• Title/Summary/Keyword: Nd

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Microstructure and Magnetic Properties of Rapidly Solidified Nd-Fe(-Co) and Sm-Co(-Fe) Laves Compounds (급속냉각된 Nd-Fe(-Co)와 Sm-Co(-Fe)계 Laves 화합물의 미세조직과 자기특성)

  • 이우영;최승덕;양충진
    • Journal of the Korean Magnetics Society
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    • v.1 no.1
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    • pp.17-24
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    • 1991
  • Laves phases of $NdFe_2$, $Nd{(Fe_{0.5})}_2$, $SmCo_2$ and $Sm{(Fe_{0.5}Co_{0.5})}_2$ stoichiometry were prepared using a rapid solidification technology. Low temperature magnetic properties show ferromagnetic behaviors for the $Nd{(Fe_{0.5}Co_{0.5})}_2$, $SmCo_2$ and $Sm{(Fe_{0.5}Co_{0.5})}_2$Nd(Feo,Coo,) Laves compounds while a sort of spin reorientation has been suggested for the supposed composition of $NdFe_2$ alloy. This rapidly solidified $NdFe_2$ alloy is believed to consist of metastable rhombohedral $NdFe_7$ phase plus fine particles of Nd-rich phase. Some evidence of phase transition from the mixture of unstable $NdFe_7$ compound plus Nd-rich to $Nd_2Fe_{17}$ plus Fe-Nd-O phase was obtained after annealing the $NdFe_2$, alloy. The pseudo-binary Laves compound, $Sm{(Fe_{0.5}Co_{0.5})}_2$ exhibits a high coercivityof 4 kOe at room temperature with Curie temperature of $400^{\circ}C$ while the $Nd{(Fe_{0.5}Co_{0.5})}_2$ compound shows a magnetic moment of $2.8\;{\mu}_B/f.u.$.

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Solvent Extraction of Nd from Chloride Solution with PC88A (염산용액에서 PC88A에 의한 Nd의 용매추출)

  • Lee Gwang-Seop;Lee Jin-Young;Kim Sung-Don;Kim Joon-Soo;Lee Man-Seung
    • Resources Recycling
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    • v.13 no.4
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    • pp.39-45
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    • 2004
  • Solvent extraction experiments of Nd from chloride solution were studied with PC88A. Solvent extraction reaction of Nd with PC88A and the equilibrium constant were evaluated from the extraction experimental data and extraction conditions. Nd$aq^{3+}$ + 1.5 $H_2$$A_2$,org = $NdA_3$,org + 3H/sun $aq^{+}$ , K=0.25 The predicted distribution coefficients of Nd agreed well with the experimental results. The effect of saponification of PC88A on the extraction of Nd and on the change of equilibrium pH was investigated. Saponified PC88A present as a monomer in the organic reaction and enhanced the distribution coefficient of Nd. The initial extraction conditions had a great effect on the equilibrium pH.

양계 질병분석 및 방역대책- ND질병발생 동향과 예방대책 - 산란전 충분한 면역 형성을 위하여 -

  • Son, Yeong-Ho
    • KOREAN POULTRY JOURNAL
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    • v.38 no.2 s.436
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    • pp.84-87
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    • 2006
  • 최근 문제가 되고 있는 ND가 현재의 양상으로 발생하기 시작한 것은 벌써 8년여가 된다. 필자가 양계전문병원을 시작할 무렵이 ND가 서서히 전국적으로 확산되던 시기이니, 대략 그 정도가 지난 것으로 보인다. 물론 지역별로 분석을 해보면 서해안쪽과 호남지역은 부분적으로 5~6년 정도 ND로 인한 피해를 경험한 지역도 있다. ND가 본격적으로 발병하기 시작할 무렵에는 많은 사람들이 유행적인 발병, 다시 말하면 일정기간 폭발적으로 발병하다가 없어질 질병으로 예상하였지만, 예상은 여지없이 빗나가고 오랜기간을 농가에 지속적으로 피해를 입히는 질병으로 남아 있다. 본소에서 질병관리를 하는 농장들에 대해 2000년도부터 ND를 혈청학적으로 집중 모니터링하기 시작했다. 본소가 출입하는 모든 농장들의 전 계군에 대해 일정간격으로 질병발생 여부에 상관없이 혈청모니터링을 실시하다보니 농장별 ND발생의 특징과 매년 ND가 발생하는 동향에 약간의 변화들을 감지할수 있었다. 그 대표적인 발생 동향으로 첫째 산란을 시작하기 전 높은 면역을 부여해주지못한 계군에서 산란급상승 기간 중에 ND발생으로 인한 피해를 들 수 있으며, 둘째는 주로 동절기에만 발생하던 ND가 이제는 1년 내내 발생하는 양상으로 바뀌어 온 것 등 두 가지 동향에 대해 분석을 해보기로 한다. ND의 발생동향 분석이 ND예방에 어떻게 참고가 될 것인지는 그것을 정확히 인식하기 위한노력을 기울이는 농장들과 발생동향에 따른 대책을 적극 수행하는 농장들에 달려있다. ND발생시 피해의 정도를 결정하는 것은 여러가지이다. 계군의 면역상태와 고른 면역 정도, 영양상태, 환경조건, ND바이러스의 병원성 정도 등 여러 조건에 따라 ND에 의한 피해 정도가 결정된다. 이러한 조건 중 어느 하나도 중요하지 않은 것은 없으며 이것들은 ND로 인한 피해정도를 결정하는 중요한 요소들이다.

