• Title/Summary/Keyword: Hydrogen content

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Response of Ascorbate Peroxidase and Dehydroascorbate Reductase in Lettuce (Lactuca sativa L.) Leaves Exposed to Cold Stress (저온 처리한 상추의 잎 내에서 ascorbate peroxidase와 dehydroascorbate reductase의 반응)

  • Kang, Sang-Jae
    • Journal of Life Science
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    • v.18 no.12
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    • pp.1705-1711
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    • 2008
  • To investigate the relationship between cold stress and the activity of ascorbate peroxidase(APX), dehydroascorbate reductase (DHAR), mRNA expression level of two enzymes, hydrogen peroxide content was studied in lettuce leaves under stress condition imposed by cold stress at $4^{\circ}C$ for 24 hr in the dark and following recovery at $20^{\circ}C$ from cold stress. Hydrogen peroxide content increased gradually in lettuce leaves during cold stress, but decreased slightly following recovery from cold stress. Soluble protein content, however, decreased gradually during cold stress, and then rapidly returned to normal levels following recovery. Total chlorophyll content decreased gradually during cold stress, and then keep constant following recovery. The patterns of chlorophyll a and b content similar to that of total chlorophyll content, and carotenoid content didn't change. The ratio of chlorophyll a and total chlorophyll was increased during cold stress, but decreased with rapid during cold stress, and then the ratio returned to normal levels following recovery. During cold stress, the activity of APX and DHAR in the lettuce leaves increased dramatically, and also transcript levels of mRNA of APX and DHAR, as determined by probing 32P-labeled single stranded RNA of APX and DHAR, highly increased and returned to normal levels following recovery, respectively. Relationship between APX and DHAR activity and hydrogen peroxide highly related ($R^2$=0.8715 and 0.8643), whereas between hydrogen peroxide and total chlorophyll content and soluble content related reversely ($R^2$=0.5021 and 0.8915).

A Study on Prevention of Weld Transverse Crack for Thick Plate(Ⅱ) (후판 용접부의 횡균열 발생 방지에 관한 연구(Ⅱ))

  • Jeong, Ho-Sin;Gang, Seong-Won
    • Journal of Ocean Engineering and Technology
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    • v.13 no.3 s.33
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    • pp.57-67
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    • 1999
  • Welding is widely applicable and reliable process and is mainly adopted for fabricating heavy structures. Recently, weld metal transverse cracks in butt and fillet weld joint is a serious problem, and they must be eliminated for improving weld joint reliability. The weld metal transverse crack susceptibility of butt and fillet joint was carried out by cantilever type tensile crack testing jig and CTS test. In this view of point, this study investigated the potential factors for weld metal transverse crack. The main results obtained were as follows: 1. The content o fdiffusible hydrogen in weld metal played an important role for weld metal transverse cracks. 2. From cantilever type tensile crack tests, it was pointed out that the higher the diffusible hydrogen content and tensile restraint, the more susceptible to weld metal transverse craking. 3. The TSN(thermal severity number) and diffusible hydrogen were important factors for determining weld metal transverse cracks in fillet weld joints.

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Solid-Solution Mechanism of Aluminum and Hydrogen in Stishovite (스티쇼바이트에 고용하는 알루미늄과 수소와의 관계)

  • 정정인;김희수
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.3
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    • pp.245-254
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    • 2003
  • Stishovite was synthesized from hydrous basaltic starting materials at 10∼15 ㎬ and $1000∼1400^{\circ}C$. Water content of synthetic stishovite has been determined, and solid solution mechanism of $H_2$ and Al in stishovite was investigated. The maximum water content obtained from stishovite single crystal was up to $844\pm$44 ppm $H_2$O. The concentration of hydrogen increased with increasing substitution of trivalent cation, mainly Al. The temperature effect on the hydrogen content in stishovite is more sensitive than that on any other impurities. Among the nominally anhydrous mantle-minerals, stishovite could be an important water-containing phase and contribute to the transportation of $H_2$O to lower mantle.

