• Title/Summary/Keyword: Non-linear corrosion

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Enhanced Classical Tafel Diagram Model for Corrosion of Steel in Chloride Contaminated Concrete and the Experimental Non-Linear Effect of Temperature

  • Hussain, Raja Rizwan
    • International Journal of Concrete Structures and Materials
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    • v.4 no.2
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    • pp.71-75
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    • 2010
  • The chloride ion attack on the passive iron oxide layer of reinforcement steel embedded in concrete under variable temperature environment is influenced by several parameters and some of them still need to be further investigated in more detail. Different school of thoughts exist between past researchers and the data is limited in the high temperature and high chloride concentration range which is necessary with regards to setting boundary conditions for enhancement of tafel diagram model presented in this research. The objective of this paper is to investigate the detrimental coupled effects of chloride and temperature on corrosion of reinforced concrete structures in the high range by incorporating classical Tafel diagram chloride induced corrosion model and laboratory controlled experimental non-linear effect of temperature on corrosion of rebar embedded in concrete.

Reliability Evaluation of ER Type Corrosion Sensor for Monitoring Corrosion of Piping System Under Accelerated Corrosion Environment (배관의 부식 상태 진단에 사용되는 ER 부식센서의 가속부식환경에서의 신뢰성 평가)

  • Hwang, Hyun-Kyu;Shin, Dong-Ho;Kim, Heon-Hui;Lee, Jung-Hyung
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.403-411
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    • 2021
  • In this study, the reliability of a commercial ER-type corrosion sensor was evaluated under an accelerated corrosion environment to verify its suitability for application in monitoring of ship's seawater piping system. A closed-loop pump piping testbed was designed and constructed to compare the wall thickness reduction of the pipe and the response from the sensor. The sensor was attached inside the pipe near the outlet of the pump that was exposed to a 3.5% NaCl solution with or without copper accelerated acetic acid (CASS). The results demonstrated that the presence of CASS significantly increased the corrosivity of the solution as well as the thickness reduction of the pipe, as expected. On the other hand, the corrosion products formed by the solution with CASS were thicker compared with those without CASS. The sensor response to temperature variation was found to be a clear linear relationship for the solution without CASS but there was a non-linear relationship where CASS was present.

Assessment of External and Internal Corrosion Growth Rate for Metallic Water Pipes (상수도 금속관의 외면과 내면 부식속도 평가에 관한 연구)

  • Bae, Chulho;Kim, Juhwan;Kim, Jeonghyun;Hong, Seongho
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.1
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    • pp.17-25
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    • 2008
  • In this study, external and internal pit growth rate model and external non-linear regression corrosion model were proposed by measuring pit depths and evaluating various soil factors known to contribute to the corrosion for metallic water pipes. Average pit depths of external and internal for metallic water pipes were measured 1.38 mm and 2.13 mm, and internal pit growth rate also fasted twice than external pit growth rate. This means the corrosion potential of water quality was higher than soil. The corelation between external corrosion rate and each soil corrosion factor was low. However, proposed external non-linear regression corrosion model considering all soil corrosion factors showed a little higher correlation ($R^2=0.46$) than conventional model.

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Numerical models for stress analysis of non-uniform corroded tubular members under compression

  • Chinh, Vu Dan;Nguyen, Ha Thi Thu
    • Structural Engineering and Mechanics
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    • v.84 no.4
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    • pp.517-530
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    • 2022
  • In re-assessing the Jacket-type fixed steel structures, the current standards often allow the simplicity of corrosion sections using local buckling or equivalent section approach to applying empirical formulae of frame stress and resistance analyses. However, those approaches can lead to significant errors for non-uniform corroded frames in a specific area, including force distribution, stress, and allowable strength of the tubular section, compared to the actual cases. This paper investigates a suitable approach to determine the actual stress on non-uniform corroded tubular frames under compression through the non-linear ABAQUS model by considering the effect of large deformation on the frame axis and the frame section. There are 3 scenarios of interest. In the 1st and 2nd scenarios with simple corrosion cases, the stress ratios using the numerical model and theoretical formulae correspond to the calculation of allowable strength reduction ratios in standards. However, scenario 3, which describes non-uniform corroded sections based on survey data, provides considerable differences in results. Therefore, it proves the reliable and effective results when using this method to analyze the resistance of the actual corroded section in the Jacket platforms.

