• Journal of Environmental Health Sciences
• /
• v.44 no.3
• /
• pp.238-243
• /
• 2018

Objectives: The purpose of this study was to determine skin adhesion rate of children's modeling clay for exposure assessment. Methods: Children's modeling clays were classified into 10 categories as PVA clay, PVA soft clay, starch-based clay, foam clay, rubber clay, oil clay, muddy clay, terra clay, paper clay and slime. A total of 26 children's clay goods was selected. Moisture content (%) and hardness of clays were measured. Five adults aged 20 to 25were recruited for experiment. Gravimetric difference of modeling clay was determined after 3 minutes playing time. Skin adhesion rate ($g/min/cm^2$) was estimated bythe amount of skin adhesion per minute (g/min) and each individual's palm surface area ($cm^2$). Results: Twenty four of the 26 children's modeling clay products were adhesive to skins. Two products of foam and rubber clay were not adhered to skin. For the 24 products, the average skin adhesion rate was $5.5{\times}10^{-4}{\pm}4.0{\times}10^{-4}g/min/cm^2$. The highest skin adhesion rate was $1.3{\times}10^{-3}{\pm}4.4{\times}10^{-4}g/min/cm^2$ for paper clay. The lowest skin adhesion rate was $4.6{\times}10^{-5}{\pm}1.1{\times}10^{-4}g/min/cm^2$ for oil clay. The skin adhesion rate was increased with increase of moisture content. Adhesion rates of some clays were varied by person and testing trials. Conclusion: The study determined skin adhesion rate of children's modeling clay. The adhesion rate is useful for exposure and risk assessments and setting safety guideline to protect children's health.

• Korean Journal of Computational Design and Engineering
• /
• v.4 no.1
• /
• pp.12-18
• /
• 1999

A deformable non-Uniform Rational B-Spline (NURBS) based volume is programed for the force reflecting exoskeleton haptic device. In this work, a direct free form deformation (DFFD) technique is applied for the realistic manipulation. In order to implement the real-time deformation, a nodal mapping technique is used to connect points on the virtual object with the NURBS volume. This geometric modeling technique is ideally incorporated with the force reflecting haptic device as a virtual interface. The results in this work introduce details for the complete set-up for the realistic virtual clay modeling task with force feedback. The force reflecting exoskeleton haptic manipulator, coupled with a supporting PUMA 560 manipulator and the virtual clay model are integrated with the graphics display, and results show that the force feedback from the realistic physically based virtual environment can greately enhance the sense of immersion.

• Nuclear Engineering and Technology
• /
• v.51 no.4
• /
• pp.1047-1059
• /
• 2019

This work describes the development of a numerical module with a multiphysics structure to simulate the thermo-hydro-chemo-mechanical behavior of compacted bentonites. First, the conceptual model, based on the state-of-the-art formulation for clay-based engineered barriers in deep geological repositories, is described. Second, the advantages of multiphysics-based modules are highlighted. Then, the guidelines to develop a code using such tools are outlined, presenting an example of implementation. Finally, the simulation of three tests that illustrate the behavior of compacted bentonites assesses the scope of the developed code. The satisfactory results obtained, and the relative simplicity of implementation, show the opportunity of the modeling strategy proposed.

• Transactions of Materials Processing
• /
• v.1 no.1
• /
• pp.5-10
• /
• 1992

• Journal of Environmental Health Sciences
• /
• v.48 no.1
• /
• pp.36-43
• /
• 2022

Background: Preservatives are used to prevent product deterioration in modeling clay. Parabens, a representative preservative, have been found to be endocrine disruptors and cause skin irritation and allergic reactions. Isothiazolinone preservatives can be irritating to the skin, respiratory tract, and eyes. Thorough investigation and regulation of clay are necessary because clay is marketed to children, who are more sensitive to the toxic effect of chemicals. Objectives: In this study, the presence of 16 preservatives was analyzed in modeling clay and the results were compared with current standards. Methods: A total of 200 samples were collected from 28 children's clay products sold in South Korea (13 from Korea and 15 imported from overseas). Twelve preservatives, such as parabens, were analyzed using high-performance liquid chromatography (HPLC). Isothiazolinone preservatives (chloromethylisothiazolinone; CMIT, methylisothiazolinone; MIT, octylisothiazolinone; OIT, and benzisothiazolinone; BIT) were analyzed using ultra performance liquid chromatography-tandem mass spectrometery (UPLC-MS/MS). Results: Dehydroacetic acid (DHA) was detected the most in the clays at 51.50% (103 cases) detection; 38 cases (median 190.42 ㎍/g) in Korean products and 65 cases (median 169.62 ㎍/g) in Chinese products. CMIT, which is prohibited in Korea, was detected in 14 (median 16.28 ㎍/g) Chinese products. OIT, which has a chemical structure similar to CMIT was found in 28 (median 68.38 ㎍/g) samples in Korean products. Conclusions: The use of CMIT and MIT in children's products is prohibited in Korea and the European Union (EU). The detection of CMIT in Chinese clay products suggests that management is necessary for imported products. It is necessary to review the safety and regulatory status for OIT because OIT was used as a substitute for CMIT and MIT in Korean products.

