• 제목/요약/키워드: Impedance spectroscopy

검색결과 755건 처리시간 0.029초

전기화학적 전력 기기의 모델링을 위한 저가의 임피던스 분광 시스템의 개발 (Development of the Low Cost Impedance Spectroscopy System for Modeling the Electrochemical Power Sources)

  • 이주형;최우진
    • 전력전자학회논문지
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    • 제13권1호
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    • pp.46-54
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    • 2008
  • 본 논문에서는 연료전지나 배터리 및 슈퍼커패시터 등의 전기화학적 전력기기의 임피던스 모델링에 적합한 저가의 임피던스 분광 시스템을 설계하고 구현하였다. 제안된 시스템은 간단한 센서회로 및 상용 DAQ(Data Acquisition) Board와 강력한 HMI(Human-Machine Interface)를 지원하는 그래픽 언어인 LabVIEW 소프트웨어를 이용하여 구성되었고 고가의 EIS(Electrochemical Impedance Spectroscopy) 장비를 대체하여 널리 사용될 수 있을 것으로 기대된다. 또한, 제안된 시스템에서는 Lock-in Amplifier를 이용함으로써 노이즈(Noise)가 많은 환경에서도 측정 주파수 성분의 정확한 측정이 가능하게 하였다. 제안된 시스템을 이용하여 Ballard Nexa 1.2kW PEM 연료전지 스택의 주파수별 임피던스를 측정하였고, 이를 바탕으로 한 등가 임피던스 모델도 제안된다. 제시된 모델과 개발된 장비의 유용함은 리플전류에 의한 연료전지 스택의 교류 손실 측정을 통해 증명된다.

CHARACTERISTICS OF LOW-TEMPERATURE PROCESSED DYE-SENSITIZED SOLAR CELL BY ELECTROCHEMICAL IMPEDANCE AND PHOTOCURRENT-PHOTOVOLTAGE TRANSIENT SPECTROSCOPY

  • Li, Yuelong;Lee, Doh-Kwon;Kim, Kyung-Kon;Ko, Min-Jae
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.381-381
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    • 2011
  • In this study, a TiO2 colloidal sol was synthesized by sol-gel process, which was used as a "glue" agent to enhance interconnection of TiO2 particles in low temperature process for plastic dye sensitized solar cell. The crystalline phase of this TiO2 glue is pure anatase with average particles size of 5 nm, which was characterized by powder X-ray diffraction and high revolution-TEM. The viscous alcoholic paste without any organic binder was prepared from the mixture of commercial P25 powder and glue. Paste composition and sintering process parameters were optimized for high photovoltaic performance based on low temperature process. The electrochemical impedance spectroscopy and photocurrent-photovoltage transient spectroscopy were also employed to investigate the mechanism of electron transport in this binder free TiO2 film system.

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원추 관입형 임피던스 수분센서 개발을 위한 기초 연구 (Basic Study for Cone Penetrometer Type Soil Water Content Sensor using Impedance Spectroscopy)

  • 이동훈;이규승;정선옥
    • Journal of Biosystems Engineering
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    • 제34권6호
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    • pp.434-438
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    • 2009
  • This study was conducted to design an cone penetrometer type impedance sensor that can measure soil water content in realtime. The best width between electrical probe was determined by 5 mm. For optimization about realtime application device, linear regression analysis was applied between soil water content and impedance signal. It was concluded that proper combination of excitation frequency, impedance parameter, and model would provide acceptible performance of a soil waler content sensoe. Best model was obatained at a 36.5 MHz with |Z| as a predictor variable, with a coefficient of determination of 0.96 (RMSE=1.35, RPD=4.98).

EIS를 이용한 염화물 및 방청제가 첨가된 콘크리트에 매립된 철근의 방식성능 평가에 관한 실험적 연구 (A Experimental Study on the Evaluation of Anti-corrosion Performance of rebar in concrete added chloride and inhibitor using EIS method)

  • 박장현;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2016년도 추계 학술논문 발표대회
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    • pp.134-135
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    • 2016
  • To evaluate anti-corrosion performance of rebar in concrete according to the amount of chloride and inhibitor, electrochemical impedance spectroscopy(EIS) method was conducted in this study. For the anti-corrosion performance evaluation according to time, Impedance of rebar in concrete was measured before and after 5 cycle of corrosion acceleration. As a results, The impedance of rebar in concrete added chloride decreased than before corrosion acceleration. However impedance of other specimens was maintained or increased than before corrosion acceleration.

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Impedance spectroscopy for lifetime analysis of OLED

  • Yoon, Chul-Oh;Kim, Hyun-Chul;Yi, Seok-Kyung;Kong, Ung-Gul;Lee, Nam-Heon;Lee, Chang-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.137-140
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    • 2002
  • The frequency response analysis of complex impedance spectra using small perturbation ac impedance spectroscopy is an informative method of OLED performance characterization and lifetime analysis. Using simple RC equivalent circuit mode,l macroscopic nonliniear transport properties of semiconductive emission/transport layers can be analyzed and parameterized. We present the bias voltage dependence and aging effect in impedance spectra measured from an ITO/CuPC/TPD/$Alq_3$/LiF/Al OLED device, and discuss possible failure mechanism based on impedance model parameters.

