• Title/Summary/Keyword: High efficiency negative electrode

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Effect of KHCO3 Concentration Using CuO Nanowire for Electrochemical CO2 Reduction Reaction

  • Kanase, Rohini Subhash;Kang, Soon Hyung
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.11-17
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    • 2020
  • Copper has been proved to be the best catalyst for electrochemical CO2 reduction reaction, however, for optimal efficiency and selectivity, its performance requires improvements. Electrochemical CO2 reduction reaction (RR) using CuO nanowire electrode was performed with different concentrations of KHCO3 electrolyte (0.1 M, 0.5 M, and 1 M). Cu(OH)2 was formed on Cu foil, followed by thermal-treatment at 200℃ under the air atmosphere for 2 hrs to transform it to the crystalline phase of CuO. We evaluated the effects of different KHCO3 electrolyte concentrations on electrochemical CO2 reduction reaction (RR) using the CuO nanowire electrode. At a constant current (5mA), low concentrated bicarbonate exhibited a more negative potential -0.77 V vs. Reversible Hydrogen Electrode (RHE) (briefly abbreviated as VRHE), while the negative potential reduced to -0.33 VRHE in the high concentration of bicarbonate solution. Production of H2 and CH4 increased with an increased concentration of electrolyte (KHCO3). CH4 production efficiency was high at low negative potential whereas HCOOH was not influenced by bicarbonate concentration. Our study provides insights into efficient, economically viable, and sustainable methods of mitigating the harmful environmental effects of CO2 emission.

Removal of Dust in Positive and Negative Plates of Electrode Coated with Activated Carbon (활성탄으로 코팅된 전극에서 분진의 제거)

  • Kim, Kwang Soo;Park, Hyun Chul;Jun, Tae Hwan;Lee, Ju Haeng;Nam, Sang Chul
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.6
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    • pp.830-837
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    • 2013
  • The purposes of this research are to know the dust removal efficiency according to the changes of gab between positive and negative plates in dust removal chamber. The experiments for dust removal efficiencies were conducted with changing the electrode-plate gab from 2 cm to 1 cm while the electric pressure, influent flow, and linear velocity were kept 5 kV, 80 L/min, and 6 cm/sec, respectively. From the experimental results of the electrode-plate gab of 2 cm, dust removal efficiencies were decreased to as low as about 50%. Attached dust on the surface of electrodes was released due to a reverse electric charge of dust. From the experimental results of the electrode-plate gab of 1 cm, dust removal efficiencies were increased to as high as about 80% due to the dust attachment velocity to the electrodes to be far more fast than influent linear velocity. Finally, to protect a attached dust from occurring a reverse electric charge it is needed to install the non-conductor between positive and negative electrodes and also to remove air humidity.

Improvement of Electrochemical Performance of KVO3 as High Capacity Negative Electrode Material for Lithium-ion Batteries (리튬이온 이차전지용 고용량 KVO3 음극의 전기화학적 성능개선)

  • Kim, Tae Hun;Gim, Gyeong Rae;Park, Hwandong;Kim, Haebeen;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.22 no.4
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    • pp.148-154
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    • 2019
  • Vanadium oxide based materials have been studied as novel negative electrode materials in lithium-ion batteries (LIBs) because of their high specific capacity. In this study, potassium metavanadate ($KVO_3$) was synthesized and its electrochemical properties are evaluated as a negative electrode materials. The aqueous solution of $NH_4VO_3$ is mixed with a stoichiometric amount of KOH. The solution is boiled to remove $NH_3$ gas and dried to obtain a precipitate. The obtained $KVO_3$ powders are heat-treated at 300 and $500^{\circ}C$ for 8 h in air. As the heat treatment temperature increases, the initial reversible capacity decreases, but the cycle performance and Coulombic efficiency are improved slightly. On the contrary, the electrochemical performances of the $KVO_3$ electrodes are greatly improved when a polyacrylic acid (PAA) as binder was used instead of polyvinylidene fluoride (PVDF) and a fluoroethylene carbonate (FEC) was used as electrolyte additive. The initial reversible capacity of the $KVO_3$ is 1169 mAh/g and the Coulombic efficiency is improved to 76.3% with moderate cycle performance. The $KVO_3$ has the potential as a novel high-capacity negative electrode materials.

