• Title/Summary/Keyword: Light-activated

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Investigation of degradation mechanism of phosphorescent and thermally activated delayed fluorescent organic light-emitting diodes through doping concentration dependence of lifetime

  • Song, Wook;Kim, Taekyung;Lee, Jun Yeob;Lee, Yoonkyoo;Jeong, Hyein
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.350-354
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    • 2018
  • Lifetime study of blue phosphorescent and thermally activated delayed fluorescent organic light-emitting diodes was carried out to understand the dominant degradation process during electrical operation of the devices. Doping concentration dependence of the phosphorescent and thermally activated delayed fluorescent organic light-emitting diodes was studied, which demonstrated long lifetime at low doping concentration in the phosphorescent devices and at high doping concentration in the thermally activated delayed fluorescent devices. Detailed mechanism study of the two devices described that triplet-triplet annihilation is the main degradation process of phosphorescent organic light-emitting diodes, whereas triplet-polaron annihilation is the key degradation factor of the thermally activated delayed fluorescent devices.

Light-activated mechanism for metal oxide gas sensors (금속 산화물 가스 센서의 광 활성화 센싱 메커니즘)

  • Oum, Wansik;Shin, Ka Yoon;Yu, Dong Jae;Kang, Sukwoo;Kim, Eun Bi;Kim, Hyoun Woo
    • Journal of Sensor Science and Technology
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    • v.30 no.6
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    • pp.381-383
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    • 2021
  • Light-activated metal oxide gas sensors have been investigated in recent decades. Light illumination enhances the sensing attributes, including the operational temperature, sensitivity, and selectivity. Unfortunately, high operating temperature is a major problem for gas sensors because of the huge energy consumption. Therefore, the importance of light-activated room-temperature sensing has increased. This paper reviews recent light-activated sensors and their sensing mechanisms with a specific focus on metal oxide gas sensors. Studies use the outstanding ZnO and SnO2 sensors to research photoactivation when illuminated by various sources such as ultraviolet (UV), halogen lamp, or monochromatic light. Photon induction generates electron-hole pairs that increase the number of adsorption sites of gas molecules and ions improving the sensor's sensing properties.

HARDNESS CHANGE OF LIGHT-ACTIVATED GLASS IONMER CEMENT WITH THICKNESS AND TIME (광경화형 글래스아이오노머 시멘트의 두께 및 시간경과에 따른 경도의 변화)

  • Lee, Kyoung-Jin;Oh, Won-Mann;Kim, Sun-Hun
    • Restorative Dentistry and Endodontics
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    • v.20 no.1
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    • pp.303-315
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    • 1995
  • An adequate and homogeneous cure of light-activated restroative material is very important for improvement of marginal adaptation and prevention of marginal leakage, secondary caries and pulpal irritation as well as expressing natural physical property of that material. The purpose of this study was to evaluate the change of surface hardness and cure uniformity of light-activated glass ionomer cements. Restorative(Fuji II LC, Vitremer) and lining(Baseline VLC, Vitrebond) light-activated glass ionomer cements were investigated for this study. The surface hardness of the top and bottom surfaces and cure uniformity of each 1mm, 1.5mm, 2mm, 2.5mm & 3mm in the thickness of specimen were measured immediately, at 1 hour, 24 hours and 1 week after light activation. The surface hardness change and cure uniformity of all the specimens were measured by Knoop hardness tester. The results were as follows. 1. The surface hardness of top and bottom surfaces in all groups increased with time(p<0.01). 2. Both top and bottom surfaces hardness of Vitrebond group measured immediately after light-activation were significantly lower than those of the other groups(p<0.01). 3. The surface hardness of top and bottom surfaces of restorative light -activated glass ionomer cements was higher than those of lining materials at 1 week(p<0.10). 4. Surface hardness of Vitremer group decreased as the specimen thickness increased, except top and bottom surfaces hardness of the specimen at 1 week(p<0.01). There was no significant difference in the surface hardness of Fuji II LC with changes in the thickness except bottom surface hardness of specimen at 24 hours and 1 week (p>0.05). 5. Surface hardness of Vitrebond group significantly decreased as the specimen thickness increased(p<0.01). There was no significant difference in the surface hardness of Baseline VLC group with changes in the thickness except bottom surface hardness of specimen measured immediately after light -activation(p>0.05). 6. The hardness ratio of top against bottom surface in all groups decreased with time(p<0.05). 7. There was no significant difference in the hardness ratio of top against bottom surface with changes of the thickness except Vitrebond group, 24 hours and 1 week of Vitremer group and 1 week of Baseline VLC group (p>0.05). These results suggest that surface hardness of restorative ligh-activated glass ionomer cements were highter than those of lining light-activated materials. In all groups, the surface hardness and cure uniformity continuously increased with time.