Low Heat Input Welding to Improve Impact Toughness of Multipass FCAW-S Weld Metal

  • Bang, Kook-soo;Park, Chan;Jeong, Ho-shin
    • Journal of Ocean Engineering and Technology
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    • v.28 no.6
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    • pp.540-545
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    • 2014
  • Multipass self-shielded flux cored arc welding with different heat inputs (1.3–2.0 kJ/mm) was conducted to determine the effects of the heat input on the proportion of the reheated region, impact toughness, and diffusible hydrogen content in the weld metal. The reheated region showed twice the impact toughness of the as-deposited region because of its fine grained ferritic-pearlitic microstructure. With decreasing heat input, the proportion of the reheated region in the weld metal became higher, even if the depth of the region became shallower. Accordingly, the greatest impact toughness, 69 J at −40℃, was obtained for the lowest heat input welding, 1.3 kJ/mm. Irrespective of the heat input, little difference was observed in the hardness and diffusible hydrogen content in the weld metal. This result implies that low heat input welding with 1.3 kJ/mm can be performed to obtain a higher proportion of reheated region and thus greater impact toughness for the weld metal without the concern of hydrogen cracking.

A study on the laminar burning velocity according to the H2 content variation in a large range of equivalence ratio of syngas(H2/CO)-air premixed flames (넓은 당량비 구간에서 수소 함유량에 따른 합성가스(H2/CO)-공기 예혼합 화염의 층류연소속도에 관한 연구)

  • Jeong, Byeong-Gyu;Hwang, Cheol-Hong;Lee, Kee-Man
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.215-218
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    • 2012
  • In this study, syngas laminar burning velocities with various hydrogen contents were studied using both experimental measurements and kinetic simulations. The laminar burning velocities were measured by the angle method of Bunsen flame configuration and the numerical calculations including burning velocities were made using CHEMKIN Package with USC-Mech II. A large range of syngas mixture compositions such as 10:90%, 25:75%, 50:50%, 75:25% and equivalence ratio from lean condition of 0.5 to rich condition of 5.0 have been conducted. The experimental results of burning velocity were in good agreement with previous other research data and numerical simulation. Also, it was shown that the experimental measurements of laminar burning velocity linearly increased with the increasing of $H_2$ content although the flame speed of hydrogen is faster about ten times than carbon monoxide. This phenomenon is attributed to the rapid production of the hydrogen related radicals such as H and OH at the early stage of combustion, which is confirmed the linear increasing of radical concentrations on kinetic simulation.

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Decrease of the Hydrogen Sulfide($H_2S$) in the Produced Biogas by the Anaerobic Digestion (혐기성소화 시 발생되는 $H_2S$ 감소에 관한 연구)

  • Hong, Jong-Soon;Kim, Jae-Woo
    • Journal of environmental and Sanitary engineering
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    • v.24 no.4
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    • pp.80-89
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    • 2009
  • In the organic waste, food waste is the most difficult controls. In the study, food waste was treatmented to removal only the dockage. To decrease the hydrogen sulfide($H_2S$) in the produced biogas, iron chloride put in the anaerobic digester. Respectively treatment quantity of the food waste, content of the methane($CH_4S$) gas in the biogas, produced gases quantity, put in the quantity of the Iron chloride, pH, TS, Alkalinity, VFA, Ammonia. The results obtained from the experiment are as follows: 1. The produced biogases quantity/the treatment quantity of the food waste was $83.82{\sim}129.41m^3/ton$. 2. The content of the hydrogen sulfide($H_2S$) in the produced biogas is below of the 500ppm. The iron chloride put in the anaerobic digester. 200~300kg of the iron chloride put in the anaerobic digester at the steady-state. 400~850kg of the iron chloride put in the anaerobic digester at the unsteady-state. 3. Factor of the operator was the pH: 7.7~8.4, content of mathane: 55~65%. 4. TS(total solid) of the digestor sludge was 17~20%, Alkalinity was 38,500~41,750ppm, VFA(Volatile Fatty Acids) was 2,800~2,420ppm, Ammonia was 4,300~3,650ppm.

