• Korean Journal of Crystallography
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• v.6 no.1
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• pp.27-35
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• 1995

The crystal structure of 1-tert-butoxycarbonyl-4-[N-(tert-butoxycarbonyl)-N-(ethoxycarbonylmethyl)amino]-3-phenylsulfonylpyrrolidind [C24H36O8N2S] has been from single crystal x-ray diffraction study ; C24H36O8N2S triclinic, p1, a=11.363(8)Å, b=11.589(6)Å, c=11.013(10)Å,α=95.32(6)°,β=98.64(7)°,γ=79.57(5)°,V=1406.8(18)Å3, t=293K, Z=2, CuKα(λ=1.5418Å). The molecular structure was solved by diredt method and refined by full-matrix least squares to a final R=9.78% for 3621 unique observed [F≥4σ(F)] reflections and 703 paramenters.

• Korean Journal of Materials Research
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• v.10 no.8
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• pp.540-544
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• 2000

The effect of atmospheric annearling on the densification and electrical poperty of the Ca-doped $YCrO_3$were investigated. In order to study the densification and elecrical properties of $Y_{0.7}Ca_{0.3}CrO3$ the sample sintered at $1700^{\circ}C$ for 12hrs were subsequently annealed at $1400^{\circ}C$ under various atmospheres($O_2$, Air, $N_2$)as a function of time. The density of $Y_{0.7}Ca_{0.3}CrO3$ was $4.5/cm^3$ before annealing. Under the $N_2$ annealingm the bulk density of $Y_{0.7}Ca_{0.3}CrO3$ was increased to $4.9g/cm^3$ at 24hrs and then remained unchanged at 48hrs. When $Y_{0.7}Ca_{0.3}CrO3$nwas annealing at $1400^{\circ}C$ for 12hrs and 24hrs under $O_2$ activation energies were about 0.16eV at 12hrs and 24hrs, and showed 0.167eV below 400K, and 0.24eV over 400K at 48hrs.

• Bulletin of the Korean Chemical Society
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• v.24 no.2
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• pp.249-252
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• 2003

• Investigative Magnetic Resonance Imaging
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• v.10 no.1
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• pp.20-25
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• 2006

Purpose : To evaluate the NMR relaxation properties of newly developed high performance paramagnetic complexes. Materials and methods : 4-aminomethylcyclohexane carboxylic acid (0.63g, 4 mmol) was mixed with the suspension solution of DMF (15mL) and DTPA-bis-anhydride (0.71g, 2 mmol) to synthesize the ligand. The ligand was then mixed with Gd2O3 (0.18g, 0.5 mmol) to synthesize Gd-chelate. For the measurement of magnetic relaxivity of paramagnetic compounds, the compounds were diluted to 1mM and then the relaxation times were measured at 1.5T(64 MHz). Inversion-recovery pulse sequence was employed for T1 relaxation measurement and CPMG(Carr-Purcell-Meiboon-Gill) pulse sequence was employed for T2 relaxation measurement. Using MATLAB(Version 7.1) program, T1 magnetic relaxation map, R1 map, T2 magnetic relaxation map and R2 map were developed to represent magnetic relaxation time and magnetic relaxivity as image. Results : Compared to $R1=4.9mM^{-1}sec^{-1}$ and $R2=4.8mM^{-1}sec^{-1}$ of Omniscan (Gadodiamide), which is commercially available paramagnetic MR agent, R1 of SUK090(Gd-C32H74N5O24) was $12.46mM^{-1}sec^{-1}$ and R1 of SUK091(Gd-C34H78N5O24) was $12.77mM^{-1}sec^{-1}$. However, R1 of SUK092(Gd-C30H56N5O17) was decreased to $2.09mM^{-1}sec^{-1}$. In case of R2, SUK090(Gd-C32H74N5O24) was $8.76mM^{-1}sec^{-1}$ and SUK091(Gd-C34H78N5O24) was $7.60mM^{-}1sec^{-1}$ whereas SUK092(Gd-C30H56N5O17) was decreased to $1.82mM^{-1}sec^{-1}$. Conclusion : Among three new paramagnetic complexes, SUK090(Gd-C32H74N5O24) and SUK091(Gd-C34H78N5O24) showed higher T1, T2 magnetic relaxation rates than that of commercially available paramagnetic MR agent and thus expected to have more contrast enhancement effect.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2009.05a
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• pp.192-193
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• 2009

CrN 코팅막은 고온에서 치밀한 Cr2O3 확산방지막을 형성함으로 $800^{\circ}C$까지 기계적성질을 유지할 수 있다. 본 실험에서는 Ar, N2, 그리고 $O_2$ 가스 분위기에서 AIP(Arc Ion Plating) 기법에 의해 다양한 조성의 Cr-O-N 박막을 Si(200)과 AISI 304 기판 위에 증착되었다. Cr-O-N 코팅막은 47.4at% 미만의 산소함량을 포함 할 때까지 B1구조를 유지하였고 코팅막 내 산소함량 24.6at%에서는 강한 XRD peak intensification을 나타내었다. 47.4at%에서는 결정상을 전혀 찾아볼 수 없는 전이구조를 나타내었고, 그 이상의 산소함량에서는 Cr22O3 결정상을 나타내었다. Cr-O(17at%)-N 조성의 코팅막에서는 (200)배향의 Grain 크기 증가 및 압축잔류응력이 증가하였으나, 그 이상의 산소함량에서는 점차 감소하였다. Cr-O(24.6at%)-N 조성의 코팅막이 가장 높은 경도를 나타내었고, 산소함량이 증가할수록 점차 향상된 마찰특성을 보였다.