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Mitogen-Activated Protein Kinase Kinase 3 Is Required for Regulation during Dark-Light Transition

  • Lee, Horim
    • Molecules and Cells
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    • v.38 no.7
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    • pp.651-656
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    • 2015
  • Plant growth and development are coordinately orchestrated by environmental cues and phytohormones. Light acts as a key environmental factor for fundamental plant growth and physiology through photosensory phytochromes and underlying molecular mechanisms. Although phytochromes are known to possess serine/threonine protein kinase activities, whether they trigger a signal transduction pathway via an intracellular protein kinase network remains unknown. In analyses of mitogen-activated protein kinase kinase (MAPKK, also called MKK) mutants, the mkk3 mutant has shown both a hypersensitive response in plant hormone gibberellin (GA) and a less sensitive response in red light signaling. Surprisingly, light-induced MAPK activation in wild-type (WT) seedlings and constitutive MAPK phosphorylation in dark-grown mkk3 mutant seedlings have also been found, respectively. Therefore, this study suggests that MKK3 acts in negative regulation in darkness and in light-induced MAPK activation during dark-light transition.

Isolation and Characterization of a Mutant Defective in Light-activated Heterotrophic Groth from Synechocystis sp. PCC 6803 (Synechocystis sp. PCC 6803으로부터 광활성 종속영양 생장결핍 돌연변이체의 분리 및 특성)

  • Park, Mi-Seon;Lee, Young-Sook;Kim, Young-Chang
    • Korean Journal of Microbiology
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    • v.32 no.3
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    • pp.202-207
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    • 1994
  • A mutant strain PRM1 defective in light-activated heterotrophic growth was isolated from Synechocystis sp. PCC 6803. PRM1 could be grown at growth rate equivalent to Synechocystis 6803 under mixotrophic growth conditions. However, PRM1 could not be grown under light-activated heterotrophic conditions, in which a daily pulse of light for 5 min was given. These results suggest that PRM1 is not defective in heterotrophic metabolism, but in the transduction pathway of light signal essential to the growth. Plasmid patterns, absorption spectra of whole cells, and the exterior and interior structures of PRM1 were similar to those of Synechocystis 6803, except that PRM1 could not produce amorphous slime holding cells together.

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The Effect or Resin ann ruler Type on the compressive strength of Light-activated Composite Resins (광중합형 복합레진의 압축강도에 미치는 레진과 필러의 영향)

  • 원대희
    • Journal of Biomedical Engineering Research
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    • v.18 no.1
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    • pp.1-8
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    • 1997
  • This study was performed to evaluate the effect of resin and filler type on the compressive strength of light-activated composite resins. Experimental composite resins containing either amorphous spherical silica or crushed quartz in two matrix resins of BisGMA/TEGDMA and UTMA/TEGDMA were prepared and the specimens of 3 m in diameter and 6m in length were made. Compressive test was subjected to a crosshead speed of 0.5 mm/min, and the fracture surFaces were examined by SEM. The compressive strength of UTMA-based composite resin was higher than that of BisGMA-based composite resin. The loading rate of spherical silica was higher than that of crushed silica when the size dis- tribution of fillers was same. Strength decrease of Bis-GMA-based composite resin was severer than that of UTMA-based composite resin in a $37^{\circ}$c water environment. Fracture surface showed that the composite resin failure developed along the matrix resin and the filler/resin interface region.

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Relationship of Optical Density and Wavelength on Light Source for Activated Sludge Concentration (활성슬러지 농도에 따른 광학밀도와 광원파장의 상관관계)

  • Kim, Do-Han;Lee, Chang-Han;Wang, Bo-Kwon;Suh, Jung-Ho;Song, Seung-Koo
    • KSBB Journal
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    • v.25 no.1
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    • pp.67-72
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    • 2010
  • In this study, we developed a comprehensive correlation for better prediction of the activated sludge concentration in the relationship between measurement of optical density by the Beer's law and sludge properties. Effects of activated sludge properties, which are sludge types and anaerobic storage time, show that absorbance deviation for sludge properties decreased on wavelength of light source near to 950 nm. We also developed a method to measure limitation with non-linear correlation on the measurement of high concentration by the Beer's law using a double layer probe cell and empirical equations.

