• Journal of Microbiology and Biotechnology
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• v.29 no.2
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• pp.283-291
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• 2019

Fermentation of food waste in the presence of different concentrations of salt ($Na^+$) and ammonia was conducted to investigate the interrelation of $Na^+$ and ammonia content in bio-hydrogen production. Analysis of the experimental results showed that peak hydrogen production differed according to the ammonia and $Na^+$ concentration. The peak hydrogen production levels achieved were (97.60, 91.94, and 49.31) ml/g COD at (291.41, 768.75, and 1,037.89) mg-N/L of ammonia and (600, 1,000, and 4,000) $mg-Na^+/L$ of salt concentration, respectively. At peak hydrogen production, the ammonia concentration increased along with increasing salt concentration in the medium. This means that for peak hydrogen production, the C/N ratio decreased with increasing salt content in the medium. The butyrate/acetate (B/A) ratio was higher in proportion to the bio-hydrogen production (r-square: 0.71, p-value: 0.0006). Different concentrations of $Na^+$ and ammonia in the medium also produced diverse microbial communities. Klebsiella sp., Enterobacter sp., and Clostridium sp. were predominant with high bio-hydrogen production, while Lactococcus sp. was found with low bio-hydrogen production.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.5
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• pp.467-479
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• 2020

Various researches are being conducted to reduce greenhouse gases generated by the consumption of traditional energy resources. This study was conducted to numerically analyze the combustion characteristics and N-S reaction behavior with respect to the H₂ content of syngas composed of CO and H₂ in pressurized air combustion. A non-premixed opposed flow flame model was applied a modified detailed mechanism with S-chemistry was developed based on GRI 3.0 to simulate the syngas reaction. As the hydrogen content increased, the flame thickness increased due to the fast reactivity of hydrogen. In the rich region, NO and SO₂ were reduced by reaction with H radical and H bonding of NO was suppressed by the formation of HOSO.

• Journal of Welding and Joining
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• v.32 no.2
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• pp.18-21
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• 2014

Cold cracking of weldment is one of the most serious welding problems. A sufficient quantity of diffusible hydrogen, a residual stress, and a sensitive microstructure are the causes of cold cracking. Removal of any one of these factors can be used to prevent cold cracking. Application of flux cored arc welding process is increasing due to high productivity and easiness of welding. In addition, to prevent cold cracking in the HAZ or weldment, preheat temperature and interpass temperature have to be controlled. In this study, the effect of preheat temperature on the levels of diffusible hydrogen in the weld metal deposited using flux cored wire was examined. The levels of preheat temperature of base metal specimen were ambient temperature, 50, 100 and $150^{\circ}C$ respectively. The result showed that the increase of preheat temperature was a linear relationship with reduction of diffusible hydrogen content in weldment.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.6
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• pp.737-746
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• 2016

This article describes a comparison on laminar burning velocity measured by Bunsen and spherical flame methods of synthetic natural gas (SNG) with various composition of hydrogen. In this study, the laminar burning velocity measurements were employed by Bunsen burner and cylindrical constant combustor at which flame images were captured by Schlieren system. These results were also compared with numerical based on CHEMKIN package with GRI 3.0, USC-II and UC Sandiego mechanism. In case of spherical flames, the suitable flame radius range and theoretical models were verified using the well-known previous results in methane/air flames. As an experimental condition, hydrogen content of SNG was adjusted 0% to 11%. Equivalence ratios of Bunsen flames were adjusted from 0.8 to 1.6. On the other hand, those of spherical flames were adjusted from 0.6 to 1.4, relatively. From results of this study, the both laminar burning velocities measured in Bunsen and spherical flame methods were resulted in similar tendency. As the hydrogen content increased, the laminar burning velocity also increased collectively. Laminar burning velocity of measured SNG-air flames was best coincided with GRI 3.0 mechanism by comparison of reaction mechanisms.

• Journal of Welding and Joining
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• v.7 no.2
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• pp.49-59
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• 1989

The effect of non-metallic inclusions on the HAZ hydrogen induced cracking was investigated. Quench and temper high tensile strength steels containing various sulphur contents were employed. The sulphur contents range between 0.007% and 0.040%. Non-metallic inclusions were mainly MnS type sylphide and Mn-Al-Si type. The sensitivity of HAZ delayed cracking was evaluated by implant testing. Diffusible hydrogen content was varied by controlling the moisture absorbing condition of manual arc welding electrodes. The one was asreceived condition, the other was dipping the electrodes in the water for ten minutes. The main results obtained were as follows; 1) The results of implant test showed that critical stress increased with increasing S content up to 0.013%. But steel containing 0.040%S showed lower critical stress than that of 0.013% S. These result suggest that there will be optimum S content to prevent HAZ delayed cracking of high strength steels. 2) Under the lower D.H.C. level, critical stress was increased with rolling reduction, but higher D.H.C. level, effect of rolling reduction was not recognized.

