• Title/Summary/Keyword: J%2FS

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Application of a LIBS technique using femtosecond and nanosecond pulses for the CIGS films analysis (펨토초 및 나노초 레이저를 이용한 박막태양전지의 레이저 플라즈마 분광 분석)

  • Lee, S.H.;Choi, J.H.;Gonzalez, J.J.;Hou, H.;Zorba, V.;Russo, R.E.;Jeong, S.H.
    • Laser Solutions
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    • v.17 no.4
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    • pp.7-13
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    • 2014
  • In this work, the application of laser induced breakdown spectroscopy (LIBS) for the composition analysis of thin $Cu(In,Ga)Se_2$ (CIGS) solar cell films ($1-2{\mu}m$ thickness) is reported. For the ablation of CIGS films, femtosecond (fs) laser (wavelength = 343nm, pulse width = 500fs) and nanosecond (ns) laser (wavelength = 266nm, pulse width = 5ns) were used under atmospheric environment. The emission spectra were detected with an intensified charge coupled device (ICCD) spectrometer and multichannel CCD spectrometer for fs-LIBS and ns-LIBS, respectively. The calibration curves for fs-LIBS and ns-LIBS intensity ratios of Ga/Cu, In/Cu, and Ga/In were generated with respect to the concentration ratios measured by inductively coupled plasma optical emission spectrometry (ICP-OES).

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Concentration and Gas-particle Partition of PCDDs/Fs and dl-PCBs in the Ambient Air of Ansan Area (안산지역 대기 중 다이옥신 및 dl-PCBs의 오염특성 조사)

  • Heo, Jong-Won;Kim, Dong-Gi;Song, Il-Seok;Lee, Gang-Woong
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.5
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    • pp.517-532
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    • 2010
  • After establishment of Banwol industrial complex in 1987, Ansan city becomes the largest industrial sector development in Gyeonggi-do, Korea. As the population and industrial activity grow over this region, toxic air pollutants, particularly POPs (Persistent Organic Pollutants) from various emission sources have been major public concerns. Air samples for POPs monitoring were collected at the industrial sites ($A_2$), residential sites ($B_1$, $B_2$), commercial site (C), and rural/remote site (D) of the area of Ansan during 2008 with a prolonged industrial sampling site $A_1$ from 2001 to 2008. All samples were analysed for 2,3,7,8 substituted-polychlorinated dibenzo-p-dioxin and dibenzofurans (PCDD/Fs) and dioxin like polychlorinatd diphenyls (dl-PCBs). In site $A_1$, a steady decline of their concentrations from 2003 to 2008 was observed due to the reinforced emission guideline from waste incinerators. The average concentration of the PCDD/Fs and dl-PCBs ranged between 0.118 pg-TEQ/$m^3$ (rural/remote site D) and 0.532 pg-TEQ/$m^3$ (industrial area $A_2$). These level were generally consistent with previous studies in Gyeonggi-do, while higher than other places. Most of PCDD/Fs congener were partitioned into particle phase, whereas dl-PCBs were partitioned into gas phase. The logarithm of gas-particle partition coefficient $K_P$ of dl-PCBs and PCDD/Fs were well correlated with sub-cooled liquid vapor pressure $P_L$. The slope $m_T$ of log $K_P$ versus log $P_L$ for PCDD/Fs (-1.22) and dl-PCBs (-1.02) in industrial area ($A_2$) were high compared to other residential/commercial area. It suggests that this area was likely influenced by the direct emission source of PCDD/Fs and dl-PCBs. To simulate the partition of PCDD/Fs and dl-PCBs between gas and particle phase, Junge-Pankow model ($P_L$-base) and $K_{oa}$ model were applied. It was found that J-P model was more suitable than the $K_{oa}$ model in this study.

