• Title/Summary/Keyword: Interfacial defects

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Relative Influence of Surface and Interfacial Defects in Hydrothermally Grown Nanostructured ZnO (수열 합성된 나노구조를 갖는 ZnO 에 대한 표면 및 계면 결함의 상대적인 영향)

  • Park, Cheolmin;Lee, Jihye;So, Hye-Mi;Chang, Won Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.10
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    • pp.831-835
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    • 2014
  • The relative concentration of surface and interfacial defects in hydrothermally grown ZnO nanostructures was investigated by a comparison of two samples having different growth temperatures via bias voltage sweep rate under laser illumination of 405 and 355 nm. The current of small ZnO nanostructures (growth temperature of $75^{\circ}C$) decreased when induced more slowly bias voltage sweep rate under the laser illumination. In contrast, the current of large ZnO nanostructures (growth temperature of $90^{\circ}C$) increased. This difference in currents indicates the relation of relative defects concentration between surface and interfacial defects of ZnO nanostructure. Our experimental approach has potential applicability in the analysis of influence on defects in ZnO devices.

Parametric study on multichannel analysis of surface waves-based nondestructive debonding detection for steel-concrete composite structures

  • Hongbing Chen;Shiyu Gan;Yuanyuan Li;Jiajin Zeng;Xin Nie
    • Steel and Composite Structures
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    • v.50 no.1
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    • pp.89-105
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    • 2024
  • Multichannel analysis of surface waves (MASW) method has exhibited broad application prospects in the nondestructive detection of interfacial debonding in steel-concrete composite structures (SCCS). However, due to the structural diversity of SCCS and the high stealthiness of interfacial debonding defects, the feasibility of MASW method needs to be investigated in depth. In this study, synthetic parametric study on MASW nondestructive debonding detection for SCCSs is performed. The aim is to quantitatively analyze influential factors with respect to structural composition of SCCS and MASW measurement mode. First, stress wave composition and propagation process in SCCS are studied utilizing 2D numerical simulation. For structural composition in SCCS, the thickness variation of steel plate, concrete core, and debonding defects are discussed. To determine the most appropriate sensor arrangement for MASW measurement, the effects of spacing and number of observation points, along with distances between excitation points, nearest boundary, as well as the first observation point, are analyzed individually. The influence of signal type and frequency of transient excitation on dispersion figures from forwarding analysis is studied to determine the most suitable excitation signal. The findings from this study can provide important theoretical guidance for MASW-based interfacial debonding detection for SCCS. Furthermore, they can be instrumental in optimizing both the sensor layout design and signal choice for experimental validation.

The change in mechanical properties of bond materials for micro-blades with the amount of lubricants (충진 윤활제의 첨가량에 따른 블레이드용 결합제의 기계적 특성)

  • Kim, Song-Hee
    • Journal of Industrial Technology
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    • v.28 no.A
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    • pp.195-198
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    • 2008
  • Graphite and $MoS_2$ were added respectively to the Cu/Sn bond materials of the same composition as a lubricant in order to find out the effect of lubricants on the mechanical properties and the increase in density of the sintered products for microblades. The addition of $MoS_2$ as a lubricant was more beneficial to strength, fracture toughness, and hardness as well as densification than graphite. $MoS_2$ seemed to be more effective in reducing the friction between the metallic powders and die wall during hot pressing process. Due to the better wettability of MoS2 with bond metal alloy, less amount of interfacial defects which is detrimental to mechanical properties use observed.

