• 제목/요약/키워드: Iso-valeric acid

검색결과 20건 처리시간 0.021초

차량 내 미생물에 의해 생성되는 악취유발 화학물질의 분석 (Determination of Malodor-causing Chemicals Produced by Microorganisms Inside Automobile)

  • 박상준;김의용
    • KSBB Journal
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    • 제29권2호
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    • pp.118-123
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    • 2014
  • It was confirmed that malodor connected with an air-conditioner in an automobile is caused by microbial volatile organic compounds (MVOCs) produced by microorganisms getting into an air-conditioner when it is operating. Chemicals such as hydrogen sulfide, dimethyl sulfide, nbutyric acid, n-valeric acid, iso-valeric acid, n-octanol and toluene were detected above the odor threshold inside the automobile. The characteristics of a funky odor in the air blown into the automobile were due to detected sulfur compounds (hydrogen sulfide and dimethyl sulfide). Dimethyl sulfide was produced by microorganisms such as Aspergillus versicolor, Methylobacterium aquaticum, Herbaspirillum sp. and Acidovorax sp. In addition, the characteristics of a sour odor in the air blown into the automobile were due to detected organic acids (n-butyric acid, n-valeric acid and iso-valeric acid). N-valeric acid and iso-valeric acid were generated from Aspergillus versicolor, while iso-valeric acid was produced by Methylobacterium aquaticum. In addition, the odor intensity of the air blown into the automobile was affected by the concentration of detected sulfur compounds and organic acids. On the other hand, it is estimated that chemicals such as hydrogen sulfide, n-octanol and n-butyric acid detected in the air blown into the automobile were produced by non-identified species of microorganisms.

알코올 및 휘발성 유기산류가 뽕나무버섯의 균사속 생산에 미치는 영향 (Alcohols and Volatile Organic Acids as Stimulants of Rhizomorph Production by Armillaria mellea)

  • 홍재식;김명곤;이재홍;김형무
    • 한국균학회지
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    • 제18권3호
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    • pp.158-163
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    • 1990
  • 천마와 뽕나무버섯의 공생관계를 검토해 보고자 천마 중에 존재할 것으로 추측되는 저분자의 휘발성 성분들로 알코올류와 휘발성 유기산들이 뽕나무버섯의 균사속 생육에 미치는 영향을 검토하였고 또한 천마 중에 함유된 휘발성 유기산의 존재를 GC로 확인하였다. 각종 알코올류와 휘발성 유기산류 중 acetic acid와 methanol을 제외한 성분들은 뽕나무버섯의 균사속 생육을 촉진하였는데 이 중, 가장 큰 효과를 보인 것은 valeric acid와 ethanol이었으며 valeric acid는 0.1%(v/v)에서 ethanol은 1%(v/v) 수준의 농도에서 효과가 있었다. 이들 화합물들은 3일 간격으로 보충할 경우는 이 농도보다 훨씬 낮은 0.01%(v/v)에서 양호한 촉진효과를 볼 수 있었다. 또한 천마 중에 존재하는 휘발성 유기산류를 GC로 분석한 결과 propionic, iso-butyric, butyric, iso-valeric, valeric, iso-caproic, caproic 및 heptanoic acid 등이 함유되어 있음을 확인하였으며, 이들 중 가장 많은 함량을 차지하는 것은 valeric acid 이었다.

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피등어꼴뚜기의 자숙취에 관한 연구 (VOLATILE CONSTITUENTS OF COOKED SQUID)

  • 이응호;소천천추;야중순삼구
    • 한국수산과학회지
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    • 제11권4호
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    • pp.183-188
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    • 1978
  • 피등어꼴뚜기를 가열가공할 때 발생하는 취기를 제거할 목적으로 취기성분을 gas chromatography로 공석한 것을 단보로서 요약하면 다음과 같다. 1. 피등어꼴뚜기 취기성분 추출에는 methanol이 가장 적합하였다. 2. 빙수trap에서 25개 peak, dry ice-acetone trap에서 32개 peak가 검출되었고, 그 중 acetic acid, butyric acid, iso-valeric acid, valeric acid, caproic acid 등 5성분을 동정하였다. 3. 액체질소 trap의 head space vapor에서 11개 peak가 검출되었고, 그 중 mothylamine, trimethylamine, dimethylamine, ethylamine, isopropylamine등 5성분을 동정하였다.