Numerical analysis of fs laser ablation of metals (금속의 펨토초 어블레이션의 수치해석)

  • Oh B.K.;Kim D.S.;Kim J.G.;Lee J.H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.657-658
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    • 2006
  • Although there are many numerical models to simulate fs laser ablation of metals, no model can analyze the ablation phenomena over a wide range of fluence. In this work, a numerical code for simulating the fs laser ablation phenomena of metals has been developed. The two temperature model is employed to predict the ablation rate and the crater shape of metals using phase explosion mechanism in the relatively high fluence regime. Also, the ultrashort thermoelastic model is used for the low fluence regime to account for spallation of the sample by high strain rate. It has been demonstrated that the thermoelastic stress generated within the sample can exceed the yield stress of the material even near the threshold fluence. Numerical computation results are compared with the experiment for Cu and Ni and show good agreement. Discussions are made on the hydrodynamic model considering phase change and hydrodynamic flow.

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Determination of PCDD/Fs in Disposable Diaper for Infant (유아용 일회용 기저귀의 다이옥신 분석)

  • Shin Jeoung Hwa;Ahn Yun Gyong;Seo Jung Ju
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.6
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    • pp.814-824
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    • 2005
  • This study analyzed and standardized the harmful substances of organic compounds(dioxins) in disposable diapers for infant's clothing. Commercial samples obtained from Korea, Japan, America and German were determined by HRGC/HRMS. Experimental Methods were consisted of comparision of extracting solvent, analysis of PCDD/Fs, and analysis of PCDD/Fs of extraction in disposable diaper. The results were as follows. No high TEQ values in TCDD(1), PCDD(0.5) and HxCDD(0.1) were found for commercial disposable diapers from country Korea, Japan, U.S.A and German. In extraction for 6hrs experiments, HpCDD and OCDD were detected in disposable diapers of U1, U2 and G2, respectively. In extraction fur 24hrs experiments, HpCDD, OCDD and OCDF were detected in disposable diapers of J3, U1, U2 and U3. So we need to set standards of measurement for harmful materials contained in textile goods. This will make a safe and comfortable clothing environment for all users, regardless of age.

Satellite Monitoring of Smoke Aerosol Plume during the Russian Fire Episode of May 2003 over Northeast Asia

  • Lee, Kwon H.;Kim, Young J.;Hoyningen-Huene, Wolfgang V.
    • Proceedings of the KSRS Conference
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    • 2003.11a
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    • pp.491-492
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    • 2003
  • The large amount of smoke produced near Lake Baikal was transported to Northeast Asia with high AOT (Aerosol Optical Thickness) as seen in satellite images. Aerosol retrieval using a separation technique was applied to MODIS (Moderate Imaging Spectroradiometer) and SeaWiFS (Sea-viewing Wide Field-of-view Sensor) data observed during 14-22 May 2003. Large AOT, 2.0~5.0 was observed on 20 May 2003 over Korea due to the influence of the long range transport of smoke aerosol plume from the Russian fires, resulting in high PM10 concentration was observed at the surface.

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Particle Acceleration by High Power (> TW) Femtosecond Lasers in Plasmas (고출력 펨토초 레이저와 플라즈마를 이용한 입자가속)

  • Suk, H.;Hafz, N.;Kim, C.B.;Kim, G.H.;Kim, J.U.;V. Kulagin;Lee, H.J.;Kim, J.C.;Ko, I.S.;Hahn, S.J.;Pae, G.H.
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.07a
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    • pp.62-62
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    • 2003
  • Charged particles can be accelerated to relativistic high energies by high power (> terawatt) laser beams. We have a research project on laser and plasma-based advanced accelerators in Center for Advanced Accelerators at Korea Electrotechnology Research Institute (KERI), in which the 2 TW (1.4 J/700 fs) Ti:sapphire/Nd:glass hybrid laser system and a He plasma will be used for particle acceleration experiments. In this presentation, we introduce the ongoing research activities and the planned experiments at KERI.

