• Transactions of the Korean hydrogen and new energy society
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• v.13 no.2
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• pp.110-118
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• 2002

The hydrogen storage vessel having a good heat conductivity along with a simple structure and a low cost for these alloys was designed and manufactured, and then its characteristic properties were studied in this study. The various parts in hydrogen storage vessel consisted of copper pipes and stainless steel of 250 mesh reached the setting temperature after 4~5 minutes, which indicated that storage vessel had a good heat conductivity that was required in application. And also the storage vessel had a good property of hydrogen transport considering that the reaction time between hydrogen and rare-earth metal alloys in storage vessel was found to be within 10 min at $18^{\circ}C$ under 10 atmospheric pressure. It showed that the average capacity of discharged hydrogen volume was found to be $120{\ell}$ for $MmNi_{4.5}Mn_{0.5}$ under discharging conditions of $40^{\circ}C{\sim}80^{\circ}C$ at a constant flow rate of $5{\ell}$/min. It was found that the optimum discharging temperature for obtaining an appropriate pressure of 3atm was determined to be $60^{\circ}C$ for $MmNi_{4.5}Mn_{0.5}$ hydrogen storage alloy.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.4
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• pp.249-257
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• 2010

In this paper, a three-dimensional hydrogen absorption model is developed to precisely study hydrogen absorption reaction and resultant heat and mass transport phenomena in metal hydride hydrogen storage vessels. The 3D model is first experimentally validated against the temperature evolution data available in the literature. In addition to model validation, the detailed simulation results shows that at the initial absorption stage, the vessel temperature and H/M ratio distributions are uniform throughout the entire vessel, indicating that the hydrogen absorption is so efficient during the early hydriding process and thus local cooling effect is not influential. On the other hand, nonuniform distributions are predicted at the latter absorption stage, which is mainly due to different degrees of cooling between the vessel wall and core regions. This numerical study provides the fundamental understanding of detailed heat and mass transfer phenomena during hydrogen absorption process and further indicates that efficient design of storage vessel and cooling system is critical to achieve fast hydrogen charging and high hydrogen storage efficiency.

• Applied Chemistry for Engineering
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• v.33 no.6
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• pp.653-660
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• 2022

In liquid hydrogen storage tanks, tank damage or leakage in the surrounding pipes possess a major risk. Since these tanks store huge amounts of the fluid among all the liquid hydrogen process facilities, there is a high risk of leakage-related accidents. Therefore, in this study, we conducted a risk assessment of liquid hydrogen leakage for a grid-type liquid hydrogen storage tank (lattice-type pressure vessel (LPV): 18 m³) that overcame the low space efficiency of the existing pressure vessel shape. Through a commercially developed three-dimensional computational fluid dynamics program, the geometry of the site, where the liquid hydrogen storage tank will be installed, was obtained and simulations of the leakage scenarios for each situation were performed. From the computational flow analysis results, the pool formation behavior in the event of liquid hydrogen leakage was identified, and the resulting damage range was predicted.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.2
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• pp.184-193
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• 2020

One of the technical methods to increase the volumetric energy density of hydrogen is to pressurize the gaseous hydrogen and then contain it in a rigid vessel. Especially for automotive systems, the compressed hydrogen storage can be found in cars as well as at refueling stations. During the charging the pressurized hydrogen into a vessel, the temperature increases with the amount of stored hydrogen in the vessel. The temperature of the vessel should be controlled to be less than a limitation for ensure stability of material. Therefore, the accurate estimation of temperature is of significance for safely storing the hydrogen. In this work, three well-known cubic equations of state (EOSs) were adopted to examine the accuracy in regenerating thermodynamic properties of hydrogen within the temperature and pressure ranges for the compressed hydrogen storage. The formulations representing molar volume, internal energy, enthalpy, and entropy were derived for Redlich-Kwong (RK), Soave-Redlioch-Kwong (SRK), and Peng-Robinson (PR) EOSs. The calculated results using the EOSs were compared with literature data given by NIST. It was revealed that the accuracies of RK and SRK EOSs were satisfactorily compatible and better than the results by PR EOS.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.3
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• pp.363-371
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• 2011

