• Title/Summary/Keyword: Ionic strength

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The Electroresponse Properties of Alginate Films under the Electric Field (알지네이트 필름의 전기장 하에서의 응답 특성)

  • 김인중;강휘원;정창남
    • Polymer(Korea)
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    • v.27 no.3
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    • pp.195-200
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    • 2003
  • Alginate is a natural ionic polymer including numerous anionic groups and can be actuated by the ionic group under the electric field. The crosslinked alginate films were fabricated with CaCl$_2$. The thermal, mechanical and electroresponse properties of the films were investigated by thermogravimetric analysis, tensile and bending tests. The initial degradation and tensile strength increased according to the degree of crosslinking. Also, the swelling ratio of the films increased with decreasing degree of crosslinking and increasing pH due to free volume and electrostatic repulsion. The films actuated by an electric stimulus exhibited gentle and flexible action like a pendulum. In the electric field, the electric stimuli such as the applied voltage, ionic strength and kind of electrolyte solution had an effect on the electroresponse of the films. Alginate films with 5 wt% crosslinking agent showed the highest bending angle and reversible bending behavior. When the ionic strength of NaCl and KCl electrolyte solution was 0.1 M, the films showed the highest electroresponse. The bending behavior of the films increased with the applied voltage.

A Simple Approach to the Ionic-covalent Bond Based on the Electronegativity and Acid Strength of Cations. Part Two:Application to the Description of the Electronic Properties of Oxides

  • Josik Portier;Guy Campet
    • Journal of the Korean Chemical Society
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    • v.41 no.8
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    • pp.437-441
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    • 1997
  • The acid strngth of cations, determined with ICP (Ionic Covalent Parameter): ICP=log(P)-1.38x+2.07 where P is the polarizing power and X its electronegativity expresses the competition between the covalent and ionic forces. This concept, together with electronegativity, is used to describe the properties of oxides with various electronic properties (insulators, metals, degenerate semiconductors, superconductors).

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Treatment of Cu-EDTA by using Photocatalytic Oxidation Process - Comparison between UV Lamp and Solar Light - (광산화 공정을 이용한 Cu-EDTA 처리 - 인공 자외선램프와 태양광의 처리경향 비교 -)

  • Shin, In-Soo;Choi, Bong-Jong;Lee, Seung-Mok;Yang, Jae-Kyu
    • Journal of Korean Society on Water Environment
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    • v.21 no.1
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    • pp.66-72
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    • 2005
  • Effect of the pH, molar ratio of Cu(II)/EDTA, concentration of Cu(II)-EDTA and ionic strength on the photocatalytic oxidation(PCO) of Cu(II)-EDTA in solar light was studied in this work. Experimental results in this work were compared with previous results obtained with UV-lamp. In the kinetics, Cu(II)-EDTA decomposition was favorable below neutral pH. The removal of Cu(II) and DOC was favorable as $TiO_2$ dosage increased. The initial rate for the decomplexation of Cu(II)-EDTA linearly increased as the concentration of Cu(II)-EDTA increased. The removal of Cu(II) and DOC was not much affected by variation of ionic strength with $NaClO_4$ as a background ion while much reduction was observed in the presence of background ions having higher formal charges. The removal trend of Cu(II) and DOC with variation of ionic strength and concentration of Cu(II)-EDTA in solar light was similar with that in UV light. Variation of the molar ratio of Cu(II)/EDTA showed a negligible effect on the removal of both Cu(II) and DOC. However, removal of both Cu(II) and DOC was two-times greater than that previous results obtained with UV light.

Bubble Properties in Bubble Columns with Electrolyte Solutions (전해질용액 기포탑에서 기포특성)

  • Yoo, D.J.;Lim, D.H.;Jeon, J.S.;Yang, S.W.;Kang, Y.
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.543-547
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    • 2016
  • Bubble properties such as size (chord length) and rising velocity were investigated in a bubble column with electrolyte solutions, of which diameter was 0.152m and 2.5m in height, respectively. The size and rising velocity of bubbles were measured by using the dual electrical resistivity probe method. Effects of gas and liquid velocities and ionic strength of liquid phase on the size and rising velocity of bubbles were determined. The bubble size increased with increasing gas velocity but decreased with increasing liquid velocity or ionic strength of liquid phase. The rising velocity of bubbles increased with increasing gas velocity and decreased with increasing ionic strength of liquid phase, however, it showed a slight maximum value with varying liquid velocity. The size and rising velocity of bubbles were well correlated with operating variables.

