• Title/Summary/Keyword: In-situ precipitation

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Morphological and Physical Properties of ONP Treated by CaCO3 In-situ Precipitation Method (탄산칼슘 in-situ precipitation 처리된 신문고지의 형태와 물성변화)

  • Lee, Young Ho;Jung, Jae Kwon;Lee, Ki Seung;Seo, Yung Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.6
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    • pp.44-54
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    • 2013
  • Replacing OMG (old magazine) to ONP (old newspaper) by raising optical property through $CaCO_3$ in-situ precipitation method in white duplex board presents cost reduction and possible drying energy saving. The strength property impairment by the presence of $CaCO_3$ could be supplemented by the fiber furnish treatment or strength polymer addition. In $CaCO_3$ in-situ precipitation of ONP, it was found from morphological study using FlowCAM, an image analyzer, that most of calcium carbonate were formed on the fines, and made the size of the fines larger. For the case of forming calcium carbonate only on the fractionated fines, the size of the fines were the biggest, and there were more clean surface areas available for bonding for the fractionated long fibers when fractionated fibers and fines were regrouped to make paper.

Effects of Titania Whisker Precipitation on Wear Property of the Glass-Ceramic (타이타니아 단섬유상의 석출이 결정화유리의 마모특성에 미치는 영향)

  • 이경호
    • Journal of the Korean Ceramic Society
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    • v.33 no.2
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    • pp.192-202
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    • 1996
  • In Li0.4Ca0.05AlP0.5Si0.75O4.5 composition glass, glass-ceramic having a near 100% crystallinity after nucleation heat treatment of 74$0^{\circ}C$/2 h and crystallization heat treatment of 90$0^{\circ}C$/2 h and in-situ TiO2 whisker reinforced glass-ceramic after heat treatment of 105$0^{\circ}C$ for 20 h were fabricated with the addition of 4% TiO2 as a nucleating agent. With these materials a ball-on-disc type wear test was conducted in order to examine the effect of TiO2 whisker prepcipitation on ambient and high temperature wear properties of the glass-ceramic. Wear test results indicated that all specimens exhibited micro-fracture wear mechanism in ambient temperature. As temperature increased the wear rates of the materials were increased. However the in-situ TiO2 whisker reinforced glass-ceramic exhibited the lowest wear rate over the test temperature range. This resulted from the improvement of harness and fracture toughness of the material as the glass converted into the glass-ceramic followed by precipitation of TiO2 whiskers throughout the glass-ceramic matrix.

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Preparation of in situ Patterned ZnO Thin Films by Microcontact Printing (Microcontact Printing을 이용한 미세패턴 ZnO 박막 제조)

  • 임예진;윤기현;오영제
    • Journal of the Korean Ceramic Society
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    • v.39 no.7
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    • pp.649-656
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    • 2002
  • In situ patterned zinc oxide thin films were prepared by precipitation of Zn(NO$_3$)$_2$ aqueous solution containing urea and by microcontact printing using Self-Assembled Monolayers(SAMs) on A1/SiO$_2$/Si substrates. The visible precipitation of Zn(OH)$_2$ that was formed in the Zn(NO$_3$)$_2$ aqueous solution containing urea was enhanced with an increase of the reaction temperature and the amount of urea. As the reaction time of Zn(NO$_3$)$_2$ with urea was prolonged, the thickness and grain size of Zn(OH)$_2$ thin layers were increased, respectively. The optimum precipitation condition was at 80$\^{C}$ for 1 h for the solution with the ratio of Zn(NO$_3$)$_2$ to urea of 1 : 8. Homogeneous ZnO thin films were fabricated by the heat treatment of 600$\^{C}$ for 1 h of Zn(OH)$_2$ precipitation on Al/SiO$_2$/Si substrate. This was available to the in-situ patterned ZnO thin films with uniform grain size. Hydrophobic SAM, Octadecylphosphonic Acid(OPA) and hydrophilic SAM, 2-Carboxyethylphosphonic Acid(CPA) were applied on the Al/SiO$_2$/Si substrate by microcontact printing method. In situ patterned ZnO thin film was successfully prepared by the heat treatment of Zn(OH)$_2$ precipitated on the surface of hydrophilic SAM, CPA.