Development of Integrated Corrosion Monitoring and Control System (통합 부식 모니터링 및 통합 제어 시스템의 개발)

  • Yoo, Nam-Hyun;Kim, Young-Hun
    • Journal of Ocean Engineering and Technology
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    • v.27 no.3
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    • pp.8-14
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    • 2013
  • Although there are various factors that threaten the security of ships, one of the most harmful is corrosion. It is not easy to find corroding areas and the status of corrosion, even though corrosion causes serious problems such as submergence and marine pollution as a result of leaking oil and polluted water. To monitor the corrosion of ships, non-destructive inspection, weight loss coupons, electrical resistance, linear polarization resistance, zero resistance ammeter, and electrochemical impedance spectroscopy have been developed. However, these methods require much time to detect corrosion, and most are not appropriate for real time monitoring. Coating, sacrificial anode, and impressed current cathodic protection (ICCP) methods have been developed to control corrosion. The ICCP and sacrificial anode methods are the most popular ways to prevent ship corrosion. However, ICCP is only appropriate for the outside of a ship and cannot be used for complex structures such as ballast tanks because these are composed of many separate chambers. Sacrificial anodes have to be replaced periodically. This paper proposes an integrated corrosion monitoring and control system (ICMCS) that can detect corrosion in real time and is appropriate for complex structures such as ballast tanks. Because the system uses titanium for an anode, exhausted anodes do not need to be replaced.

An advanced technique to predict time-dependent corrosion damage of onshore, offshore, nearshore and ship structures: Part I = generalisation

  • Kim, Do Kyun;Wong, Eileen Wee Chin;Cho, Nak-Kyun
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.12 no.1
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    • pp.657-666
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    • 2020
  • A reliable and cost-effective technique for the development of corrosion damage model is introduced to predict nonlinear time-dependent corrosion wastage of steel structures. A detailed explanation on how to propose a generalised mathematical formulation of the corrosion model is investigated in this paper (Part I), and verification and application of the developed method are covered in the following paper (Part II) by adopting corrosion data of a ship's ballast tank structure. In this study, probabilistic approaches including statistical analysis were applied to select the best fit probability density function (PDF) for the measured corrosion data. The sub-parameters of selected PDF, e.g., the largest extreme value distribution consisting of scale, and shape parameters, can be formulated as a function of time using curve fitting method. The proposed technique to formulate the refined time-dependent corrosion wastage model (TDCWM) will be useful for engineers as it provides an easy and accurate prediction of the 1) starting time of corrosion, 2) remaining life of the structure, and 3) nonlinear corrosion damage amount over time. In addition, the obtained outcome can be utilised for the development of simplified engineering software shown in Appendix B.

An advanced technique to predict time-dependent corrosion damage of onshore, offshore, nearshore and ship structures: Part II = Application to the ship's ballast tank

  • Kim, Do Kyun;Lim, Hui Ling;Cho, Nak-Kyun
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.12 no.1
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    • pp.645-656
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    • 2020
  • In this study (Part II), the empirical formulation of corrosion model of a ship's ballast tank was developed to predict nonlinear time-dependent corrosion wastage based on the advanced data processing technique proposed by Part I. The detail on how to propose generalised mathematical formulation of corrosion model was precisely documented in the previous paper (Part I). The statistical scatter of corrosion data at any exposure time was investigated by the refined method and formulated based on a 2-parameter Weibull distribution which selected the best fit PDF. Throughout the nine (9) steps, empirical formulation of the ship's seawater ballast tank was successfully proposed and four (4) key step results were also obtained. The proposed method in Part I was verified and confirmed by this application of seawater ballast tank, thus making it possible to predict accurate behaviours of nonlinear timedependent corrosion. Developed procedures and obtained corrosion damage model for ship's seawater ballast tank can be used for development of engineering software.