Advanced Tenderization of Brine Injected Pork Loin as Affected by Ionic Strength and High Pressure

  • Kim, Honggyun;Ramachandraiah, Karna;Yun, Young Chan;Kwon, In Suk;Park, Ha Neul;Kim, Hack-Youn;Lee, Eun-Jung;Hong, Geun-Pyo
    • Food Science of Animal Resources
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    • v.40 no.6
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    • pp.1055-1065
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    • 2020
  • This study investigated the effects of brine injection and high hydrostatic pressure (HHP) on the quality characteristics of pork loin. Brine with ionic strength conditions (0.7% vs 1.5% NaCl, w/v) were injected into pork loins, and the meat was pressurized up to 500 MPa for 3 min. As a quality indicator, moisture content, color, cooking loss and texture profile analysis (TPA) of pork loins were estimated. Based on the results, brine with low ionic strength (0.7% NaCl) resulted in low injection efficiency and high cooking loss, although, it improved tenderness of pork loin at moderate pressure level (~200 MPa). While high ionic strength condition (1.5% NaCl injection) lowered the hardness of pork loins at relatively high HHP level (400-500 MPa), it also caused high cooking loss. To commercialize the brine injected pork loins, it was necessary to regulate brine compositions, which was not evaluated in this study. Nevertheless, the present study demonstrated that brine injection followed by moderate pressure (200 MPa) could improve the tenderness of pork loins without causing other major quality losses.

Comparison of Flocculation Characteristics of Humic Acid by Inorganic and Organic Coagulants: Effects of pH and Ionic Strength

  • Xu Mei-Lan;Lee Min-Gyu;Kam Sang-Kyu
    • Journal of Environmental Science International
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    • v.14 no.8
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    • pp.723-737
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    • 2005
  • The effects of pH (5, 7 and 9) and ionic strength of different salts on the flocculation characteristics of humic acid by inorganic (alum, polyaluminum chloride (PAC) with degree of neutralization, r=(OH/Al) of 1.7) and organic (cationic polyelectrolyte) coagulants, have been examined using a simple continuous optical technique, coupled with measurements of zeta potential. The results are compared mainly by the mechanisms of its destabilization and subsequent removal. The destabilization and subsequent removal of humic acid by PAC and cationic polyelectrolyte occur by a simple charge neutralization, regardless of pH of the solution. However, the mechanism of those by alum is greatly dependent on pH and coagulant dosage, i.e., both mechanisms of charge neutralization at lower dosages and sweep flocculation at higher dosages at pH 5, by sweep flocculation mechanism at pH 7, and little flocculation because of electrostatic repulsion between negatively charged humic acid and aluminum species at pH 9. The ionic strength also affects those greatly, mainly based on the charge of salts, and so is more evident for the salts of highly charged cationic species, such as $CaCl_2$ and $MgCI_2.$ However, it is found that the salts have no effect on those at the optimum dosage for alum acting by the mechanism of sweep flocculation at pH 7, regardless of their charge.

Evaluation of Electrokinetic Flow Mobility Using Isotacho-Electrophoresis Techniques

  • An, J.H.;Joo, Y.H.;Lee, C.Y.;Lee, Y.J.;Park, C.W.
    • Journal of Magnetics
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    • v.16 no.4
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    • pp.444-448
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    • 2011
  • In the present study, we separated the marker particles from the suspending particle mixture solution using isotacho-electrophoresis technique, a novel quantitative ionic particle separation method, in the microchannel. A multiple stacking zone of the suspending particle was visualized with variations in electric field strength, pH value and concentration of the ionic solution. In particular, the electrophoretic mobility of ionic particle (fluorescein) was estimated based on the electrophoretic velocity value measured by the particle image velocimetry. As a result, isotacho-electrophoresis zones were clearly visualized as going downstream in the electric field. The particle migration velocity increased proportional to the applied voltage increase; it was also affected by the pH value variations in the ionic solution.