In this paper, a three-dimensional hydrogen desorption model is developed to precisely study the hydrogen desorption kinetics and resultant heat and mass transport phenomena in metal hydride hydrogen storage vessels. The metal hydride hydrogen desorption model, i.e. governed by the conservation of mass, momentum, and thermal energy is first experimentally validated against the temperature evolution data measured on a cylindrical $LaNi_5$ metal hydride vessel. The equilibrium pressure used for hydrogen desorption simulations is derived as a function of H/M atomic ratio and temperature based on the experimental data in the literature. The numerical simulation results agree well with experimental data and the 3D desorption model successfully captures key experimental trends during hydrogen desorption process. Both the simulation and experiment display an initial sharp decrease in the temperature mainly caused by relatively slow heat supply rate from the vessel external wall. On the other hand, the effect of heat supply becomes influential at the latter stages, leading to smooth increase in the vessel temperature in both simulation and experiment. This numerical study provides the fundamental understanding of detailed heat and mass transfer phenomena during hydrogen desorption process and further indicates that efficient design of storage vessel and heating system is critical to achieve fast hydrogen discharging performance.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.06a
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• pp.239-245
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• 2005

The reduction of heat transfer rate to the stored liquid hydrogen from outside condition is extremely important to keep the liquid hydrogen longer. In this paper the highly efficient support system for the liquid hydrogen storage vessel was newly developed and analysed. The support system was composed of a spherical ball in the center of supporter to reduce the heat transfer area, with its above and below supporting blocks which are the SUS and PTFE blocks inserted in the SUS tube. The heat transfer rate and temperature distribution of the support system were evaluated by FLUENT, and the thermal stress and strain were estimated by ANSYS software. The results showed that the heat transfer rate from outer vessel to inner one was extremely decreased compared with the common method which is simply SUS tubes inserted between inner and outer tanks. The thermal stress and strain were obtained well below the limited values. As a result, it was the most efficient support system of storage vessel for liquid hydrogen and most cryogenic fluids.

• Journal of the Korean Institute of Gas
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• v.27 no.2
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• pp.95-103
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• 2023

In this paper, in order to evaluate the deformation characteristics of the hydrogen gas storage vessel(Type 1) when considering gas pressure, the VMS generated in the hydrogen gas storage vessel according to the notch shape of ISO 18119 was interpreted as a FEM(Finite Element Method). According to the analysis results, the maximum VMS generated in the longitudinal notch was higher than the transverse notch. In addition, the stress of the storage vessel was analyzed by the stress ratio, which is the yield strength ratio of the material to the VMS generated. According to the analysis results, in the case of a storage vessel with a notch formed in the longitudinal direction, the inside and outside of the storage vessel increased to 0.85 and 0.50 at a gas pressure of 50 MPa, respectively, but were analyzed to be lower than 1.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.1
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• pp.32-37
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• 2023

In this study, in order to propose a integrity evaluation for type IV high aspect ratio hydrogen storage vessel, a numerical analysis of the hoop tensile test and pressure test was performed using FEM software, and the results of the actual physical property test were reviewed. The property test and numerical analysis were compared, and very similar results were obtained with deviations of maximum tensile strength of 4.75% and fiber direction stress of 5.39%.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.1
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• pp.26-31
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• 2023

In this study, in order to propose a modular method for type IV high aspect ratio modular hydrogen storage vessel, a numerical analysis was conducted on the heat transfer behavior in series and parallel connection methods, and the differences according to each connection method were reviewed. Computational fluid dynamics software was used to check the internal temperature and pressure values of the hydrogen storage container under charging conditions. In terms of thermal safety when charging hydrogen gas, it was confirmed that the parallel modularization method was superior.

• Journal of the Korean Society of Safety
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• v.34 no.5
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• pp.7-14
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• 2019

The type III vessel, which is used to store high-pressure hydrogen gas, is made by wrapping the vessel's liner with carbon fiber composite materials for strength performance and lightening. The liner seals the internal gas and the composite resists the internal pressure. The properties of the fiber composite material depends on the angle and thickness of the fiber. Thus, engineers should consider these various design variables. However, it significantly increases the design cost due to the trial and error under designing based on experience or experiments. And, for aluminum liners, fatigue loads due to using and charging could give a huge impact on the performance of the structure. However, fatigue failure does not necessarily occur in the position under the highest load in use. Therefore, for hydrogen storage vessel, fatigue evaluation according to design patterns is essential because stress distribution varies depend on composite layer patterns. This study performed an optimization analysis and evaluated a high-pressure hydrogen storage vessel to minimize these trial and error and improve the reliability of the structure, while simultaneously conducting fatigue assessment of all patterns derived from the optimization analysis process. The results of this study are thought to be useful in the strength improvement and life design of composite reinforced high-pressure storage vessels.