• Title/Summary/Keyword: Nano-composite epoxy

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Dielectric Properties of Epoxy/Micro-sized Alumina Composite and of Epoxy/Micro-sized/Nano-sized Alumina Composite

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.6
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    • pp.338-341
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    • 2015
  • Epoxy/micro-sized alumina composite was prepared, and the effects of alumina content on the dielectric properties were investigated in order to develop an insulation material for gas-insulated switchgears (GIS). Nano-sized alumina (average particle size: 30 nm) was also incorporated into the epoxy/micro-sized alumina composite. Dielectric tests were carried out in ASTM D 150, and capacitance (Cp) and dielectric loss (tanδ) were measured. The dielectric constant increased with increasing alumina content in the epoxy/micro-alumina system and the epoxy/micro-alumina/nano-alumina system. As 1,3-diglycidyl glyceryl ether (DGE) content increased, the dielectric constant decreased and dielectric loss increased. This ocurred as a result of the weak electric field enhancement due to homogeneous dispersion of micro- and nano-sized alumina particles in an epoxy composite.

Effect of Nano-silicate on the Mechanical, Electrical and Thermal Properties of Epoxy/Micro-silica Composite

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.3
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    • pp.153-156
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    • 2012
  • In order to develop electrical insulation materials, epoxy/micro-silica composite (EMC) and epoxy/micro-silica/nano-silicate composite (EMNC) were prepared, and their tensile and flexural strength, AC insulation breakdown strength and thermal conductivity and thermal expansion coefficient were compared. Nano-silicate was prepared in an epoxy matrix by our AC electric field process. All properties of the neat epoxy were improved by the addition of micro-silica, which was improved much further by the addition of nano-silicate to the EMC system.

AC Electrical and Mechanical Properties of Epoxy-Nano-Microsilica Mixed Composites for Eco-Friendly GIS Spacer (친환경 GIS Spacer용, 에폭시-나노-마이크로실리카 혼합 콤포지트의 교류 전기적, 기계적 특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.9
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    • pp.1181-1188
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    • 2018
  • In order to develop new insulating materials for GIS Spacer using environmentally friendly insulating gas, three kinds of dispersed liquid nano composites of solid epoxy /nano layered silicate filled material were prepared. And the epoxy/nano/micro silica composite was prepared by mixing epoxy/nano 3 phr dispersion/4 kinds of filler contents(40,50,60, 70wt%). The electrical insulation breakdown strengths of the nano and nano/micro mixed composites were evaluated by using 8 kinds of samples including the original epoxy. The mechanical tensile strength of the epoxy / nano / micro silica composite were evaluated, also. The TEM was measured to evaluate the internal structure of nano/micro composites. As a result, it was confirmed that the layered silicate nano particles was exfoliated through the process of inserting epoxy resin between silicate layers and the layers. In addition, dispersion of nano / micro silica resulted in improvement of electrical insulation breakdown strength with increase of filling amount of dense tissue with nanoparticles inserted between microparticles. In addition, the tensile strength showed a similar tendency, and as the content of microsilica filler increased, the mechanical improvement was further increased.

Permittivities of the Carbon Nano Fiber/Epoxy Composite According to the Dispersion Methods (분산 방법에 따른 카본 나노 섬유/에폭시 복합재료의 유전율)

  • 김태욱;김진봉;공진우;정재한;김준현
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.55-58
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    • 2003
  • This paper presents a study on the permittivities of the carbon nano fiber/epoxy composite at microwave frequency. The permittivities of composite materials depend on the concentrations and the dispersion methods of the carbon nano fibers. The experimental values of complex permittivities were obtained for the specimen made by dispersion method using ethyl alcohol as dispersion media and compared with the results by simple mechanical mixing method.

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Filler Nano/Micro 혼합비가 Epoxy 수지의 유전특성에 미치는 영향

  • Jeong, In-Beom;Choe, Hyeon-Min;Sin, Jong-Yeol;Lee, Jong-Yong;Hong, Jin-Ung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.249-249
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    • 2009
  • we have studied that a effect depending on dielectric properties of epoxy resin mixing filler nano/micro. When compare with nano/micro composite and virgin, the nano/micro composite is better than virgin. A specimen mixing nano/micro is changed as temperate, however the width of change is low.

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Electrical Properties of the Epoxy Nano-composites according to Additive

  • Shin, Jong-Yeol;Park, Hee-Doo;Choi, Kwang-Jin;Lee, Kang-Won;Lee, Jong-Yong;Hong, Jin-Woong
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.3
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    • pp.97-101
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    • 2009
  • The use of a filler material in epoxy composite materials is an essential condition for reducing the unit cost of production and reinforcing mechanical strength. However, the dielectric strength of insulators decreases rapidly due to interactions between the epoxy resin and filler particles. In contrast to existing composite materials, nano-composite materials have superior dielectric strength, mechanical strength, and enduring chemical properties due to an increase in the bond strength of the polymer and nano material, It is reported that nano-fillers provide new characteristics different from the properties of the polymer material. This study is to improve the insulation capability of epoxy resins used in the insulation of a power transformer apparatus and many electronic devices mold. To accomplish this, the additional amount of nano-$SiO_2$ to epoxy resin was changed and the epoxy/$SiO_2$ nano composite materials were made, and the fundamental electrical properties were investigated using a physical properties and an analysis breakdown test. Using allowable breakdown probability, the optimum breakdown strength for designing an electrical apparatus was determined. The results found that the electrical characteristics of the nano-$SiO_2$ content specimens were superior to the virgin specimens. The 0.4 wt% specimens showed the highest electrical properties among the specimens examined with an allowable breakdown probability of 20 %, which indicates stable breakdown strength in insulating machinery design.