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DL-1-Amino Alkyl Phosphonic Acid 와 그 유도체들의 합성 (ll) (Synthesus of DL-1-Amino Alkyl Phosphonic Acids and Their Derivatives (II))

  • 조경연;김덕찬;김용준
    • 대한화학회지
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    • 제15권5호
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    • pp.275-280
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    • 1971
  • Six previously unreported N-acylated-DL-1-amino alkyl phosphonic acids were prepared; N-Acetyl-DL-1-amino-3-methyl butyl phosphonic acidN-Benzoyl-DL-1-amino-2-methyl propyl phosphonic acidN-Benzoyl-DL-1-amino-3-methyl butyl phosphonic acidN-Benzoyl-DL-1-amino-2-methyl butyl phosphonic acidN-Acetyl-DL-1-amino-2-methyl propyl phosphonic acidN-Acetyl-DL-1-amino-2-methyl butyl phosphonic acidThe first four compounds were characterized, and the last two compounds were obtained in the crude oil state. The above three DL-1-amino-alkyl phosphonic acid were synthesized from iso-valeric acid, iso-caproic acid and ${\beta}$-methyl valeric acid using Hell-Volhard-Zelinsky reaction, the condensation reaction with triethyl-phosphite and the modified Curtius Reaction. Iso-caproic acid and ${\beta$-methyl valeric acid were prepared by the conventional methods.

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Deodorization of Pig Feces by Fungal Application

  • Kim, T.I.;Ham, J.S.;Yang, C.B.;Kim, M.K.
    • Asian-Australasian Journal of Animal Sciences
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    • 제17권9호
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    • pp.1286-1290
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    • 2004
  • This study was carried out to screen yeasts effective in reducing odor from pig feces. Three isolates from soil and compost sources were selected to treat pig feces. On the basis of morphological and biochemical characteristics, one isolate from compost was Candida rugosa, and two isolates from soil were Candida rugosa and Candida maris. These isolates showed deodorizing activity by reducing the concentration of ${NH}_3$ and R-${NH}_2$. Volatile fatty acids (VFA) are the specific malodorous compounds of pig feces, and the Candida maris from soil showed a 100% reduction of butyric, iso-butyric, and iso-valeric acid in 10% pig slurry medium. However, the Candida rugosa from compost showed a 100% reduction of butyric and iso-butyric acid while that from soil showed a 100% reduction of propionic, butyric acid and iso-valeric acid in the medium. Also, these yeasts were effective in reducing $NH_{4}-N$, soluble-N, and biological oxygen demand (BOD).

한국산(韓國産) 다엽(茶葉)의 특수성분(特殊成分)에 관(關)한 연구(硏究) (Studies on the Special Components of the Korean Tea-leaves)