In-situ Monitoring of Matric Suctions in a Weathered Granite Soil Slope (풍화화강토 사면에서 강우로 인한 모관흡수력 변화에 대한 실험 연구)

  • 이인모;조우성;김영욱;성상규
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.03a
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    • pp.509-516
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    • 2002
  • Rainfall-induced landslides in a weathered granite soil slope have mostly relative shallow slip surfaces above the groundwater table The pore-water pressure of soil above the groundwater table is usually negative. This negative pore-water pressure(or matric suction) has been found to make a large contribution to the slope stability. Therefore, the variation of in-situ matric suction profiles with time in a soil slope should be understood. In this study, a field measurement program was carried out from June to August, 2001 to monitor in-situ matric suctions and volumetric water contents in a weathered granite soil slope. The influence of climatic conditions on the variation of in-situ matric suctions could be found to decrease rapidly with depth. It could be found that decrement of matric suction induced by precipitation is affected not only by the amount and duration of rainfalls but also by the initial matric suction just prior to rainstorms. The soil-water characteristic from the field monitoring tends toward the wetting path of SWCC obtained from the laboratory test.

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In-situ Precipitation of Arsenic and Copper in Soil by Microbiological Sulfate Reduction (미생물학적 황산염 환원에 의한 토양 내 비소와 구리의 원위치 침전)

  • Jang, Hae-Young;Chon, Hyo-Taek;Lee, Jong-Un
    • Economic and Environmental Geology
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    • v.42 no.5
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    • pp.445-455
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    • 2009
  • Microbiological sulfate reduction is the transformation of sulfate to sulfide catalyzed by the activity of sulfate-reducing bacteria using sulfate as an electron acceptor. Low solubility of metal sulfides leads to precipitation of the sulfides in solution. The effects of microbiological sulfate reduction on in-situ precipitation of arsenic and copper were investigated for the heavy metal-contaminated soil around the Songcheon Au-Ag mine site. Total concentrations of As, Cu, and Pb were 1,311 mg/kg, 146 mg/kg, and 294 mg/kg, respectively, after aqua regia digestion. In batch-type experiments, indigenous sulfate-reducing bacteria rapidly decreased sulfate concentration and redox potential and led to substantial removal of dissolved As and Cu from solution. Optimal concentrations of carbon source and sulfate for effective microbial sulfate reduction were 0.2~0.5% (w/v) and 100~200 mg/L, respectively. More than 98% of injected As and Cu were removed in the effluents from both microbial and chemical columns designed for metal sulfides to be precipitated. However, after the injection of oxygen-rich solution, the microbial column showed the enhanced long-term stability of in-situ precipitated metals when compared with the chemical column which showed immediate increase in dissolved As and Cu due to oxidative dissolution of the sulfides. Black precipitates formed in the microbial column during the experiments and were identified as iron sulfide and copper sulfide. Arsenic was observed to be adsorbed on surface of iron sulfide precipitate.

Satellite monitoring and prediction for the occurrence of the red tide in the coastal areas in the South Sea of Korea - I. The relationship between the occurrence of red tide and the meteorological factors

  • Yoon, Hong-Joo;Kim, Young-Seup;Kim, Sang-Woo
    • Proceedings of the KSRS Conference
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    • 2002.10a
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    • pp.656-656
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    • 2002
  • It is studied on the relationship between the occurrence of red tide(Chlorophyll-a concentration by the in-situ and satellite data) and the meteorological factors (precipitation, air temperature, sunshine and winds) in the coastal areas in the South Sea of Korea. In summer and early-fall which frequently occurred the red tide, the precipitation above 213mm had directly influence on the occurrence of red tide because it carried the nutritive substance which originated from the land into the coastal areas. Then air temperature kept up generally high values as 23~26$^{\circ}C$, and sunshine with 187~198hours and wind velocity with 3.1~7.9m/s showed not directly the relationship on the occurrence of red tide.

