• Title/Summary/Keyword: LB Technique

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Evaluation of Fatty Acid System LB Films by using a Quartz Crystal (수정진동자에 의한 지방산계 LB막의 누적평가)

  • Park, Man-Chul;Choi, Yong-Sung;Chang, Sang-Mok;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 1992.07a
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    • pp.498-500
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    • 1992
  • In this paper, we described a evaluating technique of deposition status of LB films by quartz crystal. As a deposited material for this experiments, arachidic acid and stearic acid were used. We observed the deposition status of LB films on the surface of quartz crystal. The experimental results showed that Y type H films are deposited according to frequency shift, deposition ratio, and SEM photographs etc.

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Study on Preparation of PAHPV LB Films and Their Luminescent Characterisrics (PAHPV LB막의 제작 및 그 발광 특성에 관한 연구)

  • Hwang, Jang-Hwan;Choo, Jung-Woo;Kim, Young-Kwan;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.2
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    • pp.71-79
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    • 1997
  • Ultra-thin films of poly[2-[4-(9-(10-phenyl)anthracenyl)phenoxy)hexyloxy]]-1,4-phenylenevinyleylene(PAHPV) were prepare-d on the hydrophilic ITO substrate by Langmuir-Blodgett(LB) technique. ${\lambda}_{max}$ in the photoluminescence spectrum of these films was 458nm at the excitation wavelength of 365nm before thermal treatment, which comes from diphenylanthracene side chain of PAHPV. It was also confirmed with UV-Vis spectrometer that ultra-thin LB films of PAHPV precursor polymer were prepared well. After thermal treatment for conjugation of PAHPV precursor polymer, ${\lambda}_{max}$ in the photoluminescence spectrum of these films changed to 365nm, which means that the conjugation of these PAHPV films was completed.

Electrical Properties of Amphiphillic Squarylium Dye Ultra Thin Films (양친매성 스쿠아릴리움색소 초박막의 전기적 특성)

  • Jeong, Soon-Wook
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.2
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    • pp.177-181
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    • 2003
  • Ultra-thin films of amphiphillic squarylium dye were prepared on the hydrophillic substrate by Langmuir-Blodgett(LB) technique. In this study, the photoelectric properties of a amphiphillic squarylium dye LB film was investigated. The visible light(${\lambda}$ = 684nm ) of xenon lamp was illuminated on the amphiphillic squarylium dye LB films and light absorptivity and photoconductivity were observed. The photoconductivity was nearly constant regardless of nominal layer number. The photoelectric properties of the amphiphillic squarylium dye LB films with bottom electrode showed better than that top electrode.

A Study of The NO$_2$Gas Detect Properties of N-docosyl pyridinium(TCNQ) LB Film (N-docosyl pyridinium(TCNQ) LB막의 NO$_2$가스탐지 특성에 관한 연구)

  • 유병호;조형근;김형석;이창희;김정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.75-78
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    • 1994
  • Organic ultra thin films about 500${\AA}$ in thickness are fabricated by LB(Langmuir-Blodgett) technique and their gas detect properties are investigated. The LB films deposited are made of the specimen named as N-docosyl pyridinium(TCNQ) and the deposition is verified by capacitance conductivity measurement. From the study of gas detect properties with I-V characteristics and UV spectrum we have found that their conductivities were increased about 3 times of magnitude and peaks of UV spectrum were decreased.

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Application of Layer-by-Layer Assembly in Triboelectric Energy Harvesting (마찰대전 기반의 에너지 하베스팅에서 다층박막적층법의 응용)

  • Habtamu Gebeyehu, Menge;Yong Tae, Park
    • Composites Research
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    • v.35 no.6
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    • pp.371-377
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    • 2022
  • Triboelectric nanogenerator (TENG) devices have generated a lot of interest in recent decades. TENG technology, which is one of the technologies for harvesting mechanical energy among the energy wasted in the environment, is obtained by the dual effect of electrostatic induction and triboelectric charging. Recently, a multilayer thin film stacking method (or layer-by-layer (LbL) self-assembly technique) is being considered as a method to improve the performance of TENG and apply it to new fields. This LbL assembly technology can not only improve the performance of TENG and successfully overcome the thickness problem in applications, but also present an inexpensive, environmentally friendly process and be used for large-scale and mass production. In this review, recent studies in the accomplishment of LbL-based materials for TENG devices are reviewed, and the potential for energy harvesting devices reviewed so far is checked. The advantages of the TENG device fabricated by applying the LbL technology are discussed, and finally, the direction and perspective of this fabrication technology for the implementation of various ultra-thin TENGs are briefly presented.

Electrochemical Study of Molecular Devices Using Functional LB Monomolecular Layer Compounds (신기능성 LB 단분자막을 이용한 분자소자의 전기화학적 연구)

  • Park, Soo-Gil
    • Applied Chemistry for Engineering
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    • v.2 no.4
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    • pp.311-329
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    • 1991
  • Electrochemical behavior of surface active Osmium bipyridine complex adsorbed in a monomolecular layer on tin oxide electrodes by the Langmuir-Blodgett method was studied. Theoretical equation of cyclic voltammetry of electrode reactions for redox species adsorbed as monolayer form was discussed by reversible and quasi-reversible waves. The film was transferred onto the $SnO_2$ electrode surface and then amounts of charge on the electrode were measured in the technique of cyclic voltammetry. The electron transfer mediation of these monolayer with $Fe^{2+}$, TEMPOL and others were studied. And the cyclic voltammetry were simulated by taking into account the interaction parameters. From these values, we found it possible to fit almost all measured cyclic voltammograms with these parameters. The recent works and directions using LB method were introduced with various applicable field.