  • 김동연;정지흔;김관;이종욱;박근형
    • Applied Biological Chemistry
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    • 제22권2호
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    • pp.97-100
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    • 1979
  • 다류제품(茶類製品)의 품질(品質)을 좌우(左右)하는 다엽(茶葉)의 tannin, caffeine을 지역별(地域別) 및 야생다엽(野生茶葉)과 재배다엽별(栽培茶葉別)로 5월(月), 7월(月), 9월(月)에 적채(摘采)하여 분석(分析) 비교(比較)하였고 2종(種)의 3번재배다엽(番栽培茶葉)의 향기성분(香氣成分)을 분석(分析)하여 다음과 같은 결과(結果)를 얻었다. 1. Tannin의 함량(含量)은 $10{\sim}14%$ 범위(範圍)로 타(他) 중국종(中國種)과 같은 양(量)이며 정채시기(摘采時期)가 1,2,3기(期)에 따라 점차 증가(增加)하였으며 지역간(地域間) 및 야생다엽(野生茶葉)과 재배다엽간(栽培茶葉間)의 차이(差異)는 없었다. 2. Caffeine의 함량(含量)은 $1.5{\sim}3%$의 범위(範圍)로 타(他) 중국종(中國種)과 같은 양(量)이며 지역간(地域間) 및 야생다엽(野生茶葉)과 재배다엽간(栽培茶葉間)의 차이(差異)는 없었다. 3. 향기성분(香氣成分)은 두 재배다엽간(栽培茶葉間)에 비슷한 pattern이며 32개(個)의 peak 중(中) phenol, iso-butyl aldehyde, n-butyl aldehyde, iso-valeraldehyde, n-butyl alcohol, iso-amyl alcohol, iso-valeric acid, benzaldehyde, n-valeric acid 및 linalool 의 10종(種)을 동정(同定)하였다.

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Relationship Linking Dietary Quercetin and Roughage to Concentrate Ratio in Feed Utilization, Ruminal Fermentation Traits and Immune Responses in Korean Indigenous Goats

  • Cho, Chi Hyun;Yang, Byung Mo;Park, No Seong;Lee, Hyung Suk;Song, Minho;Yi, Young Joo;Heo, Jung Min;Wickramasuriya, Samiru Sudharaka;Cho, Hyun Min;Lee, Soo Kee
    • 한국초지조사료학회지
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    • 제37권1호
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    • pp.10-18
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    • 2017
  • A total of nine Korean indigenous goats were used in a cross-over arrangement to give nine replicates per treatment, and they were housed individually assigned to 1 of 9 dietary treatments. Nine treatments were 0, 500, and 1000 ppm of quercetin supplementation in diets by mixing roughage and concentrate with different ratios (RC ratio) of 3:7 (RC 30), 5:5 (RC 50) and 7:3 (RC 70). Nutrient utilizations of dry matter, crude fat and NDF were not affected by neither RC ratio nor dietary quercetin (p>0.05), but the rate of crude protein and ADF increased in animals in RC 70 group regardless of quercetin supplementation (p<0.05). In addition, higher RC ratio increased (p<0.05) N retention and N retention rate. Total VFA, acetic acid, propionic acid, iso-butyric acid, butyric acid, iso-valeric acid and valeric acid contents were not affected (p>0.05) by dietary quercetin. Meanwhile, lower total cholesterol level exhibited in animals in RC 70 group compared to RC 30 or 50 groups, unrelated to dietary quercetin (p<0.05), however other plasma parameters were not influenced (p>0.05) by RC ratio and dietary quercetin. Our results indicated that both RC ratio and dietary quercetin may not directly affect the production indices and immune responses in Korean indigenous goat.

화학물질의 재현을 통한 악취발생원인 규명 (Investigation on the Cause of Malodor through the Reproduction of Chemicals)

  • 박상준;오영환;조보연;이재신;김의용
    • KSBB Journal
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    • 제29권5호
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    • pp.392-398
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    • 2014
  • It was confirmed that malodor connected with an air-conditioner in an automobile is caused by microbial volatile organic compounds (MVOCs) produced by microorganisms and through microorganisms coexisting with each other to form a biofilm on the evaporator surface. A bacterium, Methylobacterium aquaticum, can form a biofilm on the evaporator surface. The biofilm was composed of 45.79% C (Carbon), 42.36% O (Oxygen), 1.85% Na (Sodium), 5.42% Al (Aluminum), 1.39% P (Phosphorus), 0.74% Cl (Chlorine) and 2.45% K (Potassium). This result matches the composition of the biofilm formed on the surface of the used evaporator. It was determined that sulfur compounds (Hydrogen sulfide, Dimethyl sulfide) and organic acids (n-Butyric acid, n-Valeric acid, iso-Valeric acid) in the air which was blown into the automobile were generated by Methylobacterium aquaticum and Aspergillus versicolor, respectively. On the other hand, volatile organic compounds (Toluene, Xylene, 2-Ethylhexanol, 2-Phenyl- 2-propanol, Ethylbenzene) were not found. It is estimated that the reason is due to the low concentration of generated MVOCs or is caused by the change of some MVOCs depending on the nutrients (medium).