The effect of Ni content on the discharge characteristics of Zr-V-Mn-Ni hydrogen storage alloy electrode (Zr-V-Mn-Ni 수소저장합금전극의 방전특성에 미치는 Ni 양의 효과에 관한 연구)

  • Lee, Sang-Min;Kim, Dong-Myung;Jung, Jae-Han;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.1
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    • pp.11-21
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    • 1997
  • $ZrV_{0.7}Mn_{0.5}Ni_{1.2}$ alloy is attractive for anode material in Ni/MH secondary battery because of its large hydrogen storage capacity in gas-solid reaction and long cycling durability in KOH electrolyte. In this work, in order to further improve the discharge performance of this alloy electrode, the alloy was annealed by optimal condition which is for 12 hours at $1000^{\circ}C$. The alloy annealed under optimal condition had higher rate capability and discharge capacity than as-cast one. The microstructure of the as-cast and annealed alloy was investigated by scanning electron microscopy and energy dispersive spectroscopy. Ni content in the matrix was increased, being this homogenized after annealing. Additionally, The measurement of the surface area by B.E.T. analysis showed that there was little difference as-cast and annealed alloy. Therefore, improvement in the rate capability of the annealed alloy is due to increase of Ni content in the matrix.

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Effects of Adding Mg to AlSi Coating for Hot Stamping Steel (자동차용 핫스탬핑 AlSi 도금중 Mg 첨가효과)

  • Yang, Wonseog;Lee, Jeamin;Kim, Changkyu;Ahn, Seungho;Castaneda, Homero
    • Corrosion Science and Technology
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    • v.20 no.4
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    • pp.196-203
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    • 2021
  • To improve corrosion resistance and reduce the hydrogen uptake of 22MnB5, up to 5% Mg was added to the AlSi coating of 22MnB5. After hot-stamping and electrocoating were done on the metallic-coated specimen, the surface characteristics of the steel, hydrogen uptake content, and corrosion resistance were examined by transmittance electron microscopy, thermal desorption spectrometry, cyclic corrosion testing, and electrochemical impedance spectroscopy. Mg was investigated as MgO on the surface layer after hot-stamping while it existed as Mg2Si before hot-stamping. The total hydrogen content of 22MnB5 was decreased along with the Mg content. However, there was no difference at 0.2 wt% or more. When a small amount of Mg was added, the coating corrosion resistance was decreased, but when it was added at around 1.0 wt%, the greatest corrosion resistance increase was seen. However, when 3 wt% or more was added excessively, the corrosion resistance was decreased. MgO on the surface was considered to suppress H uptake by the AlSi melting solution and increase the barrier effect of the coating.

Supercritical Water Gasification of Low Rank Coal with High Moisture Content (고함수 저등급 석탄의 초임계수 가스화 특성)

  • Yoon, Sang Jun;Lee, Jae Goo;Ra, Ho Won;Seo, Myung Won
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.4
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    • pp.340-346
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    • 2013
  • Study on clean and efficient utilization technology for low rank coal with high moisture content is actively ongoing due to limited reserves of petroleum and of high grade coal and serious climate change caused by fossil fuel usage. In the present study, supercritical water gasification of low rank coal was performed. With increasing reaction temperature, content of combustible gases such as $H_2$ and $CH_4$ in the syngas increased while the $CO_2$ content decreased. As the reaction pressure increased from 210 to 300 bar, the $CO_2$ content in the syngas increased while the hydrocarbon gas content decreased. The $H_2$ and $CH_4$ content in the syngas increased slightly with pressure. With the addition of Pd, Pt, and Ru catalysts, it was possible to improve the production of $H_2$. Moreover, the increase of active metal content in the catalyst increased the $H_2$ productivity. The Ru catalyst shows the best performance for increasing the $H_2$ content in the syngas, while decreasing the $CO_2$ content.

Optimized Mixing Design of Lightweight Aerated Concrete by Response Surface Analysis (반응표면분석법에 따른 경량기포콘크리트 최적배합 도출에 관한 연구)

  • Lee, Sang-An;Jung, Chan-Woo;Kim, Wha-Jung;Ahn, Jung-Hyun
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.745-752
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    • 2009
  • This paper presents the optimized mixing design of lightweight aerated concrete using hydrogen peroxide. Design of experiments in order to the optimized mixing design was applied and commercial program (MINITAB) was used. Statistical analysis was used to Box-Behnken (B-B) method in response surface analysis. The influencing factors of experimental are unit cement content, water ratio and hydrogen peroxide ratio. According to the analysis of variance, at the hardened state, water ratio and hydrogen peroxide ratio affects on dried density, compressive strength and bending strength of lightweight aerated concrete, but unit cement content affects on only dried density. In the results of response surface analysis, to obtain goal performance, the optimized mixing design for lightweight aerated concrete using hydrogen peroxide were unit cement content of 800 kg/$m^3$, water ratio of 44.33% and hydrogen peroxide ratio of 10%.