• Title/Summary/Keyword: Modification

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Preconcentration and Determination of Trace Cobalt and Nickel by the Adsorption of Metal-PDC Complexes on the Anion-Exchange Resin Suspension (금속-PDC 착물의 음이온교환 수지 상 흡착에 의한 흔적량 코발트와 니켈의 동시 예비농축 및 정량)

  • Han, Chul-Woo;In, Gyo;Choi, Jong-Moon;Kim, Sun Tae;Kim, Young-Sang
    • Analytical Science and Technology
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    • v.13 no.5
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    • pp.608-615
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    • 2000
  • A determination method of trace nickel and cobalt in water samples was studied and developed by adsorbing their complexes on ion exchange resin suspension. The analytical ions were formed as complexes with a ligand of APDC (ammonium pyrrolidinedithiocarbamate) and adsorbed on anion exchange resin of Dowex 2-X8. After the suspension was filtered out with membrane filter, the complexes were dissolved in HCl solution by an ultrasonic vibrator for ET-AAS determination. Several conditions were optimized as followings. pH of sample solution: 5.0, amount of ligand APDC: more than 430 times in mole ratio, the type and concentration of acid: 0.1 M HCl, and vibration time: 7 minutes. The addition of palladium in the HCl solution could improve the reproducibility and sensitivity by a matrix modification in the absorbance measurement. This procedure was applied for the analysis of three kinds of real water samples. The detection limits equivalent to 3 times standard deviation of blank were Co 0.36 ng/mL and Ni 0.27 ng/mL and recoveries in spiked samples were 99-102% for cobalt and 100-105% for nickel.

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Preparation and properties of gelatin from conger eel skin (붕장어껍질로부터 젤라틴의 제조 및 그 특성)

  • Ihm, Chi-Won;Kim, Poong-Ho;Kim, Jin-Soo
    • Applied Biological Chemistry
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    • v.39 no.4
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    • pp.274-281
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    • 1996
  • To prepare edible skin gelatin of conger eel such as material fur quality improvement of surimi gel, the defatted skin was limed with 1% calcium hydroxide at $5^{\circ}C$ for 2 days, washed thoroughly with tap water, extracted with 8 volumes of distilled water to dehydrated skin for 2 hours at $50^{\circ}C$. The gelatin extract was centrifuged, filtered and then passed through anion(Amberlite 200C) and cation (Amberlite IR 900) resins. The purified gelatin solution was evaporated and dried by hot-air blast$(40^{\circ}C)$. The gelatin prepared by above condition had the highest quality as revealed by physical property values i.e. 240.5 g in gel strength, $28.0^{\circ}C$ in melting point and $28.0^{\circ}C$ in gelling point. Funtional property values were 56.8% in solubility, 1.8 ml/g in oil binding capacity, 55.0% in emulsifying capacity and 48.5% in emulsifying stability. jelly strength and senso교 evaluation of surimi gel from fish with red muscle were not improved by addition of emulsifying curd from conger eel skin gelatin as emulsifier. Therefore, the conger eel skin gelatin requires a suitable modification of functional group and improvement of processing operation to utilize as a material for quality Improvement of surimi gel.

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Stratigraphy of the Central Sub-basin of the Gunsan Basin, Offshore Western Korea (한국 서해 대륙붕 군산분지 중앙소분지의 층서)