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Temperature-dependent dielectric relaxation in ITO/Alq3/Al organic light-emitting diodes

  • Ahn, Joonho;Kim, Tae Wan;Lee, Won Jae
    • Journal of Ceramic Processing Research
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    • 제13권spc2호
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    • pp.163-165
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    • 2012
  • Impedance spectroscopy informs electrical properties of materials as accumulated charges, contact status between electrode and organic materials. We carried out impedance spectroscopy of organic light-emitting diodes as ITO/Alq3(60 nm)/Al on temperatures from 10 K to 300 K. The result described Z'-Z" plot, cole-cole plot and dielectric relaxation time τ. Z'-Z" plot means that real and imaginary part of materials in organic and electrode by frequencies and temperature. Z' as real part of impedance by applied frequency depending on temperature shows the plateau in low frequency region as Rs+ Rp and over 100 kHz in high frequency region as Rs. Cole-cole plot shows resistance of materials in equivalent circuit of the device by temperatures. And equivalent circuit and dielectric relaxation could be accomplished by using the complex impedance analysis.

Investigation on the phase transition of $Ni_2$MnGa alloy by using impedance spectroscopy

  • Park, S.Y.;Cho, K.H.;Lee, Y.P.
    • Journal of Korean Vacuum Science & Technology
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    • 제7권1호
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    • pp.13-17
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    • 2003
  • The influence of structural transition on the resistance and impedance behavior of Ni$_2$MnGa alloy was investigated. The temperature-dependent resistance and impedance were measured in a temperature range of 4 - 350 K and 185 - 300 K, respectively. The dependence of temperature coefficient of resistivity on temperature shows a kink at 220 K, which is related to the structural transition. The change in dominant scattering mechanism results in the observed kink. Significant increases were also observed around the transition temperature for both real and imaginary parts of impedance. It is thought that this phenomenon originates from disappearance of the martensite twin boundaries during the structural transformation.

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Novel State-of-Charge Estimation Method for Lithium Polymer Batteries Using Electrochemical Impedance Spectroscopy

  • Lee, Jong-Hak;Choi, Woo-Jin
    • Journal of Power Electronics
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    • 제11권2호
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    • pp.237-243
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    • 2011
  • Lithium batteries are widely used in mobile electronic devices due to their higher voltage and energy density, lighter weight and longer life cycle when compared to other secondary batteries. In particular, a high demand for lithium batteries is expected for electric cars. In the case of the lithium batteries used in electric cars, driving distance must be calculated accurately and discharging should not be done below a level that makes it impossible to crank. Therefore, accurate information on the state-of-charge (SOC) becomes an essential element for reliable driving. In this paper, a novel method for estimating the SOC of lithium polymer batteries using AC impedance is proposed. In the proposed method, the parameters are extracted by fitting the measured impedance spectrum on an equivalent impedance model and the variation in the parameter values at each SOC is used to estimate the SOC. Also to shorten the long length of time required for the measurement of the impedance spectrum, a novel method is proposed that can extract the equivalent impedance model parameters of lithium polymer batteries with the impedance measured at only two specific frequencies. Experiments are conducted on lithium polymer batteries, with similar capacities, made by different manufacturers to prove the validity of the proposed method.

Interfacial Electrical/Dielectric Characterization in Low Temperature Polycrystalline Si

  • Hwang, Jin-Ha
    • 마이크로전자및패키징학회지
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    • 제12권1호
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    • pp.77-85
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    • 2005
  • Impedance spectroscopy was applied to low temperature polycrystalline Si in order to investigate the electrical/dielectric information in polycrystalline Si. By combined microstructure and impedance spectroscopy works, it was shown that the electrical information is sensitive to the corresponding microstructure, i.e., the grain size and distribution, judged from the capacitance vs. grain size relationship. At $360 mJ/cm^2$, the maximum in capacitance and the minimum in resistance correspond to the largest grain sizes of unimodal distribution in polycrystalline Si. The electrical/dielectric characterization is compared with Raman spectroscopic characterizations in terms of microstructure.

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Effect of $HfO_X$ treatment on ITO surface of organic light emitting diodes using Impedance spectroscopy analysis

  • Cho, Jae-Hyun;Park, Hyung-Jun;Han, Kyu-Min;Sohn, Sun-Young;Jung, Dong-Geun;Yi, Jun-Sin
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.506-508
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    • 2008
  • In this work, we used impedance spectroscopy analysis to determine the effect of the $HfO_X$ treatment on the surface of ITO and to model the equivalent circuit for OLEDs. Devices with an ITO/Organic material/Al structure can be modeled as resistances and capacitances arranged in parallel or in series. The number of elements depends on the composition of the structure, essentially the number of layers, and the contacts.

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