Preformulation Study of Prokidin : Chemical Stability

  • Lee, Yun-Jin;Chun, In-Koo
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 2001.11a
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    • pp.88-88
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    • 2001
  • The effects of pH and temperature on the degradation of prokidn in various buffered aqueous solutions(pH 1.32~9.66) and temperatures (35, 45 and 6$0^{\circ}C$ were investigated. The effect of ionic strength on the degradation of prokidin was also measured by varying ionic strength (0.0466~1.5) at pH 1.35 and 45$^{\circ}C$ The effect of metal ions on the degradation of prokidin at pH 7.35 and 3.98 was observed. The degradation of prokidin followed the pseudo- first- order kinetics. The degradation rate of prokidin showed pH-dependent and temperature-dependent patterns. Prokidin was very stable at the pH below 3.95, where half-lives at 35, 45 and 6$0^{\circ}C$were 294, 206 and 107 day, respectively. However, it degraded very rapidly at pH above 6.49; the half-lives at 35, 45 and 6$0^{\circ}C$were 60, 25 and 13 day, respectively. As ionic strength increased, the degradation rate of prokidin increased. Some metal ions increased the degradation rate in the rank order of Mn > Fe > Cu >Fe On the other hand. other metal ions such as Bi, Ba. Zn, Ni, Co did not show unfavorable effect.

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Effect of pH and ionic strength on the removal of radionuclide by Na-mica (pH와 이온강도가 나트륨-운모를 이용한 방사성 핵종 흡착제거에 미치는 영향)

  • Seol, Bitna;Cho, Yunchul
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.1
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    • pp.83-89
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    • 2014
  • The aim of this study is to investigate the sorption/ion exchange of radioactive nuclides such as $Cs^+$ and $Sr^{2+}$ by synthetic Na-micas. In order to prepare Na-micas, two natural micas (phlogopite and biotite) were used as precursor materials. XRD, SEM, and EDS analyses were used to examine material characterization of synthetic Na-micas. Analyses of materials revealed that Na-micas were successfully obtained from natrual micas by K removal treatment. On the other hand, single solute (Cs or Sr) and bi-solute (Cs/Sr) sorption experiments were carried out to determine sorption capacity of Na-micas for Cs and Sr under different pH and ionic strength conditions. Uptake of Cs and Sr by micas in bi-solute system was lower than in single-solute system. Additionally, Langmuir and Langmuir competitive models were applied to describe sorption isotherm of Na-micas. bi-solute system was well described by Langmuir competitive models. For the results obtained in this study, Na-micas could be promising sorbents to treat multi-radioactive species from water and groundwater.

Interaction of NpO+2 with Cl- in Na-Ca-Cl-type solutions at ionic strength of 6M: Effect of presence of Ca ion on interaction

  • Nagasaki, Shinya;Saito, Takumi;Tsushima, Satoru;Goguen, Jared;Yang, Tammy
    • Nuclear Engineering and Technology
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    • v.49 no.8
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    • pp.1778-1782
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    • 2017
  • The interaction of $NpO^+_2$ with $Cl^-$ was studied using visible-near-infrared spectroscopy in $NaCl-Ca-Cl_2-NaClO_4$, $NaCl-NaClO_4$, and $CaCl_2-NaClO_4$ solutions with ionic strength (I) of 6M. The spectra of $NpO^+_2$ around 980 nm varied with $Cl^-$ concentration in the $NaCl-CaCl_2-NaClO_4$ and $NaCl-NaClO_4$ solutions at [$Cl^-$] ${\geq}3.5M$, but not in the $CaCl_2-NaClO_4$ solution. Assuming the 1:1 interaction between $NpO^+_2$ and $Cl^-$, the apparent equilibrium constants at I = 6M were evaluated. The presence of $Ca^{2+}$ was found to destabilize overall interaction between $NpO^+_2$ and $Cl^-$. The observations were consistent with the density functional theory calculation.