• Economic and Environmental Geology
• /
• v.43 no.2
• /
• pp.185-196
• /
• 2010

Clay veins that occurred in a slope by hydrothermal alteration, can significantly affect its slope stability. The effect of clay veins on the slope stability was investigated by numerical modeling study. Various parameters such as cohesion, internal friction angle, orientation, groundwater level, rainfall intensity and duration, have been modelled. As shear strength increased, factor of safety increased. As groundwater level developed, factor of safety decreased. For the case of slip surface developed on interface, factor of safety was lower than that for case of slip surface developed on either weathered soil or clay vein. The effect of various soil types of the slope stability was also investigated by simulating seepage through the slopes with various soils. The groundwater level significantly increased on the slopes with silty and generic soils. For the slope with sandy soil, almost no change in groundwater level was observed due to rapid drainage.

• Geomechanics and Engineering
• /
• v.10 no.6
• /
• pp.827-836
• /
• 2016

The rate of softening is an important factor to determine whether the failure occurs along localized shear band or in a more diffused manner. In this paper, strength loss and softening rate effect depending on sensitivity are investigated for weakly cemented clays, for both artificially cemented high plasticity San Francisco Bay Mud and low plasticity Yolo Loam. Destructuration and softening behavior for weakly cemented sensitive clays are demonstrated and discussed through multiple vane shear tests. Artificial sensitive clays are prepared in the laboratory for physical modeling or constitutive modeling using a small amount of cement (2 to 5%) with controlled initial water content and curing period. Through test results, shear band thickness is theoretically computed and the rate of softening is represented as a newly introduced parameter, ${\omega}_{80%}$. Consequently, it is found that the softening rate increases with sensitivity for weakly cemented sensitive clays. Increased softening rate represents faster strength loss to residual state and faster minimizing of shear band thickness. Uncemented clay has very low softening rate to 80% strength drop. Also, it is found that higher brittleness index ($I_b$) relatively shows faster softening rate. The result would be beneficial to study of physical modeling for sensitive clays in that artificially constructed high sensitivity (up to $S_t=23$) clay exhibits faster strain softening, which results in localized shear band failure once it is remolded.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2005.03a
• /
• pp.232-239
• /
• 2005

Recently geosynthetics that can be constructed on soft ground have been used for reinforcement and separation in various ways. Through laboratory model tests and numerical analysis, in this study, estimated the suitability of cable elements and appropriate input factors considering loading effect in modeling of geosynthetics. First, in laboratory model tests, geosynthetics were constructed on the clay, and covered with the thickness, 7.5cm of sand mat. And then static and dynamic model tests were performed measuring loading, settlement, ground lateral displacement, and displacements of geosynthetics, but, for cyclic loading, bearing capacity increased linearly with stiff slop because cyclic loading with constant cyclic pressure compacted the ground. Numerical analysis were performed with FLAC 4.0 2D using Mohr-Coulomb and Modified Cam-Clay models, and they compared with the results of model tests. Cable elements of FLAC in modeling geosynthetics couldn't consider the characteristics of geosynthetics that increase shear strength between geosynthetics and clay according to the loading increase. Therefore, in this study, appropriate equation that can consider loading effects in Cable elements was proposed by Case Study.

• Geomechanics and Engineering
• /
• v.14 no.1
• /
• pp.43-50
• /
• 2018

Applicability of constructing piled raft foundations on soft clay has been given attention in recent years. Lack of sufficient stiffness for soil and thus excessive settlements to allow higher contribution of piles is the major concern in this regard. This paper presents a numerical investigation of performance of piled-raft foundations on soft clay with focusing on a case study. A 3D FEM numerical model is developed using ABAQUS. The model was calibrated by comparing physical and numerical modeling results of other researchers. Then the possibility of using piled-raft system in construction of foundation for a water storage tank in Sarbandar, Iran is assessed. Soil strength parameters in the numerical model were calibrated using the instrumentation data of a heavily instrumented preloading project at the construction site. The results indicate that choosing the proper combination of length and spacing for piles can lead to acceptable differential and total settlements while a high percentage of total bearing capacity of piles can be mobilized, which is an efficient solution for the project. Overall, the construction of piled-rafts on soft clays is promising as long as the total settlement of the structure is not imposing restrictions such as the common 25 mm allowable settlement. But instead, if higher allowable settlements are adopted, for example in the case of rigid steel tanks, the method shall be applicable with considerable cost savings.

• Journal of the Korean Geotechnical Society
• /
• v.15 no.6
• /
• pp.17-28
• /
• 1999

In order to analyze effects of strain rate on consolidation of natural clay, this paper presents a nonlinear elasto viscoplastic model in which viscoplastic behavior is modeled by a unique effective stress-strain-strain rate relationship (equation omitted). The predicted values using numerical analysis are compared with measured ones in several laboratory tests such as creep test, multistage load test, and relaxation test for Berthierville clay. It is possible to estimate consolidation behavior of natural clay with reasonable accuracy using the proposed nonlinear viscoplastic model.