended films with improved surface properties were prepared by heterogeneous saponification. The structural changes caused by heterogeneous saponification were confirmed by FT-IR analysis, where both saponification and deacetylation reactions occurred in the saponification solution. In addition, the surface property changes were analyzed by FE-SEM and contact angle analyses, and the transmittance changes of the modified films were also assessed.

• Proceedings of the KIEE Conference
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• 2001.11a
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• pp.288-289
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• 2001

흡착열공간분포를 외형적으로 포함하는 Heterogeneous 표면상의 흡착등온식을 형식화한다 그리고 흡착열공간분포는 위치에 대한 주기함수로서 주어지는 것임을 논한다. 본 논문에서 얻어진 결과를 재료의 박막형성 문제에 결부시켜 논의한다.

• Bulletin of the Korean Chemical Society
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• v.31 no.6
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• pp.1711-1714
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• 2010

• 한국연소학회:학술대회논문집
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• 2000.05a
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• pp.152-161
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• 2000

The catalytically stabilized combustion of $CH_4$-air mixture on platinum catalyst was investigated numerically using a 2-D boundary layer model with detailed heterogeneous and homogeneous chemistries. The actual surface site density of monolith coated with platinum was decided by the comparison with experimental data. The comparisons were made between results for cases where only heterogeneous chemistry was allowed and both heterogeneous and homogeneous chemistries were allowed. It was found that the homogeneous reaction in the monolith had little effect on the change of temperature profile, methane conversion rate and light off location. The contributions of each reactions related with CO formation were discussed on the surface. The effects of operation conditions such as equivalence ratio, temperature, velocity and pressure at the entrance were studied. In thermal combustor, CO and NOx was produced less than 1 ppm at the exit and the production of $N_{2}O$ was more dominant than that of NO.

• Macromolecular Research
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• v.14 no.2
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• pp.230-234
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• 2006

• Journal of the Korean Ceramic Society
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• v.32 no.8
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• pp.909-914
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• 1995

From alumina powder and TEOS, $\alpha$-Al2O3/SiO2 composite powder for reaction-sintered mullite was synthesized by heterogeneous coagulation and surface coating, and investigated the mullitization reaction and sintering behavor of these powders. In $\alpha$-Al2O3/SiO2 composite powder prepared by heterogeneous coagulation, each alumina particles were surrounded by silica particles of 50~60 nm in size. And the alumina particles in composite powder prepared by surface coating were coated by uniform silica layer with thickness of 50 nm. In both methods, mullitization reaction was completed at 1$650^{\circ}C$ for 3h, and specimen sintered above 145$0^{\circ}C$ was about 95% fo the theoretical relative density. Mullite grains formed from the reaction with composite powders showed spherical shape with a size of 1~2${\mu}{\textrm}{m}$.

• Geomechanics and Engineering
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• v.16 no.2
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• pp.169-176
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• 2018

An attempt has been made here to study the propagation of SH-type surface waves in an elastic medium, which is initially stressed and heterogeneous and has a point source inside the medium. The upper portion of the composite medium is a sandy layer. It is situated on an initially stressed heterogeneous half-space, whose density, rigidity and internal friction are function of depth. The analysis has been carried out by using Fourier transform and Green's function approach. The phase velocity has been investigated for several particular situations. It has been shown that the results of the study agree with those the case of Love wave propagation in a homogeneous medium in the absence of the sandy layer, when the initial stress is absent. In order to illustrate the validity of the analysis presented here, the derived analytical expression has been computed numerically, by considering an illustrative example and the variances of the concerned physical variables have been presented graphically. It is observed that the velocity of shear wave is amply influenced by the initial stress and heterogeneity parameters and the presence of the sandy layer. The study has an important bearing on investigations of different problems in the earth's interior and also in seismological studies.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.13 no.3
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• pp.119-125
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• 2004

Generally, it is used the compensation spring to compensate the inaccuracy of screen image induced by thermal deformation in CRT monitor. Its mechanism is bi-metallic system made of heterogeneous metals and these is bonded by laser welding. But laser welding induces the non-uniform temperature distribution and locally residual stress is yielded by these temperature deviation. This paper studies residual stress of laser weldment using FEA and hole drilling method. The results are followed. In the case of heterogeneous materials weldment, higher residual stress induced in the weldment region of SUS 304 which have larger CTE than Ni 36 and residual stress on the middle of specimen is higher by 10.9% than that of its surface Measured residual stress of SUS 304 yield 481MPa and that of Ni 36 is 140.5MPa in the vicinity of the welding region. And the residual distribution is very similar in comparison with FEA result.