  • Kim, Kyung-min;Ryu, In-chang
    • Economic and Environmental Geology
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    • v.51 no.3
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    • pp.233-248
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    • 2018
  • Strata of the Central sub-basin in the Gunsan Basin, offshore, western Korea were analyzed by using integrated stratigraphy approach. As a result, five distinct unconformity-bounded units are recognized in the basin: Sequence I (Cretaceous or older(?)), Sequence II (Late Cretaceous), Sequence III (late Late Cretaceous or younger(?)), Sequence IV (Early Miocene or older(?)), Sequence V (Middle Miocene). Since the late Late Jurassic, along the Tan-Lu fault system wrench faults were developed and caused a series of small-scale strike-slip extensional basins. The sinistral movement of wrench faults continued until the Late Cretaceous forming a large-scale pull-apart basin. However, in the Early Tertiary, the orogenic event, called the Himalayan Orogeny, caused basin to be modified. From Late Eocene to Early Miocene, tectonic inversion accompanied by NW strike folds occurred in the East China. Therefore, the late Eocene to Oligocene was the main period of severe tectonic modification of the basin and Oligocene formation is hiatus. The rate of tectonic movements in Gunsan Basin slowed considerably. In that case, thermal subsidence up to the present has maintained with marine transgressions, which enable this area to change into the land part of the present basin.

Removal of Microcystis aeruginosa using polyethylenimine-coated alginate/waste biomass composite biosorbent (양이온성 고분자(polyethylenimine)가 코팅된 알지네이트/폐바이오매스 복합 흡착소재를 사용한 유해 미세조류 Microcystis aeruginosa의 제거)

  • Kim, Hoseon;Byun, Jongwoong;Choi, In Tae;Park, Yun Hwan;Kim, Sok;Choi, Yoon-E
    • Korean Journal of Environmental Biology
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    • v.37 no.4
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    • pp.741-748
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    • 2019
  • As the occurrence of harmful algal blooms (HABs) have become severe in precious water resources, the development of efficient harmful algae treatment methods is considering as an important environmental issue for sustainable conservation of water resources. To treat HABs in water resources, various conventional physical and chemical methods have been utilized and showed treatment efficiency, However, these methods can lead to discharging of cyanotoxins into the water bodies by chemical or physical algal cell lysis or destruction. Thus, to overcome this limitation, the development of safe HABs treatment methods is required. In the present study, adsorption technology was investigated for the removal of harmful algal species, Microcystis aeruginosa from aqueous phases. Industrial waste biomass, Corynebacterium glutamicum biomass was valorized as biosorbent (PEI-modified alginate/biomass composite fiber; PEI-AlgBF) for M. aeruginosa through immobilization with alginate matrix and cationic polymer (polyethylenimine; PEI) coating. The functional groups characteristic of PEI-Alg was determined using FT-IR analysis. By adsorption process used PEI-AlgBF, 52 and 67% of M. aeruginosa could be removed under the initial density of M. aeruginosa 200×104 cells mL-1 and 50×104 cells mL-1, respectively. As the increasing surface area of PEI-AlgBF, the removal efficiency was increased. In addition, we could find that adsorptive removal of M. aeruginosa has occurred without any M. aeruginosa cell lysis and destruction.

Fine Structural Modification of Mouse Ovarian Tissue by Irradiation of 6 MeV LINAC Radiation (6 MeV LINAC 방사선 조사에 의한 생쥐 난소조직의 미세구조 변화)

  • Yoon, Chul-Ho;Moon, Myung-Jin
    • Applied Microscopy
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    • v.33 no.2
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    • pp.117-130
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    • 2003
  • This research investigates the fine structural as well as the morphological changes of the mouse ovarian tissue after irradiation of various dose rates of 6 MeV LINAC radiation. The normal structure of the ovarian tissue is consisted of various stages of follicles including primordial and growing follicles, and ovarian stromal connectives. When we observed the ovarian tissues irradiated with a dose rate of 200 cGy/min using light and electron microscopes, granular cells in growing follicles are in irregular shape unlike normal follicles. Small segments of cells scattered in follicular antrum among granular cells. We could observe neutrophils and macrophages around the segments, which means the cells already got in the process of decease owing to the effects radiation. With coincident to the increase of the dose rate of x-ray irradiation as 400 or 600 cGy/min, the mature follicles appeared as an irregular form and the granular cells surrounding oocyte also deformed comparing to their normal counterparts. The granulosa cells within mature follicle are already occurred necrotic change and apoptosis. The nuclei in some cells got so fragmented that the segments formed the shape of a horseshoe or scattered in small and condensed pieces. All the cells at a granular layer irradiated with a dose rate of 600 cGy/min show typical characteristics of apoptosis. The neutrophils involved in inflammatory reaction appear evidently in follicular antrum of growing follicles, and macrophage scattered with residual and apoptotic bodies.