Cell Gap Dependent Electrode-Optic Characteristics of Fringe-Field Switching Mode using a Liquid Crystal with Negative Dielectric Anisotropy (유전율 이방성의 음인 액정을 이용한 Fringe-Field Switching mode의 cell gap 변화에 따른 전기광학 특성)

  • 정송희;김향율;이종문;이승희
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.10
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    • pp.914-922
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    • 2003
  • The FFS (fringe-field switching) mode was known to exhibit both a wide viewing angle and high transmittance, especially when using a liquid crystal with negative dielectric anisotropy. We have studied cell gap-dependent electrode-optic characteristics of the FFS mode using the LC with negative dielectric anisotropy. In case of a small cell gap of 2 ${\mu}$m, the transmittance at the center of pixel and common electrodes is relatively low because effect of surface anchoring that holds the LC to the initial state is larger than that in a large cell gap of 4 .urn such that the LCs in those regions cannot rotate enough. However, in case of a large cell gap of 4 .urn, the effect of surface anchoring becomes relatively small so that the LCs at the center of pixel and common electrode can be twisted enough by applied voltage, giving rise to high transmittance. Therefore, we can conclude that the light efficiency is dependent on the cell gap.

Cell Gap Dependent Transmission Characteristic of the Fringe-Field Switching Mode in a LC with Negative Dielectric Anisotropy

  • Kim, H.Y.;Kim, J.M.;Song, S.H.;Lee, S.K.;Lim, Y.J.;Jung, S.H.;Lee, S.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.539-542
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    • 2003
  • We have studied cell gap-dependent electrode-optic characteristics of the FFS mode using the LC with negative dielectric anisotropy. In case of a small cell gap of 2 ${\mu}m$, the transmittance at the center of pixel and common electrodes is low due to stronger influence of surface anchoring that holds the LC to the initial state than twisting force induced by neighboring LCs. In case of a large cell gap of 4 ${\mu}m$, the influence of surface anchoring force becomes weak so that the LCs at the center of pixel and common electrode can be twisted enough by applied voltage, giving rise to high transmittance. Therefore, we conclude that the light efficiency in the device is dependent on the cell gap.

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High throughput sorting(HTS) system using a cantilever-type electrode array (캔틸레버(Cantilever) 형태의 전극 어레이(array)를 이용한고속 분리 시스템)

  • Lee, Jung-Hun;Kim, Young-Ho;Kim, Young-Geun;Kim, Byung-Kyu
    • Journal of Sensor Science and Technology
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    • v.19 no.2
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    • pp.112-117
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    • 2010
  • A high-throughput sorting (HTS) system has been designed to separate target particles using a negative dielectrophoretic (n-DEP) force. The system consists of a meso-sized channel and a cantilever-type electrode(CE) array designed to separate a large number of target particles by discerning subtle difference of weight and dielectric material property of the particles. Using the polystyrene beads with various sizes of 10, 25 and $50{\mu}m$, the developed system exhibits high-throughput sorting of about 200 beads/sec and more than 80 % of separation efficiency.

High Coulombic Efficiency Negative Electrode(SiO-Graphite) for Lithium Ion Secondary Battery (리튬이온이차전지용 고효율 음극(SiO-Graphite))

  • Shin, Hye-Min;Doh, Chil-Hoon;Kim, Dong-Hun;Kim, Hyo-Seok;Ha, Kyung-Hwa;Jin, Bong-Soo;Kim, Hyun-Soo;Moon, Seong-In;Kim, Ki-Won;Oh, Dae-Hui
    • Journal of the Korean Electrochemical Society
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    • v.11 no.1
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    • pp.47-50
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    • 2008
  • A new anode composition material comprising of SiO and Graphite has been prepared by adopting High energy ball milling (HEBM) technique. The anode material shows high initial charge and discharge capacity values of 1139 and 568 mAh/g, respectively. The electrode sustains reversible discharge capacity value of 719 mAh/g at 30th cycle with a high coulombic efficiency${\sim}99%$. Since the materials formed during initial charge process the nano silicon/$Li_4SiO_3$ and $Li_2O$ remains as interdependent, it may be expected that the composite exhibiting higher amount of irreversibility$(Li_2O)$ will deliver higher reversible capacity. In this study, constant current-constant voltage (CC-CV) charge method was employed in place of usual constant current (CC) method in order to convert efficiently all the SiO particles which resulted high initial discharge capacity at the first cycle. We improved considerably the initial discharge specific capacity of SiO/G composite by pretreatment(CC-CV).