Thermal and Mechanical Properties of Epoxy/Micro- and Nano- Mixed Silica Composites for Insulation Materials of Heavy Electric Equipment

  • Park, Jae-Jun;Yoon, Ki-Geun;Lee, Jae-Young
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.3
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    • pp.98-101
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    • 2011
  • A 10 nm nano-silica was introduced to a conventional 3 ${\mu}M$ micro-silica composite to develop an eco-friendly new electric insulation material for heavy electric equipment. Thermal and mechanical properties, such as glass transition temperature (Tg), dynamic mechanical analysis, tensile and flexural strength, were studied. The mechanical results were estimated by comparing scale and shape parameters in Weibull statistical analysis. The thermal and mechanical properties of conventional epoxy/micro-silica composite were improved by the addition of nano-silica. This was due to the increment of the compaction via the even dispersion of the nano-silica among the micro-silica particles.

Electrical Properties of Epoxy Nano-composites (나노복합재료를 이용한 에폭시의 전기적 특성)

  • Kil, Yun-Seob;Kim, Jung-Dong;An, Jae-Dong;Lee, Kang-Won;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.273-274
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    • 2008
  • For the purpose of practical use of epoxy composite materials, it has been widely known that adding filler is an indispensable condition for cost-effectiveness and reinforcement of mechanical strength. However, dielectric strength of insulators made of epoxy composites rapidly decreases due to interfaces between the epoxy resin and filler particles. In this paper, it is investigated that the electrical properties of epoxy resins as the function of nano-$SiO_2$ content. We obtained that breakdown voltage of 0.4[wt%] specimens is higher than the other $SiO_2$ content.

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Characterization of Epoxy Resin Containing Nano Clay Prepared by Electron Beam (전자선에 의해 제조된 나노 clay 함유 에폭시 수지의 특성)

  • Park, Jong-Seok;Lee, Seung-Jun;Lim, Youn-Mook;Jeong, Sung-In;Gwon, Hui-Jeong;Shin, Young-Min;Kang, Phil-Hyun;Nho, Young-Chang
    • Journal of Radiation Industry
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    • v.9 no.1
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    • pp.9-13
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    • 2015
  • Epoxy resin is widely used as aerospace, automobile, construction and electronics due to their good mechanical and electrical properties and environmental advantages. However, the inherent flammability of epoxy resin has limited its application in some field where good flame retardancy is required. Nano clay can enhance the properties of polymers such as flames retardancy and thermal stability. In this study, we have investigated the nanoclay filled epoxy composite, which has good flame retardancy while maintaining high mechanical properties. The cured epoxy resins were obtained using an electron beam curing process. The nano clays were dispersed in epoxy acrylate solution and mechanically stirred. The prepared mixtures were irradiated using an electron beam accelerator. The composites were characterized by gel content and thermal/mechanical properties. Moreover, the flammability of the composite was evaluated by limited oxygen index (LOI). The flame retardancy of nano clay filled epoxy composite was evidently improved.

Electrical and Mechanical Properties of Epoxy/Micro-sized Alumina Composite and the Effect of Nano-sized Alumina on Those Properties

  • Park, Jae-Jun;Shin, Seong-Sik;Yoon, Chan-Young;Lee, Jae-Young;Park, Joo-Eon
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.5
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    • pp.260-263
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    • 2015
  • Epoxy/micro-sized alumina composite was prepared and the effects of alumina content on the electrical and mechanical properties were investigated in order to develop an insulation material for gas insulated switchgear (GIS). Nano-sized alumina (average particle size: 30 μm) was also incorporated into the epoxy/micro-sized alumina composite. An electrical insulation breakdown strength test was carried out in sphere-sphere electrodes and the data were estimated by Weibull statistical analysis. Tensile strength was measured at a crosshead speed of 10 mm/min using a universal testing machine. Alumina content was varied from 0 wt% to 70 wt%.). As micro-sized alumina content increased, insulation breakdown strength increased until 40 wt% alumina content and decreased after that content. The tensile strength of a neat epoxy system was 82.2 MPa and that value for 60 wt% alumina content was 91.8 MPa, which was 111.7% higher than inthe neat epoxy system. The insulation breakdown strength of micro-sized alumina (60 wt%)/nano-sized alumina (1 phr) glycerol diglycidyl ether (GDE) (1 phr) composite was 54.2 MPa, which was 116% higher than the strength of the system without nano-sized alumina.