Fluorination of Polymethylmethacrylate (PMMA) Film and Its Surface Characterization (폴리메틸메타아크릴레이트(PMMA) 필름의 불소화 및 그 표면특성)

  • Jung, Min-Jung;Lim, Jae-Won;Park, In-Jun;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.317-322
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    • 2010
  • In this study, poly(methyl methacrylate) (PMMA) was treated with changing mixing ratios of $F_2$ and $O_2$ using oxyfluorination method for hydrophilic modification of PMMA film. For the characterizations of oxyfluorinated PMMA surface, contact angle, surface free energy, X-ray photoelectron spectroscopy (XPS) and optical transmittance (UV-vis) were carried out. After the oxyfluorination, PMMA surface became more hydrophilic showing the decrease of water contact angle from $69^{\circ}$ to $44^{\circ}$. So, surface free energy of oxyfluorinated PMMA film was increased from 46 to $58\;mN\;m^{-1}$. These results are attributed to hydrophilic functional groups such as hydroxyl group formed oxyfluorination method on the PMMA surface. From XPS results, it was confirmed that O/C concentration ratio on the surface of PMMA was increased, the amount of C-OH bonding which shows hydrophilicity was also largely increased from 6.7 to 24.8% with increasing fluorine partial-pressure via the oxyfluorination, The oxyfluorination conditions, room temperature, 1 bar with one mixture ratio of $F_2$ to $O_2$ had little influence on optical transmittance properties of PMMA film but enhanced its surface hydrophilicity. This result suggests that oxyfluorination method could be useful to change hydrophobic PMMA surface to hydrophilic.

Effects of Oxyfluorination on Surface Graft Polymerization of Low Density Polyethylene Film and Its Surface Characteristics (함산소불소화가 저밀도 폴리에틸렌 표면의 그라프트 중합 및 그 표면 특성에 미치는 영향)

  • Yun, Seok-Min;Woo, Sang-Wook;Jeong, Eui-Gyung;Bai, Byong-Chol;Park, In-Jun;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.343-348
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    • 2010
  • The surface of low density polyethylene (LDPE) film was oxyfluorinated under different reaction conditions to introduce hydroperoxide groups and change surface characteristics. Hydroperoxide functional groups created by oxyfluorination were used as active sites for graft polymerization with hydrophobic monomer, acryl amide (AM), and hydrophilic monomer, methyl methacrylate (MMA) to carry out the second modification of the LDPE film surface. The surface properties of the OFPE films and grafted OFPE films were characterized by 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging method, ATR-IR, contact angle measurement and DSC. From the results of DPPH method, the amount of hydroperoxide groups on the oxyfluorinated LDPE film continuously increased as the total pressure in the oxyfluorination and the partial pressure of fluorine gas increased. The water contact angle and surface free energy measurements showed that hydrophilic liquid (water) contact angle on LDPE film surface decreased with hydrophilic AM grafting and hydrophobic liquid (methylene diiodide) contact angle on LDPE film surface decreased with hydrophobic MMA grafting. These were attributed to AM or MMA monomer grafting and the wettability of LDPE filmsurface to hydrophilic and hydrophobic liquids were improved.