• Applied Chemistry for Engineering
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• v.5 no.1
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• pp.24-29
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• 1994

The zeolite X was prepared from the Korean natural clinoptilolite, which contains some mordenite. Thermal treatment removed the clinoptilolite structure from the ore remaining mordenite. The natural clinoptilolites dealuminated with 2N-8N HCI solution and/or thermal treatment were mixed with NaCl, $NaAlO_2$ and NaOH, and reacted to zeolites X at $95^{\circ}C$ for 12~36 hrs. Maximum yield of NaX was obtained for the reactant mixture of 25 gr of natural zeolite acidtreated with 8 N HCI, together with 3.5g NaCl, 8g $NaAlO_2$ and 50 ml of 6N NaOH at $95^{\circ}C$, for 24 hrs.

• Journal of IKEEE
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• v.24 no.4
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• pp.1117-1121
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• 2020

In this work, it was confirmed that a SnO2 catalyst deposited by an atomic layer deposition(ALD) process can be employed in AlGaN/GaN heterostructure FET to detect NO2 gas. The fabricated HFET sensors on AlGaN/GaN-on-Si platform demonstrated that the devices with or without n-situ SiN have sensitivity of 5.5 % and 38 % at 200 ℃, respectively with response to 100 ppm-NO2.

• Journal of Korean Society for Atmospheric Environment
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• v.13 no.5
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• pp.397-410
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• 1997

An annular denuder filter pack sampling system (ADS) was used to collect acidic air pollutants in Pusan. During the study period (from June 1995 to November 1995), forty eight samples were collected every 12 hours starting from 6:00 in the morning. These samples were devided into two sets of data for day (6:00 a.m.-6:00 p.m.) and night (6:00 p.m.-6:00 a.m.). The chemical species were analyzed for HN $O_3$, HN $O_2$, S $O_2$ and N $H_3$ in the gas Phase, and N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$ and N $H_4$$^{+}$ in the particulate phase. The mean concentrations measured from this study were 0.24, 1.91, 30.07 and 4.24 $\mu\textrm{g}$/㎥ for HN $O_3$, HN $O_2$, S $O_2$ and N $H_3$, respectively. The mean concentrations of N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$ and N $H_4$$^+{\ulcorner}$ were 1.95, 7.36 and 3.48 $\mu\textrm{g}$/㎥, respectively. The mean concentrations of gaseous species except for HN $O_2$ were higher in daytime than in nighttime, but the reverse was true in the particulates except for N $H_4$$^{+}$. +/..

• Korean Journal of Soil Science and Fertilizer
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• v.25 no.1
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• pp.38-43
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• 1992

A field experiment was conducted to find out the effect level of nitrogen fertilization on the yield and quality of hop (Hallertau variety) emphasis given to ${\alpha}$-acid content. Nitrogen was applied by the rates of 0, 12, 18, 24, 30 and 36kg per 10a. Results were summarized as follows. 1. Stages of cone-hair developing and coneripening were delayed with increment of nitrogen applied. Number of nodes and length of vine increased with nitrogen applid by up to 24kg N/10a. 2. Yield was the highest in the 24kg N/10a plot and cone weight had high significant correlations with yield without regard to the years of growth. No.of flower per side blanch and weight of 100 cones had a significant correlation with yield in the four-year old and five-year old Hop plants. 3. Nutrient content in Hop plants was in the order of CaO, total nitrogen, $K_2O$, MgO and $P_2O_5$. Content of total nitrogen, CaO and MgO was high in leaves while that of $P_2O_5$ and $K_2O$ was high in cone. Nitrogen, phosphorus and magnesium increased with increment of nitrogen fetilized while potassium and calcium decreased. 4. As for the distribution of nutrients in cone developing stage $SiO_2$ content was higher in lower part than in the upper part while $P_2O_5$ contetn was higher in upper part than in lower part of the plant. And content of nitrogen and potassium was higher in middle height than in upper and lower part. 5. The optimum levels of nitrogen application were 19.3kg for 2 years, 24.3kg for 3-year, 27.9kg for 4 years and 31.8kg/10a for 5-year old Hop, respectively. 6. Nitrogen uptake in cone showed a positive correlation with the content of ${\alpha}$-acid and ${\beta}$-acid in cone.

• Journal of the Chungcheong Mathematical Society
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• v.24 no.2
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• pp.267-271
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• 2011

Let 0 < s < 1. For $f^{\ast}$ representing the symmetric radial decreasing rearrangement of f, we build up a fractional version of Polya-$Szeg{\ddot{o}}$ inequality: $${\int}_{\mathbb{R}^n}{\mid}(-\Delta)^{s/2}f^{\ast}(x){\mid}^2dx{\leq}{\int}_{\mathbb{R}^n}{\mid}(-\Delta)^{s/2}f(x){\mid}^2dx$$.