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Enhancement Pattern of the Normal Facial Nerve on Three - Dimensional (3D) - Fluid Attenuated Inversion Recovery (FLAIR) Sequence at 3.0 T MR Units (3.0T 자기공명영상기기에서 시행한 3D-FLAIR 영상에서의 정상 안면신경의 조영증강 양상)

  • Hyun, Dong-Ho;Lim, Hyun-Kyung;Park, Jee-Won;Kim, Jong-Lim;Lee, Ha-Young;Park, Soon-Chan;Ahn, Joong-Ho;Baek, Jung-Hwan;Choi, Choong-Gon;Lee, Jeong-Hyun
    • Investigative Magnetic Resonance Imaging
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    • v.16 no.1
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    • pp.25-30
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    • 2012
  • Purpose : To compare the enhancement pattern of normal facial nerves on 3D-FLAIR and 3D-T1-FFE-F) sequences at 3.0 T MR units. Materials and Methods: We assessed 20 consecutive subjects without a history of facial nerve abnormalities who underwent temporal bone MRI with contrast enhancement between January 2008 and March 2009. Two neuroradiologists independently reviewed pre-/post-enhanced 3D-T1-FFE-FS and 3D-FLAIR images respectively with 2-week interval to assess the enhancement of normal facial nerves divided into five anatomical segments. The degree of enhancement in each segment was graded as none, mild or strong, and the results of 3D-FLAIR and 3D-T1-FFE-FS image sets were compared. Results: On 3D-FLAIR images, one of the two reviewers observed mild enhancement of the genu segment in two (10%) subjects. On 3D-T1-FFE-FS images, at least one segment of the facial nerve was enhanced in 13 (65%) subjects. At least one reviewer found that 17 of the 100 segments showed enhancement on 3D-T1-FFE-FS images, with the mastoid segment being the most commonly enhanced. Interobserver agreement on 3D-T1-FFE-FS images was good for enhancement of the normal facial nerve (${\kappa}$= 0.589). Conclusion: In contrast to 3D-T1-FFE-FS, normal facial nerve segments rarely showed enhancement on 3D-FLAIR images.

The effect of irradiation on hydrodynamic properties of extraction mixtures based on diamides of N-heterocyclic dicarboxylic acids in heavy fluorinated diluents

  • Belova, E.V.;Skvortsov, I.V.;Kadyko, M.I.;Yudintsev, S.V.
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.1163-1168
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    • 2019
  • Hydrodynamic properties have been investigated for promising extraction systems: $0.05mol\;L^{-1}$ solutions of di(N-ethyl-4-ethylanilide) of 2,2'-bipyridine-6,6'-dicarboxylic acid, di(N-ethyl-4-fluoroanilide) of 2,6-pyridinedicarboxylic acid and di(N-ethyl-4-hexylanilide) of 2,2'-bipyridine-6,6'-dicarboxylic acid in meta-nitrobenzotrifluoride (F-3) or trifluoromethylphenyl sulfone (FS-13) diluents. To evaluate the perspectives for their use as extraction mixtures at the final stage of the nuclear fuel cycle, the change in density, viscosity, surface tension, and phase separation rate under irradiation with accelerated electrons was studied. The concentrations of extractants in the irradiated mixtures have been determined and the radiation-chemical yields have been calculated. Irradiation significantly decreases the phase separation rate at the stages of extraction and back extraction for all the studied systems. The viscosity of the DYP-7 solution in FS-13 increase above the values suitable for its use in extraction processes.

Numerical Analysis of Electromagnetic and Temperature Fields Induced by Femtosecond Laser Irradiation of Silver Nanowires (은 나노선 펨토초 레이저 조사에 의해 유도되는 전자기장 및 온도장 수치 해석)

  • Ha, Jeonghong;Kim, Dongsik
    • Laser Solutions
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    • v.18 no.1
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    • pp.12-17
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    • 2015
  • This work performed numerical analysis of electromagnetic field and thermal phenomena occurring in femtosecond laser irradiation of silver nanowires. The local electric field enhancement was computed to calculate the optical energy dissipation as a Joule heating source and the thermal transport was analysed based on the two-temperature model (TTM). Electron temperature increased up to 1000K after 50fs and its spatial distribution became homogeneous after 80fs at the fluence of 100mJ/cm2. The result of this work is expected to contribute to revealing the photothermal effects on silver nanowires induced by femtosecond laser irradiation. Although the highest increase of lattice temperature was substantially below the melting point of silver, the experimental results showed resolidification and fragmentation of the silver nanowire into nanoparticles, which cannot be explained by the photothermal mechanism. Further studies are thus needed to clarify the physical mechanisms.