• 한국분말재료학회지
• /
• 제12권2호
• /
• pp.146-150
• /
• 2005

An optimum route to synthesize $Al_2O_3$-based composite powders with homogeneous dispersion of carbon nanotubes (CNTs) was investigated. CNTs/Metal/$Al_2O_3$ nanocomposite powders were fabricated by thermal chemical vapor deposition of $C_2H_2$ gas over metal/$Al_2O_3$ nanocomposite catalyst prepared by selective reduction of metal oxide/$Al_2O_3$ powders. The FT-Raman spectroscopy analysis revealed that the CNTs have single- and multi-walled structure. The CNTs with the diameter of 25-43 nm were homogeneously distributed in the metal/$Al_2O_3$ powders, and their characteristics were strongly affected by a kind of metal catalyst and catalyst size. The experimental results show that the composite powder with required size and dispersion of CNTs can be realized by control of synthesis condition.

• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
• /
• pp.422-423
• /
• 2006

Ultrasonic-milling of metal oxide nanopowders for the preparation of tungsten heavy alloys was investigated. Milling time was selected as a process variable. XRD results of metal oxide nanopowders ultrasonic-milled for 50 and 100h showed that mean crystallite size reduced with increasing milling time and there was no evidence of contamination or change of composition by impurities. It was found that nanocomposite powders reduced at $800^{\circ}C$ in $H_2$ atmosphere had a composition of 93.1W-4.9Ni-2.0Fe by EDX analysis. Hardness of sintered samples of 50 and 100h was 390 and 463 Hv, respectively, which corresponds to the hardness of commercial products.

• 한국분말재료학회지
• /
• 제17권3호
• /
• pp.203-208
• /
• 2010

A new High Frequency Induction Heating (HFIH) process has been developed to fabricate dense $Al_2O_3$ reinforced with Fe-Ni magnetic metal dispersion particles. The process is based on the reduction of metal oxide particles immediately prior to sintering. The synthesized $Al_2O_3$/Fe-Ni nanocomposite powders were formed directly from the selective reduction of metal oxide powders, such as NiO and $Fe_2O_3$. Dense $Al_2O_3$/Fe-Ni nanocomposite was fabricated using the HFIH method with an extremely high heating rate of $2000^{\circ}C/min$. Phase identification and microstructure of nanocomposite powders and sintered specimens were determined by X-ray diffraction and SEM and TEM, respectively. Vickers hardness experiment were performed to investigate the mechanical properties of the $Al_2O_3$/Fe-Ni nanocomposite.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
• /
• pp.278.1-278.1
• /
• 2014

Organic materials have been explored as the gate dielectric layers in thin film transistors (TFTs) of backplane devices for flexible display because of their inherent mechanical flexibility. However, those materials possess some disadvantages like low dielectric constant and thermal resistance, which might lead to high power consumption and instability. On the other hand, inorganic gate dielectrics show high dielectric constant despite their brittle property. In order to maintain advantages of both materials, it is essential to develop the alternative materials. In this work, we manufactured nanocomposite gate dielectrics composed of organic material and inorganic nanoparticle and integrated them into organic TFTs. For synthesis of nanocomposite gate dielectrics, polyimide (PI) was explored as the organic materials due to its superior thermal stability. Candidate nanoprticles (NPs) of halfnium oxide, titanium oxide and aluminium oxide were considered. In order to realize NP concentration dependent electrical characteristics, furthermore, we have synthesized the different types of nanocomposite gate dielectrics with varying ratio of each inorganic NPs. To analyze gate dielectric properties like the capacitance, metal-Insulator-metal (MIM) structures were prepared together with organic TFTs. The output and transfer characteristics of organic TFTs were monitored by using the semiconductor parameter analyzer (HP4145B), and capacitance and leakage current of MIM structures were measured by the LCR meter (B1500, Agilent). Effects of mechanical cyclic bending of 200,000 times and thermally heating at $400^{\circ}C$ for 1 hour were investigated to analyze mechanical and thermal stability of nanocomposite gate dielectrics. The results will be discussed in detail.

• 한국재료학회지
• /
• 제32권11호
• /
• pp.458-465
• /
• 2022

Interest in the use of semiconductor-based photocatalyst materials for the degradation of organic pollutants in a liquid phase has grown, due to their excellent performance and response to the light source. Herein, we fabricated a NiO-SiC-TiO₂ ternary structured photocatalyst which had reduced bandgap energy, with strong activation under UV-light irradiation. The synthesized samples were examined using XRD, SEM, EDX, TEM, DRS, EIS techniques and photocurrent measurement. The results confirmed that the two types of metal oxides were well bonded to the SiC fiber surface. The junction of the new photocatalyst exhibited a large number of photoexcited electrons and holes. The holes tended to oxidize the water and form a hydroxyl radical, which promoted the decomposition of methylene blue. The close contact between the 2D SiC fiber and metal oxide semiconductors expanded the scope of absorption wavelength, and enhanced the usability of the ternary photocatalyst for the degradation of methylene blue. Among three synthesized samples, the NiO-SiC-TiO₂ showed the best photocatalytic effect, and was considered to have excellent photoelectron transfer due to the synergy effect between the metal oxide and SiC.

