• 제목/요약/키워드: Hill reaction

검색결과 37건 처리시간 0.045초

경사지의 지형특성에 적합한 경사지주택 개발 계획 (Development of Hill Housing Addatable to the Topographic Characteristics on Sloping Sites)

  • 현택수
    • 한국농촌건축학회논문집
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    • 제14권1호
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    • pp.57-66
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    • 2012
  • This study focuses on the applicability of hill housing design in accordance with topographic characteristics on sloping sites. The urgency for housing still exists but hill sites have to be planned by gradual development using 'all available land' within any particular community. However, there is a reaction towards being more closely involved with nature and landscape. Sloping and hill sites must be developed by intelligent and sensitive planning, integrating the existing environmental factors. The results of this study are as follows : 1. The conditions of location are regarded as the concepts of spactial configuration. It should be developed on the basis of awareness that nature and human beings exist together. 2. It is inevitable that the development of the hill housing should be performed prefer to the topographic characteristics. 3. Planning elements of ecological residental blocks which are possible for constructing on the hill site can be developed and applied, on the basis of geographical characteristics, by housing types.

Kinetics of Oxidation of Nitrotoluenes by Acidic Hexacyanoferrate (Ⅲ)

  • Bhattacharjee, A. K.;Mahanti, M. K.
    • Bulletin of the Korean Chemical Society
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    • 제4권3호
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    • pp.120-123
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    • 1983
  • The reaction of hexacyanoferrate (Ⅲ) with nitrotoluenes in aqueous acetic acid containing perchloric acid(1.0 M) at $50^{\circ}C$ gave the corresponding aldehyde as the major product. The order with respect to each of the reactants ― substrate, oxidant and acid ― was found to be unity. The Hammett plot yielded a ${\sigma}^+$ value of -1.30, and the kinetic isotope effect gave a $k_H/k_D$ value of 6.2. The pathway for the conversion of the nitrotoluenes to the products has been mechanistically visualized as proceeding through the benzylic radical intermediate, formed in the rate determining step of the reaction.

신규(新規) 합성화합물들이 cyanobacteria의 광합성전자전달계에 미치는 영향 (The Effect of Newly Synthesized Compounds on the Photosynthetic Electron Transport of Cyanobacteria (Anacystis nidulans $R_2$))

  • 황인택;김진석;조광연;요네야마 코이치;요시다 시게오
    • 한국잡초학회지
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    • 제13권2호
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    • pp.89-95
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    • 1993
  • 광합성 전자전달저해제의 탐색을 위한 biorational screening 방법으로 광합성 박테리아의 일종인 cyanobacteria의 표준형(wild type)과 $D_1$ 단백질의 구성 아미노산이 변환된 변이주 Di-1, G-264. Di-22 등 4종을 사용하여 신규합성 화합물에 대한 광합성 전자전달저해활성을 조사하여 구조-활성간의 특성을 검토하였고, 이들의 thermoluminescence band를 이용하여 결합부위를 비교하였다. 1. Phenol 화합물(E-series)들은 cyanobacteria를 이용한 광합성 전자전달 저해활성의 양상을 볼 때 diuron보다는 dinoseb과 비슷하였다. 2. 합성한 Phenol화합물에서 나타난 구조활성간의 특정으로는 치환기의 phenyl ring에 C1이 치환되지 않은 경우 Hill반응 저해활성이 나타나지 않았고, 화합물에 있는 두개의 ring을 연결하는 bridge의 길이가 길어질수록 Hill반응 저해활성은 약하게 나타났다. 3. Triazine 화합물(T-series)의 경우 T-27, T-28화합물은 대조약제 atrazine보다 각각 10, 30배 강한 저해활성을 나타내었고, 변이주 G-264에 대 한 저항성 비율이 atrazine보다 더욱 크게 나타나 이들 화합물들의 결합부위가 $D_1$ 단백질의 264번 위치와 깊은 관계가 있을 것으로 생각되었다. 4. Triazine 화합물에 있어서 치환기 -C-NH-는 전자전달계에 중요한 작용기로 생각되었다. 5. Thermoluninescence band를 이용하여 결합부위를 비교할 수는 있었지만, 명료하게 구분되지 않았다.