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Analysis of genetic divergence according to each mitochondrial DNA region of Haliotis discus hannai (북방전복 (Haliotis discus hannai) 의 mitochondrial DNA 영역별 유전적 변이성 분석)

  • Park, Choul-Ji;Nam, Won Sick;Lee, Jeong-Ho;Noh, Jae Koo;Kim, Hyun Chul;Park, Jong Won;Hwang, In Jun;Kim, Sung Yeon
    • The Korean Journal of Malacology
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    • v.29 no.4
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    • pp.335-341
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    • 2013
  • The seven mitochondrial DNA regions (ND2, ND5, ND4, ND4L, ND6, ND1 and 12SrRNA) of Haliotis discus hannai were examined to estimate the availability as a genetic marker for the study of population genetic. The region with the highest genetic variation was ND4 (Haplotype diversity = 1.0000, Nucleotide diversity = 0.0108). On the other hand, ND2 and ND1 regions have significantly appeared genetic divergence between clusters (divergence of 90% and 87%). Also, pairwise $F_{ST}$ between clusters within ND2 and ND1 regions showed high values; 0.4061 (P = 0.0000), 0.4805 (P = 0.0000) respectively. Therefore we can infer that it is the most efficient and accurate way to analyze the region of ND4 with the highest variation in addition to the regions of ND2 and ND1, which formed clusters with high bootstrap value, for study of population genetic structure in this species.

Research of Nd:LSB microchip laser (Nd:LSB 마이크로 칩 레이저 연구)

  • 장원권;김태훈;유영문
    • Korean Journal of Optics and Photonics
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    • v.13 no.6
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    • pp.554-558
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    • 2002
  • A new laser material, Nd:LSB $(Nd${3}:LaSc_3(BO_3)_4$, lanthanum scandium borate), of microchip type was grown by the Czochralski pulling method, and tested for optical and lasing properties. Nd:LSB, able to be highly doped with $Nd^{3+}$ ions while maintaining good optical, chemical, mechanical properties, was compared to another Nd-type laser material. The absorption and fluorescence spectra, and fluorescence lifetime were measured, and the crystal structure was analyzed. The lasing characteristics were investigated by using Ti:sapphire laser as a pumping light source.

Microstructure of the (Nd/Y)-Ba-Cu-O superconductors by floating zone melt growth process (부유대역용융성장법을 이용한 (Nd/Y)-Ba-Cu-O계 초전도체의 미세구조)

  • 김소정
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.2
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    • pp.83-87
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    • 2003
  • $(Nd/Y)_{1.8}Ba_{}2.4Cu_{3.4}O_{7-x}$high $T_c$ superconductor was directionally grown by floating Bone melt growth process with a large temperature gradient in air. Cylindrical green rods of (Nd/Y)1.8 oxides were fabricated by cold isostatic pressing (CIP) method using rubber mold. Microstructures were observed by SEM and TEM and superconducting properties were measured by a SQUID magnetometer. Nonsuperconducting $(Nd/Y)_2BaCuO_5$ inclusions were uniformly distributed within the superconducting $(Nd/Y)Ba_2Cu_3O_x$ matrix. The directionally melt-textured (Nd/Y) 1.8 superconductor showed an onset Tc $\geq$ 90 K and a sharp superconducting transition.

Improvement of Magnetic Properties of Nd-Fe-B Type Sintered Magnet (Nd-Fe-B계 소결자석의 자기적특성 향상 연구)

  • Kim, Yoon-B.;Jung, W.S.;Jeung, W.Y.
    • Journal of the Korean Magnetics Society
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    • v.12 no.2
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    • pp.57-63
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    • 2002
  • In order to increase the magnetic properties of a Nd-Fe-B sintered magnet, the general factors including particle size and its distribution, volume fraction of Nd$_2$Fe$_{14}$B phase, degree of alignment of Nd$_2$Fe$_{14}$B grain, oxygen content and grain size etc. should be optimized by controlling the composition of Nd-Fe-B alloy as well as the manufacturing process. In this study, fabrication of the Nd-Fe-B sintered magnet was carried out in a laboratory scale by controlling the composition of Nd-Fe-B alloy and the manufacturing process. The optimum milling condition was found by investigating the milling media, milling time and ball size. The addition of FeGa was effective to increase the coercivity of the Nd-Fe-B sintered magnet. A remanence of 14.4 kG, a coercivity of 9.4 kOe and a maximum energy product of 47 MGOe were obtained from the sintered magnet.