• 한국분말재료학회지
• /
• 제14권2호
• /
• pp.101-107
• /
• 2007

Ultrasonic-milling of metal oxide nanopowders for the preparation of tungsten heavy alloys was investigated. Milling time was selected as a major process variable. XRD results of metal oxide nanopowders ultrasonic-milled for 50 h and 100 h showed that agglomerate size reduced with increasing milling time and there was no evidence of contamination or change of composition by impurities. It was found that nanocomposite powders reduced at $800^{\circ}C$ in a hydrogen atmosphere showed a chemical composition of 93.1W-4.9Ni-2.0Fe from EDS analysis. Hardness of sintered part using 50 h and 100 h powder samples was 399 Hv and 463 Hv, respectively, which is higher than the that of commercial products (330-340 Hv).

• 한국결정성장학회지
• /
• 제19권4호
• /
• pp.202-207
• /
• 2009

본 연구에서는 $Fe/Al_2O_3$ 및 $Fe/TiO_2$계 나노복합분말을 제조하기 위하여 실온 기계적 합금화법(MA)을 적용하였다. $Fe_3O_4-M$(M= AI, Ti)이고 여기서 순금속 Al 및 Ti은 고상반응 시 환원제로서 선택하였다. $Fe_3O_4$-순금속의 각각 25시간 및 75시간 MA 처리한 결과 $Fe/Al_2O_3$ 및 $Fe/TiO_2$ 나노복합분발이 얻어졌으며, 이것은 나노결정립의 ${\alpha}$-Fe 기지에 $Al_2O_3$ 및 $TiO_2$가 각각 미세하게 분산된 나노복합분말임을 알 수 있었다. 또한 Fe$_3$O$_4$-AI계에서 보다 짧은 반응 시간에 복합분말이 생성되는 것은 $Fe_3O_4$의 Al에 의한 환원반응 시 큰 반응열에 기인하는 것으로 사료된다. MA법으로 제조된 $Fe/TiO_2$ 복합분말의 X선 회절분석으로부터 ${\alpha}$-Fe 결정립 크기는 30 nm 임을 알 수 있었다. 또한 MA 과정 중 시료의 자기 측정으로부터 $Fe_3O_4$의 순금속 Al 및 Ti 에 의한 고상환원반응 과정을 자세히 관찰할 수 있었다.

• 한국재료학회지
• /
• 제15권8호
• /
• pp.503-507
• /
• 2005

Microstructure and wear behavior of A1203-based nanocomposites with Cu and Ni-Co dispersions were investigated. $Al_2O_3/Cu$ and $Al_2O_3/Ni-Co$ nanocomposites were fabricated by hydrogen reduction and sintering method using metal oxide and metal nitrates. The nanocomposites showed increased mechanical properties compared with monolithic $Al_2O_3$. In particular, high toughness and hardness were measured for the $Al_2O_3/Ni-Co$ nanocomposite consolidated by spark plasma sintering. A minimum value of wear coefficient comparable to the monolithic $Al_2O_3$ was obtained for $Al_2O_3/Ni-Co$ nanocomposite. Wear behavior is discussed in terms of microstructure and mechanical properties of nanocomposites

• 공업화학
• /
• 제26권5호
• /
• pp.521-525
• /
• 2015

2차원 구조와 우수한 물성을 지닌 그래핀 기반의 전극 재료들은 슈퍼커패시터에 많이 응용되어 왔다. 특히 3차원 구조의 그래핀 소재들은 전극 제조에 매우 중요한데 이는 3차원 구조가 넓은 표면적, 효과적이고 빠른 전기 및 이온 전달, 우수한 기계적 물성을 제공하기 때문이다. 최근에는 3차원 하이브리드 구조를 가지는 그래핀/금속 산화물 재료들이 슈퍼커패시터의 에너지와 파워 밀도를 동시에 증가시키고자 개발되어 왔다. 본 논문은 그래핀과 금속 산화물로 이루어진 3차원 나노복합체의 최근 연구 경향을 논하고자 한다. 3차원 나노복합체의 제조와 구조 및 이를 이용한 슈 퍼커패시터의 응용을 다룬다.

• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
• /
• pp.1572-1575
• /
• 2005

Poly(vinyl phenol)(PVP)/$TiO_2$ nanocomposite the films have been prepared incorporating metal alkoxide with vinyl polymer to obtain high dielectric constant gate insulating material for a organic thin film transistor. The surface composition, the morphology, and the thermal and electrical properties of the hybrid nanocomposite films were observed by ESCA, scanning electron microscopy (SEM), atomic force microscopy(AFM), and thermogravimetric analysis (TGA). Thin hybrid films exhibit much higher dielectric constants (7.79 at 40wt% metal alkoxide).