• Asian-Australasian Journal of Animal Sciences
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• v.25 no.12
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• pp.1691-1700
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• 2012

The experiment studied the effect of harvesting frequencies and varieties on yield, chemical composition and hydrogen cyanide content in cassava foliage. Foliage from three cassava varieties, K94 (very bitter), K98-7 (medium bitter) and a local (sweet), were harvested in three different cutting cycles, at 3, 6 and 9 months; 6 and 9 months and 9 months after planting, in a 2-yr experiment carried out in Hanoi, Vietnam. Increasing the harvesting frequency increased dry matter (DM) and crude protein (CP) production in cassava foliage. The K94 variety produced higher foliage yields than the other two varieties. Dry matter, neutral detergent fibre (NDF), acid detergent fibre (ADF) and total tannin content increased with months to the first harvest, whereas CP content decreased. Hydrogen cyanide (HCN) content was lower at the first harvest than at later harvests for all cutting cycles. At subsequent harvests the content of total tannins tended to decline, while HCN content increased (p<0.05). Chemical composition differed somewhat across varieties except for total tannins and ash. Dry matter, NDF, ADF and total tannins were higher in fully matured leaves, while CP and HCN were lower in developing leaves.

• Journal of Powder Materials
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• v.13 no.3 s.56
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• pp.205-210
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• 2006

The effect of Cu content on hydrogen reduction behavior of ball-milled $WO_3$-CuO nanocomposite powders was investigated. Hydrogen reduction behavior and reduction percent(${\alpha}$) of nanopowders were characterized by thermogravimetry (TG) and hygrometry measurements. Activation energy for hydrogen reduction of $WO_3$ nanopowders with different Cu content was calculated at each heating rate and reduction percent(${\alpha}$). The activation energy for reduction of $WO_3$ obtained in this study existed in the ranging from 129 to 139 kJ/mol, which was in accordance with the activation energy for $WO_3$ powder reduction of conventional micron-sized.

• 한국연소학회:학술대회논문집
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• 2013.06a
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• pp.109-110
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• 2013

This paper describes gas turbine combustion characteristics of synthetic natural gas which contains a small amount hydrogen content. By conducting ambient pressure high temperature combustion test at gas turbine relevant combustor geometry, the combustion characteristics such as combustion instability, NOx and CO emission, temperatures at turbine inlet, nozzle and dump plane, and flame structure from high speed OH chemiluminescence images were investigated when changing hydrogen content from zero to 5%. From the results, qualitative and quantitative relationships are derived between key aspects of combustion performance, notably NOx/CO emission and combustion instability. Natural gas containing hydrogen up to 5% does not show significant difference in view of all combustion characteristics except combustion instability. Only up to 1% hydrogen addition could not change the pressure fluctuation and phase gas between fluctuations of pressure and heat release. From the results, it can be concluded that synthetic national gas which contains 1% of hydrogen can be guaranteed for the stable and reliable operation of natural gas firing gas turbine.

• Proceedings of the KWS Conference
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• 2005.06a
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• pp.141-143
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• 2005

Yttrium has been investigated as hydrogen trapping site in pure iron and HSLA steel welds. Assessment of hydrogen trapping parameters for yttrium oxide has also shown the high potential of yttrium addition to improve hydrogen management in high strength steel welding. The purpose of this study was to reduce and control the diffusible hydrogen content in the weld deposit.

• Journal of the Korean institute of surface engineering
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• v.51 no.2
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• pp.116-125
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• 2018

Aluminum-doped zinc oxide (AZO) is a commonly used material for the front contact layer of chalcopyrite $CuInGaSe_2$ (CIGS) based thin film solar cells since it satisfies the requisite optical and electrical properties with low cost and abundant elemental availability. Low-resistivity and high-transmission front contacts have been developed for high-performance CIGS solar cells, and nearly meet the required performance. However, the durability of the cell especially for the corrosion resistance of AZO films has not been studied intensively. In this work, AZO films were prepared on Corning glass 7059 substrates by radio frequency magnetron sputtering depending on the hydrogen content. The electrical and optical properties and electrochemical corrosion resistance of the AZO films were evaluated as a function of the hydrogen content. With increasing hydrogen content to 6 wt%, the crystallinity, crystal size, and surface roughness of the films increased, and the resistivity decreased with increased carrier concentration, Hall mobility, oxygen vacancies, and $Zn(OH)_2$ binding on the AZO surface. At a hydrogen content of 6 wt%, the corrosion resistance was also relatively high with less columnar morphology, shallow pore channels, and lower grain boundary angles.