Hydrodesulfuriztion of Thiophene over Neodymium Added Nickel Catalysts (네오디뮴이 첨가된 니켈 촉매의 티오펜 탈황 반응)

  • Moon, Young-Hwan;Ihm, Son-Ki
    • Applied Chemistry for Engineering
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    • v.7 no.5
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    • pp.913-924
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    • 1996
  • In this study HDS(hydrodesulfurization) of thiophene was researched over nickel catalysts added with small amounts of neodymium which were prepared by different methods such as unsupported coprepricipitated NdNi catalysts, unsupported intermetallic $NdNi_5$ catalysts, and carbon supported NdNi catalyst. The HDS activity was remarkably increased when a small amounts of neodymium was added to unsupported coprecipitated Ni catalysts. Thus it was known that the role of Nd is important in HDS of thiophene of Ni catalysts. For the case of unsupported intermetallic $NdNi_5$, the intermetallic crystallinity was destroyed to oxide and sulfide after calcination and presulfidation respectively. The HDS activity of thiophene can be explained by surface area of unsupported catalysts. And Nd acts like as structural promoter keeping the high surface area of unsupported catalysts. The HDS activity was increased by each ten times based on 1 gr. of nickel in the order of unsupported intermetallic $NdNi_5$, unsupported coprecipitated NdNi, and carbon supported NdNi catalysts according to different preparation method of catalysts.

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Computer Simulation of Enhancement of Coerciviy in Nd-Fe-B/(Nd,Dy)-Fe-B Composite Magnets

  • Kawasaki, Kohei;Yanai, Takeshi;Nakano, Masaki;Fukunaga, Hirotoshi
    • Journal of Magnetics
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    • v.16 no.2
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    • pp.145-149
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    • 2011
  • The coercivity $H_c$ of $Nd_2Fe_{14}B$ magnets and $Nd_2Fe_{14}B/(Nd_{0.7}Dy_{0.3})_2Fe_{14}B$ composite magnets were calculated by computer simulation based on the micromagnetic theory under assumptions that $Nd_2Fe_{14}B$ and $(Nd_{0.7}Dy_{0.3})_2Fe_{14}B$ grains have magnetically deteriorated layers on their surfaces and diffusion of Dy from $(Nd_{0.7}Dy_{0.3})_2Fe_{14}B$ grains to $Nd_2Fe_{14}B$ ones through the contacting boundaries recovers the magnetic anisotropy of the deteriorated layers of $Nd_2Fe_{14}B$ grains. $H_c$ of $Nd_2Fe_{14}B/(Nd_{0.7}Dy_{0.3})_2Fe_{14}B$ composite magnets increased by the diffusion of Dy from $(Nd_{0.7}Dy_{0.3})_2Fe_{14}B$ grains to $Nd_2Fe_{14}B$ ones and the resultant recovery of the anisotropy field of deteriorated layers of $Nd_2Fe_{14}B$ grains. The $H_c$ vs fraction of $(Nd_{0.7}Dy_{0.3})_2Fe_{14}B$ grains curve were convex for the magnets with the degree of alignment between 0.94 and 0.99, which suggests that the above composite magnets have larger $H_c$ values than the alloy-magnets with the same Dy content, and that we can save the consumption of Dy by using these composite magnets.

Influence of Ga-Addition on the Manetic Properties of $\alpha-Fe$ Based Nd-Fe-B Alloy (Ga 첨가가 $\alpha$-Fe기 Nd-Fe-B 합금의 자기특성에 미치는 영향)

  • 조덕호;이병엽;조용수
    • Journal of the Korean Magnetics Society
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    • v.7 no.1
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    • pp.44-48
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    • 1997
  • The nanocrystalline Nd-Fe-B alloys with low Nd content were prepared by rapid solidification technique. The alloys consist of both$\alpha$-Fe as the main phase and $Nd_2Fe_{14}B_1$ as a secondary phase and have an ultrafine grain structure of about 30 nm. The addition of Ga in $Nd_4Fe_{82}B_{10}Mo_3Cu_1$ alloy increases remanence up to 1.29 T and improves squareness. The nanocrystalline $Nd_5Fe_{81}B_9Mo_3Cu_1Ga_1$ alloy has a volume fraction of $Nd_2Fe_{14}B_1$ phase of around 35% due to the increase of Nd content and shows an improved coercivity. The remanence, coercivity and energy product of optimally annealed nanocrystalline $Nd_5Fe_{81}B_9Mo_3Cu_1Ga_1$ alloy are 1.24 T, 257.4 kA/m (3.23 kOe), and 100.3 kJ/ ㎥ (12.6 MGOe), respectively.

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