Optimal Parameter Selection by Health Monitoring of Gas Turbine Engines using Gas Path Analysis (GPA를 이용한 가스터빈 엔진의 성능진단에 의한 최적 계측변수 선정에 관한 연구)

  • ;Riti Singh
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.1
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    • pp.24-33
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    • 1999
  • For performance prediction and diagnostics of gas turbine engines, linear and non-linear gas path analysis are applied. In order to find optimal instrument parameters to detect the physical faults such as (outing, erosion and corrosion, non-linear gas path analysis is used. A typical industrial gas turbine engine, TB5000, is used to study the effect of physical faults on engine performance. Through comparison of RMS error between linear and non-linear gas path analysis, the optimal instrument parameters can be defined. As a result, it is found that the linear GPA has the level of error introduced by the assumption of the linear mode: can be of the same order of magnitude as the fault being soughtwhile the non-linear GPA can be solved the non-linear relationships between dependent and independent parameters using an iterative method such as the Newton-Raphson method with sufficient accuracy.

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Modeling of Flow-Accelerated Corrosion using Machine Learning: Comparison between Random Forest and Non-linear Regression (기계학습을 이용한 유동가속부식 모델링: 랜덤 포레스트와 비선형 회귀분석과의 비교)

  • Lee, Gyeong-Geun;Lee, Eun Hee;Kim, Sung-Woo;Kim, Kyung-Mo;Kim, Dong-Jin
    • Corrosion Science and Technology
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    • v.18 no.2
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    • pp.61-71
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    • 2019
  • Flow-Accelerated Corrosion (FAC) is a phenomenon in which a protective coating on a metal surface is dissolved by a flow of fluid in a metal pipe, leading to continuous wall-thinning. Recently, many countries have developed computer codes to manage FAC in power plants, and the FAC prediction model in these computer codes plays an important role in predictive performance. Herein, the FAC prediction model was developed by applying a machine learning method and the conventional nonlinear regression method. The random forest, a widely used machine learning technique in predictive modeling led to easy calculation of FAC tendency for five input variables: flow rate, temperature, pH, Cr content, and dissolved oxygen concentration. However, the model showed significant errors in some input conditions, and it was difficult to obtain proper regression results without using additional data points. In contrast, nonlinear regression analysis predicted robust estimation even with relatively insufficient data by assuming an empirical equation and the model showed better predictive power when the interaction between DO and pH was considered. The comparative analysis of this study is believed to provide important insights for developing a more sophisticated FAC prediction model.

Structural response of corroded RC beams: a comprehensive damage approach

  • Finozzi, Irene Barbara Nina;Berto, Luisa;Saetta, Anna
    • Computers and Concrete
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    • v.15 no.3
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    • pp.411-436
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    • 2015
  • In this work, a comprehensive approach to model the structural behaviour of Reinforced Concrete (RC) beams subjected to reinforcement corrosion is proposed. The coupled environmental - mechanical damage model developed by some of the authors is enhanced for considering the main effects of corrosion on concrete, on composite interaction between reinforcement bars and concrete and on steel reinforcement. This approach is adopted for reproducing a set of experimental tests on RC beams with different corrosion degrees. After the simulation of the sound beams, the main parameters involved in the relationships characterizing the effects of corrosion are calibrated and tested, referring to one degraded beam. Then, in order to validate the proposed approach and to assess its ability to predict the structural response of deteriorated elements, several corroded beams are analyzed. The numerical results show a good agreement with the experimental ones: in particular, the proposed model properly predicts the structural response in terms of both failure mode and load-deflection curves, with increasing corrosion level.