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HVOF Thermal Sprayed AISI316-WC Coating Layer on Stainless Steel for PEMFC Bipolar Plate (고분자 전해질 연료전지용 분리판으로서 스테인리스강에 HVOF 용사된 AISI316-WC 코팅층)

  • Nam, Dae-Geun
    • New & Renewable Energy
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    • v.4 no.1
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    • pp.31-36
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    • 2008
  • Stainless steels have been widely considered as metallic bipolar plates, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the bipolar plates and the electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

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Characteristic of HVOF AISI316-WC Coating Layer on Stainless Steel Separator for PEMFC (고분자 전해질 연료전지용 스테인리스강 분리판의 HVOF AISI316-WC 코팅층 특성)

  • Nam, Dae-Geun;Kang, Nam-Hyun;Park, Yeong-Do;Kim, Young-Seok
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.1-5
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    • 2008
  • Stainless steels have been widely considered as metallic separators, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the separators and electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

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Characterization of the effect of He+ irradiation on nanoporous-isotropic graphite for molten salt reactors

  • Zhang, Heyao;He, Zhao;Song, Jinliang;Liu, Zhanjun;Tang, Zhongfeng;Liu, Min;Wang, Yong;Liu, Xiangdong
    • Nuclear Engineering and Technology
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    • v.52 no.6
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    • pp.1243-1251
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    • 2020
  • Irradiation-induced damage of binderless nanoporous-isotropic graphite (NPIG) prepared by isostatic pressing of mesophase carbon microspheres for molten salt reactor was investigated by 3.0 MeV He+ irradiation at room temperature and high temperature of 600 ℃, and IG-110 was used as the comparation. SEM, TEM, X-ray diffraction and Raman spectrum are used to characterize the irradiation effect and the influence of temperature on graphite radiation damage. After irradiation at room temperature, the surface morphology is rougher, the increase of defect clusters makes atom flour bend, the layer spacing increases, and the catalytic graphitization phenomenon of NPIG is observed. However, the density of defects in high temperature environment decreases and other changes are not obvious. Mechanical properties also change due to changes in defects. In addition, SEM and Raman spectra of the cross section show that cracks appear in the depth range of the maximum irradiation dose, and the defect density increases with the increase of irradiation dose.

Modelling of Grain Boundary in Polysilicon Film for Photodetector Through Current-Voltage Analysis (광검출기용 다결정 실리콘 박막의 전도특성 분석을 통한 결정립계의 모형화)

  • Lee, Jae-Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.4
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    • pp.255-262
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    • 2020
  • Grain boundaries play a major role in determining device performance, particularly of polysilicon-based photodetectors. Through the post-annealing of as-deposited polysilicon and then, the analysis of electric behavior for a metal-polysilicon-metal (MSM) photodetector, we were able to identify the influence of grain boundaries. A modified model of polysilicon grain boundaries in the MSM structure is presented, which uses a crystalline-interfacial layer-SiOx layer- interfacial layer-crystalline system that is similar to the Si-SiO2 system in MOS device. Hydrogen passivation was achieved through a hydrogen ion implantation process and was used to passivate the defects at both interfacial layers. The thin SiOx layer at the grain boundary can enhance the photosensitivity of an MSM photodetector by decreasing the dark current and increasing the light absorption.

Characterization of Resistive Switching in PVP GQD / HfOx Memristive Devices (PVP GQD / HfOx 구조를 갖는 전도성 필라멘트 기반의 저항성 스위칭 소자 특성)

  • Hwang, Sung Won
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.1
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    • pp.113-117
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    • 2021
  • A composite active layer was designed based on graphene quantum dots, which is a low-dimensional structure, and a heterogeneous active layer of graphene quantum dots was applied to the interfacial defect structure to overcome the limitations. Increasing to 1.5~3.5 wt % PVP GQD, Vf changed from 2.16 ~ 2.72 V. When negative deflection is applied to the lower electrode, electrons travel through the HfOx/ITO interface. The Al + ions are reduced and the device dominates at low resistance. In addition, as the PVP GQD concentration increased, the depth of the interfacial defect decreased, and the repetition of appropriate electrical properties was confirmed through Al and HfOx/ITO. The low interfacial defects help electrophoresis of Al+ ions to the PVP GQD layer and the HfOx thin film. A local electric field increase occurred, resulting in the breakage of the conductive filament in the defect.