Preparation of CdS-AC/TiO2 Composites Designed for a High Photonic Effect and their Photocatalytic Activity Under Visible Light

  • Park, Chong-Yeon;Choi, Jong-Geun;Ghosh, Trisha;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.433-438
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    • 2011
  • In this study, CdS combined activated carbon/$TiO_2$ (CdS-AC/$TiO_2$) composites were prepared by a sol-gel method to improve the photocatalytic performance of $TiO_2$. These composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and UV-vis analysis. The photocatalytic activities were examined by the degradation of methylene blue (MB) under visible light irradiation. The photodegradation rate of MB under visible light irradiation reached 90.1% in 120 min. The kinetics of MB degradation was plotted alongside the values calculated from the Langmuir-Hinshelwood equation. The 0.2 CAT sample showed the best photocatalytic activity, which might be due to an increase in the photo-absorption effect by activated carbon and the cooperative effect of CdS.

A STUDY ON THE CHANGES IN POLYMERIZATION OF LIGHT-ACTIVATED COMPOSITE RESIN WITH VARIOUS EXPOSURE TIME AND DISTANCE (광중합형 복합레진의 중합시간과 거리에 따른 중합도의 변화)

  • Ahn, Myung-Ki;Jeong, Tae-Sung;Kim, Shin
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.2
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    • pp.293-299
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    • 2001
  • The aim of this study was to evaluate the effect of the distance of the light tip to the surface of restoration and exposure time on the polymerization of surface and 2mm below the surface of light-activated composite resins. Two light-activated composite resins were used. From the experiment, the following results were obtained. 1. Relative light intensity rapidly decreased when distance of the light tip to the surface of material is more than 2mm(p<0.05). 2. In all groups, microhardness was increased according to the increase of relative light intensity and exposure time(p<0.05). 3. The distance of the light tip to the surface of restoration and exposure time more affected 2mm below the surface rather than the surface(p<0.05). 4. Although exposure time was increased, difference of microhardness of the 2mm below the surface with the distance of the light tip to the surface of restoration was relatively high in Z100 between below 4mm and other groups and Z250 between below 2mm and other groups(p<0.05).

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Molecular Mechanism of Photic-Entrainment of Chicken Pineal Circadian Clock

  • Okano, Toshiyuki;Fukada, Yoshitaka
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.25-28
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    • 2002
  • The chicken pineal gland has been used for studies on the circadian clock, because it retains an intracellular phototransduction pathway regulating the phase of the intrinsic clock oscillator. Previously, we identified chicken clock genes expressed in the gland (cPer2, cPer3, cBmal1, cBmal2, cCry1, cCry2, and cClock), and showed that a cBMALl/2-cCLOCK heteromer acts as a regulator transactivating cPer2 gene through the CACGTG E-box element found in its promoter. Notably, mRNA expression of cPer2 gene is up-regulated by light as well as is driven by the circadian clock, implying that light-dependent clock resetting may involve the up-regulation of cPer2 gene. To explore the mechanism of light-dependent gene expression unidentified in animals, we first focused on pinopsin gene whose mRNA level is also up-regulated by light. A pinopsin promoter was isolated and analyzed by transcriptional assays using cultured chicken pineal cells, resulting in identification of an 18-bp light-responsive element that includes a CACGTG E-box sequence. We also investigated a role of mitogen-activated protein kinase (MAPK) in the clock resetting, especially in the E-box-dependent transcriptional regulation, because MAPK is phospholylated (activated) in a circadian manner and is rapidly dephosphorylated by light in the gland. Both pulldown analysis and kinase assay revealed that MAPK directly associates with BMAL1 to phosphorylate it at several Ser/Thr residues. Transcriptional analyses implied that the MAPK-mediated phosphorylation may negatively regulate the BMAL-CLOCK-dependent transactivation through the E-box. These results suggest that the CACGTG E-box serves not only as a clock-controlled element but also as a light-responsive element.

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