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Optical Characteristics of Eco-friendly In-situ Recycled Paper with Limestone as Filler (석회석을 원료로 사용한 재생용지의 친환경 In-situ Filler로서의 광학적 특성 연구)

  • Lee, Hyun-Jae;Lee, Lown;Kim, Chun-Sik;Nam, Seong-Young;Seo, Yung-Bum;Ahn, Ji-Whan
    • Journal of the Korean Ceramic Society
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    • v.51 no.2
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    • pp.132-137
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    • 2014
  • The study was performed with low-grade limestone, which is used to make cement or is disposed of due to its low CaO content. In this study, the optimal condition of limestone with which to manufacture precipitated calcium carbonate (PCC) and limestone in fiber was determined through in-situ reactions. The best firing condition is with slaked lime with rapid cooling after 2 h of firing at $1000^{\circ}C$. In addition, the content of CaO can be increased by sorting the low-grade limestone using a 200 mesh filter, and the optical quality of old newspaper (ONP) was similar when using both low-grade and high-grade limestone. Also, controlling the particle size of PCC is an important factor pertaining to the optical characteristics of paper.

Continuous Preconcentration of Sn2+/Sn4+ by the On-line Sulfide Precipitation-Dissolution

  • Yeon, Pyung-Heum;Yoon, Young-Suk;Oh, Se-Woung;Nam, Sang-Ho;Par, Yong-Nam
    • Bulletin of the Korean Chemical Society
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    • v.25 no.8
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    • pp.1156-1160
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    • 2004
  • The technique of an on-line preconcentration by the direct sulfide precipitation has been developed. Sn was homogeneously precipitated by sulfide, which was generated in situ from the hydrolysis of thioaceteamide. Precipitate was collected on a filter in the line and dissolved out instantaneously by KOH to be sent to an ICP. The enrichment factor was 4 with the sampling speed of 15/hr for 1.0 mL of sample. It was increased to more than 40 times when the sampling volume was increased to 10 mL with the sampling speed of 5/hr. $Sn^{2+}/Sn^{4+}$ could be separately determined with the on-line precipitation technique. The method was applied to the analysis of NIST SRM 1566 Oyster sample and yielded good agreement with the certified value.

Temporal Variation of Air Temperature in Ice-Valley at Milyang in Association with Ice Formation

  • Lee, Soon-Hwan;Hwang, Soo-Jin
    • Journal of the Korean earth science society
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    • v.28 no.5
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    • pp.598-602
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    • 2007
  • A long-term in situ observation was carried out in the Ice-valley at Milyang in order to explain the factors and processes associated with the summertime ice formation. The variation of temperature inside Ice-valley in relation with ice formation in summer time was found to depend on precipitation rate in spring and cold air sinking in autumn and winter. The rate of temperature rising tends to correspond to sensible heat release depending on the precipitation amount at the freezing location. The reason of the cold air accumulation in a talus in the Ice-valley is the cold air sinking over the surface of talus due to the occurrence of outside clod air mass and the accumulated cold air from autumn to spring flow outside at the bottom of talus. The out-flowing cold air can result in the ice formation in the hot summer.

Investigating the scaling effect of the nonlinear response to precipitation forcing in a physically based hydrologic model (강우자료의 스케일 효과가 비선형수문반응에 미치는 영향)

  • Oh, Nam-Sun;Lee, K.
    • Proceedings of the Korea Water Resources Association Conference
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    • 2006.05a
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    • pp.149-153
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    • 2006
  • Precipitation is the most important component and critical to the study of water and energy cycle. This study investigates the propagation of precipitation retrieval uncertainty in the simulation of hydrologic variables for varying spatial resolution on two different vegetation cover. We explore two remotely sensed rain retrievals (space-borne IR-only and radar rainfall) and three spatial grid resolutions. An offline Community Land Model (CLM) was forced with in situ meteorological data In turn, radar rainfall is replaced by the satellite rain estimates at coarser resolution $(0.25^{\circ},\;0.5^{\circ}\;and\;1^{\circ})$ to determine their probable impact on model predictions. Results show how uncertainty of precipitation measurement affects the spatial variability of model output in various modelling scales. The study provides some intuition on the uncertainty of hydrologic prediction via interaction between the land surface and near atmosphere fluxes in the modelling approach.

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