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시금치 엽록체의 광계의 활성에 미치는 추출용매와 반응용액의 영향 (Effects of Different Extraction Extraction Media and Reaction Mixtures on Photosystem II Activity of Spinach Chloroplasts)

  • 권병규
    • Journal of Plant Biology
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    • 제19권4호
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    • pp.95-99
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    • 1976
  • This work deals with different extraction media and reaction mixtures on photosystem II activity of Spinach chloroplasts. The photoreduction rate of ferricyanide and DPIP by intact chloroplasts which extracted with four kinds of extraction media; S-Tris-N pH 7.2, 8.0, S-Tricine-N pH 7.2, 8.0, was measured in five kinds of reaction mixtures; S-Tris-N pH 7.2, 8.0, S-Tricine-N pH 7.2, 8.0, 0.05 M-Tris pH 7.2. The extraction medium which shows the highest photoreduction rate was S-Tris-N at pH 7.2 and S-Tricine-N at pH 8.0. As to the reaciton mixture, S-Tricine-N pH 8.0 showed the highest rate. On the complex effects of extraction media and reaction mixtures, the highest photordeuction rate of Hill oxidant by intact chloroplasts was obtained by S-Tris-N pH 7.2 extraction medium and S-Tricine-N pH 8.0 reaction mixture. The second highest activity was obtained by S-Tricine-N pH 8.0 extraction medium and reaction mixture.

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전자렌지 반응을 이용한 인삼 사포닌의 신속한 가수분해법 (Rapid Hydrolysis of Ginseng Saponin by Microwave Oven Reaction)

  • Park, Man-Ki;Park, Jeong-Hill;Kang, Jong-Seong;Lee, Mi-Young;Park, Young-In;Yu, Su-Jeong;Han, Byung-Hoon
    • Journal of Ginseng Research
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    • 제17권1호
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    • pp.35-38
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    • 1993
  • A new and rapid method for the hydrolysis of ginsenosides to panaxadiol or panaxatriol was developed. It is based on the microwave oven reaction, which is high temperature and high-pressure reaction. The optimal hydrolysis time using 5% $H_2SO_4$ solution was found at 10 min PTFE reaction vessel in microwave oven, which is more than 30 times faster than the conventional hydrolysis method.

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Cyanobacteria를 이용한 광합성 전자전달저해제의 생합리적 스크리닝 (Biorational Screening System Using Cyanobacteria(Anacystis nidulans $R_2$) for Searching the Photosynthetic Electron Transport Inhibitors)

  • 황인택;홍경식;조광연;요시다 시게오
    • 한국잡초학회지
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    • 제13권2호
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    • pp.81-88
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    • 1993
  • 광합성 전자전달저해제의 탐색을 위한 biorational biorational screening 방법으로 광합성 박테리아의 일종인 cyanobacteria의 표준형과 $D_1$단백질의 구성 아미노산이 변환된 변이주 Di-1, G-264, Di-22, TRY-5를 사용하여 기존 약제의 혼합효과와 몇가지 합성화합물의 Hill반응 저해활성을 측정 조사하였고, 또한 시금치로 부터 분리한 chloroplast와 cyanobacteria로 부터 분리한 thylakoid membrane에 대한 기존 제초제의 반응성을 조사하였다. 1. 광합성억제형 제초제에 대한 반응성 비교에서 cyanobacteria로 부터 분리한 thylakoid membrane이 시금치로 부터 분리한 chloroplast보다 약제에 대하여 민감한 반응을 나타내어 광합성 전자전달저해제의 탐색을 위한 재료로 보다 적합하였다. 2. Diuron에 대하여 wild type보다 Di-22와 D-5 변이주는 각각 약 2,000배와 800배의 저항성을 나타내었고 atrazine에 대하여는 G-264 변이주만이 약 1,000배의 저항성을 나타내었으며, 기타 네 약제에 대하여는 뚜렷한 저항성을 나타내는 변이주가 없었다. 3. D1 단백절의 264번 위치의 serine이 다른 아미노산으로 치환된 Di-1과 D-22 및 G-264 변이주에 대한 diuron과 atrazine의 혼합처리 효과를 검토한 결과 상호 경합적으로 작용하였으며 그 정도는 G-264 변이주에 대해서 가장 뚜렷하게 나타났다. 그러나 diurone과 atrazine의 혼합처리에 의한 thermoluminescence band의 변화는 인정할 수 없었다. 4. 변이주 Di-1과 D-22는 dinoseb에 대해서 저항성을 나타내지 않았으나. dinoseb과 diuron의 혼합처리시 diuron에 대한 저항성이 크게 약화되었다.