Comparative Analysis of Fish Fauna and Community Structures Before and After the Artificial Weir Construction in the Mainstreams and Tributaries of Yeongsan River Watershed (영산강 수계의 본류 및 지천에서 4대강 사업 전.후의 어류분포 및 군집구조 특성 비교)

  • Lee, Jae Hoon;Han, Jeong-Ho;Lim, Byung Jin;Park, Jong-Hwan;Shin, Jae-Ki;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.46 no.1
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    • pp.103-115
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    • 2013
  • The purpose of this study was to analyze fish fauna and species compositions along with trophic guilds, tolerance indicators, and fish community conditions before weir construction (BWC) and after weir construction (AWC) in the Yeongsan River watershed. Total 45 and 44 fish species were sampled in BWC and AWC, respectively without any distinct differences through weir constructions. Fish fauna analysis revealed that the dominant species was the same, Zacco platypus with 24.3% and 20.8% in BWC and AWC, respectively. However, the subdominant species were Carassius auratus with 8.9% in BWC but Opsarichthys uncirostris amurensis with 20.3%, almost identical that of the dominant species AWC. This phenomenon showed the distinct modification of species composition in the watershed. We sampled the $1^{st}$ class endangered species, Liobagrus obesus in tributary stream as previously reported. Also Culter brevicauda was sampled in the mainstream of Yeongsan River watershed and this was the first sampled record in this watershed. One of the most important features were an increase of exotic species, such as Micropterus salmoides and Lepomis macrochirus, with 3.2% BWC vs. 10.2% AWC as well as the increase in tolerant species with 49.2% BWC vs. 73.7% AWC, indicating ecological degradation through weir construction. Overall, our results indicated that fish fauna and composition analyses showed distinct ecological degradations related to increases of exotic and tolerant species AWC. Further long-term studies of fish monitoring should be conducted in the future to configure existent status of river conditions and to provide key information in order to conserve the healthy ecosystem.

Detecting on Optimal Seeding and Harvesting Dates of Whole Crop Maize via Meta Data (사일리지용 옥수수의 메타자료를 이용한 적정 파종 및 수확시기의 탐색)

  • Jo, Hyun Wook;Kim, Si Chul;Kim, Moon Ju;Kim, Ji Yung;Jo, Mu Hwan;Kim, Byong Wan;Sung, Kyung Il
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.40 no.1
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    • pp.66-72
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    • 2020
  • This study aimed to discuss the optimal seeding and harvesting dates with growing degree days(GDD) via meta-data of whole crop maize(WCM). The raw data (n=3,152) contains cultivation year, cultivars, location, seeding and harvesting dates collected from various reports such as thesis, science journals and research reports (1982-2012). The processing was: recording, screening and modification of errors; Then, the final dataset (n=121) consists of seeding cases (n=29), and harvesting cases (n=92) which were used to detect the optimum. In addition, the optimal periods considering tolerance range and GDD also were estimated. As a result, the optimum seeding and harvesting periods were 14th April ~ 3rd May and 15th August ~ 4th September, respectively; where, their GDDs were 23.7~99.6℃ and 1,328.7~1,602.1℃, respectively. These GDDs could be used as a judge standard for selecting the seeding and harvesting dates.

An Efficient Disk Sharing Technique supporting Single Disk I/O Space in Linux Cluster Systems (리눅스 클러스터 시스템에서 단일 디스크 입출력 공간을 지원하는 효율적 디스크 공유 기법)

  • 김태호;이종우;이재원;김성동;채진석
    • Journal of KIISE:Computing Practices and Letters
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    • v.9 no.6
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    • pp.635-645
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    • 2003
  • One of very important features that are necessarily supported by clustered parallel computer systems is a single I/O system image in which users can access both the local and remote I/O resources transparently. In this paper, we propose an efficient disk sharing technique supporting a single disk I/O system image architecture. The design separates the I/O subsystem of a cluster into the file system and a set of virtual hard disk drivers. The virtual hard disk driver deals with a hard disk in the remote node as a local hard disk. All services provided by it are performed in the device driver level without any modification of file systems. Users can, therefore, access all the disks in the cluster regardless of their locations. Our virtual hard disk driver is implemented under the linux, and also tested in a linux cluster system. We find by experiments that it can successfully support a single disk I/O space, and at the same time it shows better performance than NFS. We are sure that this paper can be a guideline for single I/O space of other devices to be easily constructed.