Effect of Dietary Protein Levels on Composition of Odorous Compounds and Bacterial Ecology in Pig Manure

  • Cho, Sungback;Hwang, Okhwa;Park, Sungkwon
    • Asian-Australasian Journal of Animal Sciences
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    • 제28권9호
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    • pp.1362-1370
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    • 2015
  • This study was performed to investigate the effect of different levels of dietary crude protein (CP) on composition of odorous compounds and bacterial communities in pig manure. A total of 48 male pigs (average initial body weight 45 kg) fed diets containing three levels of dietary CP (20%, 17.5%, and 15%) and their slurry samples were collected from the pits under the floor every week for one month. Changes in composition of odorous compounds and bacterial communities were analyzed by gas chromatography and 454 FLX titanium pyrosequencing systems, respectively. Levels of phenols, indoles, short chain fatty acid and branched chain fatty acid were lowest (p<0.05) in CP 15% group among three CP levels. Relative abundance of Bacteroidetes phylum and bacterial genera including Leuconostoc, Bacillus, Atopostipes, Peptonphilus, Ruminococcaceae_uc, Bacteroides, and Pseudomonas was lower (p<0.05) in CP 15% than in CP 20% group. There was a positive correlation (p<0.05) between odorous compounds and bacterial genera: phenol, indole, iso-butyric acid, and iso-valeric acid with Atopostipes, p-cresol and skatole with Bacteroides, acetic acid and butyric acid with AM982595_g of Porphyromonadaceae family, and propionic acid with Tissierella. Taken together, administration of 15% CP showed less production of odorous compounds than 20% CP group and this result might be associated with the changes in bacterial communities especially whose roles in protein metabolism.

시판 현미식초의 주정첨가 유무에 따른 휘발성 성분 및 관능적 특성 비교 (Volatile Compounds and Sensory Properties of Commercial Brown Rice Vinegars Fermented with and without Ethanol)

  • 윤성란;김귀란;이지현;이수원;정용진;여수환;최한석;권중호
    • 한국식품과학회지
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    • 제42권5호
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    • pp.527-532
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    • 2010
  • 시판 현미식초를 주정첨가 유무 발효방식에 따른 휘발성 성분 특성을 살펴보고자 SPME-GC 분석, 전자코 패턴 및 관능평가를 실시하였다. 그 결과, GC-MS 분석을 통한 현미식초의 향기성분분석에서 주정 무첨가 발효된 현미식초의 주된 휘발성 성분은 acetic acid, ethyl acetate, benzaldehyde, iso-valeric acid, phenylethyl alcohol, 2-phenylethyl acetate, acetoin, isobutyric acid 등으로 총 24종의 휘발성 성분이 확인되었다. 주정첨가 발효 현미식초의 주된 휘발성 성분은 acetic acid, ethyl acetate, 1-hexyl acetate, benzaldehyde, 2-phenylethyl acetate, phenylethyl alcohol 등으로 나타났으며, 총 16종의 휘발성 성분이 확인되었다. 전자코분석시 주정 무첨가 현미식초는 알코올 발효에 의한 다양한 향의 생성으로 초산 발효시에도 각각 다른 향미패턴이 나타남을 볼 수 있었으며, 주정첨가 현미식초는 주정에 의한 초산발효로 거의 유사한 향미패턴으로 나타나 주정첨가 유무에 따라 현미식초의향 패턴이 다소 상이함을 확인하였다. 자극취, 이취의 강도에 대한 관능평가에서는 주정 무첨가 발효된 현미식초가 다소 높게 나타났다. 따라서 주정첨가 유무의 발효방식은 현미식초의 향미에 영향을 미치는 것으로 확인되었다.