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정지홈과 회전홈을 갖는 저널베어링의 안정성 평가 (Stability analysis of the rotating and stationary grooved journal bearings)

  • 이민호;이지훈;장건희
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2013년도 춘계학술대회 논문집
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    • pp.141-146
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    • 2013
  • This research investigates the stability analysis for the rotating and the stationary grooved journal bearing. The dynamic coefficients of the journal bearing are calculated by using FEM and the perturbation method. When journal bearing is in whirling motion, the dynamic coefficients have time-varying components as a sine wave due to the reaction force of oil film toward the center of journal even in the steady state. The solutions for the equations of motion can be assumed as the Fourier series expansion. The equations of motion can be rewritten as the linear algebraic equations with respect to the Fourier coefficients. Then, stability of the grooved journal bearing can be calculated by Hill's infinite determinant. The periodic function of dynamic coefficients is derived using Fourier Fast Transform(FFT).The stability of journal bearing is determined as rotating speed increases and the stability of rotating grooved journal bearing is compared and discussed with the stability of stationary grooved journal bearing.

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Chemical and Free Radical-scavenging Activity Changes of Ginsenoside Re by Maillard Reaction and Its Possible Use as a Renoprotective Agent

  • Yamabe, Noriko;Song, Kyung-Il;Lee, Woo-Jung;Han, Im-Ho;Lee, Ji-Hwan;Ham, Jung-Yeob;Kim, Su-Nam;Park, Jeong-Hill;Kang, Ki-Sung
    • Journal of Ginseng Research
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    • 제36권3호
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    • pp.256-262
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    • 2012
  • Reactive oxygen species play critical role in kidney damage. Free radical-scavenging activities of Panax ginseng are known to be increased by heat-processing. The structural change of ginsenoside and the generation of Maillard reaction products (MRPs) are closely related to the increased free radical-scavenging activities. In the present study, we have demonstrated the Maillard reaction model experiment using ginsenoside Re and glycine mixture to identify the renoprotective effect of MRPs from ginseng or ginsenosides. Ginsenoside Re was transformed into less-polar ginsenosides, namely Rg2, Rg6 and F4 by heat-processing. The free radical-scavenging activity of ginsenoside Re-glycine mixture was increased in a temperature-dependant manner by heatprocessing. The improved free radical-scavenging activity by heat-processing was mediated by the generation of antioxidant MRPs which led to the protection of LLC-PK1 renal epithelial cells from oxidative stress. Although the free radical scavenging activities of less-polar ginsenosides were weak, they could protect LLC-PK1 cells from oxidative stress. Therefore, MRPs and less-polar ginsenosides contributed to the combined renoprotective effects against oxidative renal damage.

대두 Trypsin Inhibitor의 간이검정법 (A Simple Method for Detection of Trypsin Inhibitors in Soybean (Glycine max))

  • 조구형;이춘영;홍종욱;김인수
    • 한국식품과학회지
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    • 제18권5호
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    • pp.339-344
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    • 1986
  • Trypsin inhibitor가 trypsin과 안정한 복합체를 형성하고 동시에 일반 단백질은 trypsin에 의하여 가수분해 되는 원리를 이용하여 trypsin inhibitor를 용이하게 검정 할 수 있는 방법을 고안하였다. trypsin으로 가수분해 시킨 대두추출액을 Sephadex G-50을 이용하여 trypsin-trypsin inhibitor 복합체를 분리시킨 후에 SDS 전기 영동으로 trypsin inhibitor를 복합체를 분리시킨 후에 SDS 전기 영동으로 trypsin inhibitor를 검정할 수 있었다. 이들 trypsin inhibitor는 trypsin에 의한 2차 가수분해에서도 가수분해 되지 않았으며, 또한 2차원 전기영동과 DEAE-Sephades A-25크로마토 그래피를 이용하여 trypsin inhibitor가 trypsin과 복합체를 형성하는 능력을 검정함으로써 본 방법의 유효성을 확인하였다. 본 실험 방법으로 대두(Hill 품종)의 trypsin inhibitor를 검정한 결과 7개의 trypsin inhibitor를 찾아 낼 수 있었다.

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