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A Study on the Photoisomerization of Fatty Acid and Polyamic Acid Mixture (지방산과 폴리아미드산 혼합물의 광이성질화 현상에 관한 연구)

  • 박근호;박태곤
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.8
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    • pp.695-701
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    • 2002
  • Maxwell displacement current (MDC) measuring technique has been applied on the study of monolayers of fatty acid and polyamic acid mixture. The displacement current was generated from monolayers on the water surface by monolayer compression and expansion. Displacement current was generated when the area per molecule was about 132 $^2$and 115 $^2$just before the initial rise of the surface pressure during the 1st and 2nd mixed monolayer compressions cycle, respectively. Maxwell displacement currents were investigated in connection with mixed monolayer compression cycles. It was found that the maximum of MDC appeared at the molecular area just before the initial rise of surface pressure in compression cycles. Ultra thin film of fatty acid and polyamic acid mixture was prepared on the hydrophilic quartz plate by Langmuir-Blodgett (LB) method. The precursor LB film was heated in a vacuum dry oven at 12$0^{\circ}C$ in order to convert it into the LB film of polyimide. The absorption spectra of LB films were also induced photoisomerization by UV and visible light irradiation.

Electrical Properties of Molecular Diode Using Eicosanoic Acid Langmuir-Blodgett(LB) Monolayer Film (Eicosanoic Acid Langmuir-Blodgett(LB) 박막을 이용한 분자 다이오드의 전기적 특성)

  • Koo, Ja-Ryong;Lee, Ho-Sik;Kwon, Hyuck-Joo;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.2
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    • pp.148-153
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    • 2003
  • Electron transfer through an Langmuir-Blodgett(LB) monolayer film sandwiched between metal electrodes. We used an eicosanoic acid material and the material was very famous as a thin film insulating material. Eicosanoic acid monolayer was deposited by Langmuir-Blodgett(LB) technique and a subphase was a $CdCl_2$ solution as a 2${\times}10^{-4}$ mol/L. Also we used a bottom electrode as an Al/$Al_2O_3$ and a top electrode as a Al and Ti/Al. Here, the $Al_2O_3$ on the bottom electrode was deposited by thermal evaporation method. The $Al_2O_3$ layer was acted on a tunneling barrier and insulating layer in tunnel diode. It was found that the proper transfer surface pressure for film deposition was 25 mN/m and the limiting area per molecule was about 24 ${\AA}^2$/molecule. When the positive and negative bias applied to the molecular device, the behavior shows that a tunnel switching characteristics. This result were analyzed regarding various mechanisms.

Design and Application of Location Data Management System for LBS (LBS를 위한 위치 데이터 관리 시스템 설계 및 적용)

  • Ahn Yoon-Ae
    • Journal of Korea Multimedia Society
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    • v.9 no.4
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    • pp.388-400
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    • 2006
  • There are wireless location acquisition technique, LBS platform technique, and LBS application technique in the important technical elements of the LBS. In this paper, we design a location data management system which is the core base technique of the important technical elements of the LBS. The proposed system consist of an application interface of LBS, a query processor of application. service, a location estimator of the moving objects, a location information manager, a real-time data receiver, and a database of location data. This system manages efficiently the location change information of the moving objects using the database technique, suggests some useful inform to the users of LBS, and supports operation and facility of location estimation to process continuous location data of the moving objects. On the basis of location data triggering, this system supplements the problem of the related location data management systems to complement the loss of location data in the environment of real-time.

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Electronic Properties of MIM Structure Organic Thin-films that Manufacture by LB method (LB법으로 제작한 MIM 구조 유기 박막의 전자특성)

  • Choi, Young-Il;Lee, Kyung-Sup;Lim, Jung-Yeol;Song, Jin-Won
    • 전자공학회논문지 IE
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    • v.43 no.4
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    • pp.99-104
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    • 2006
  • The Langmuir-Blodgett(LB) technique has attracted considerable interest in the fabrication of electrical and electronic devices. Maxwell displacement current (MDC) measurement has been employed to study the dielectric property of Langmuir-films. MDC flowing across monolayers is analyzed using a rod-like molecular model. A linear relationship between the monolayer compression speed u and the molecular area Am. Compression speed a was about 30, 40, 50mm/min. Langmuir-Blodgett(LB)layers of Arachidic acid deposited by LB method were deposited onto slide glass as Y-type film. The structure of manufactured device is Au/Arachidic acid/Al, the number of accumulated layers are 9$\sim$21. Also, we then examined of the Metal-Insulator-Metal(MIM) device by means of I-V. The I-V characteristics of the device are measured from -3 to +3[V]. The insulation property of a thin film is better as the distance between electrodes is larger.