Pretreatment of SiO/C Composite Anode of Lithium ion Secondary Battery for High coulombic Efficiency and High Specific Capacity (리튬이차전지용 산화실리콘-흑연 복합체 고효율 음극의 전처리 특성)

  • Shin, Hye-Min;Veluchamy, Angathevar;Kim, Dong-Hun;Chung, Young-Dong;Kim, Hyo-Seok;Doh, Chil-Hoon;Jin, Bong-Soo;Kim, Hyun-Soo;Moon, Seong-In;Kim, Ki-Won;Oh, Dae-Hui
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.43-44
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    • 2007
  • SiO and graphite composite has been prepared by adopting high energy ball milling technique. The anode material shows high initial discharge and charge capacity values of 1138 and 568 mAh/g, respectively. Since the materials formed during initial discharge process the nano silicon/$Li_4SiO_3\;and\;Li_2O$ remains as interdependent, it may be expected that the composite exhibiting higher amount of irreversible capacity$(Li_2O)$ will deliver higher reversible capacity. In this study, pretreatment method of constant current-constant voltage (CC-CV) Provided high coulombic efficiency of SiO/C composite electrode removing the greater part of irreversible capacity.

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Decomposition of Odorous Gases in a Pilot-scale Nonthermal Plasma Reactor

  • Hwang, Yoon-Ho;Jo, Young-Min
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.E2
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    • pp.57-65
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    • 2005
  • An experimental study was performed on the decomposition of gaseous ammonia and two selected volatile organic compounds (VOCs: toluene and acetone) in a combined nonthermal plasma reactor with corona and glow discharges. A lab pilot scale reactor (206 liter) equipped with a high electric power pack was used to determine the decomposition efficiency in relation with the inlet concentration and applied voltage. Three different types of discharging electrode such as wired rack, wire strings for corona discharge, and thin plate for glow discharge were put in order in the reactor. While decomposition of ammonia decreased with an increase in the initial concentration, acetone showed an opposite result. In the case of toluene however no explicit tendency was found in toluene and aceton. Negative discharge resulted in high decomposition efficiency than the positive one for all gases. A better removal of gas phase element could be achieved when fume dust were present simultaneously.

Deflective Behavior of Charged Particles in a Two-Stage Electrostatic Precipitator

  • Lim, Hun-Chan
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.7
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    • pp.83-91
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    • 2011
  • Even if smoke, fumes, mist or dust particles are removed by electrostatic precipitators (ESPs), the occurrence of ozone, which is harmful to human body, has to be severely restricted in the indoor environments of hospitals, offices, and workshops. Therefore, the two-stage ESP generating positive corona at the ionizer is typically used because it creates less ozone than the two-stage ESP generating negative corona at the ionizer. In order to predict the collection performance and the optimal design of the two-stage ESP applied to positive high-voltage, particle concentration is experimentally investigated in this paper. In addition, particle motion within the collector section is also numerically analyzed. The positive corona discharge current of the ionizer is found to be affected by the applied voltage in the collector section but less so by the particle concentration. Particle concentration shows a minimum near the high voltage electrode of the collector section. The minimum value of the collection efficiency is almost proportional to gas velocity. When the collector length decreases, the minimum value of the collection efficiency increases. Charged particles entering the collector region are linearly deflected towards the grounded plate by an electric field. From the above experimental and numerical results, two empirical equations on the concentration ratio and the collection efficiency are derived, and are in good agreement with the experimental data.