• Title/Summary/Keyword: Organic Matter

Search Result 3,987, Processing Time 0.033 seconds

Distribution Characteristics of Organic Matter and Heavy Metal of Sediment in Daecheon Port (대천항 퇴적물의 유기물 및 중금속 분포 특성)

  • Shin, Woo-Seok;Lim, Ji-Yoon;Yoon, Young-Gwan
    • Journal of Korean Society of Water Science and Technology
    • /
    • v.26 no.6
    • /
    • pp.43-51
    • /
    • 2018
  • In order to systematically and scientifically manage the organic and heavy metals against sediment at Daecheon Port, this study conducted particle composition, organic materials and heavy metals irradiation studies of sediments. Analysis of the grain size composition of sediments in the target study area showed the distribution characteristics of the mix of sand, silt and clay. That is, Station C (Stn. C) showed superior by fine-grained sediment, Station A and B (Stn. A and B) showed superior by coarse-grained sediment. The organic matter(COD, TOC, and IL) of Stn. C was appeared to be heavily polluted more than Stn. A and B. These data for the spatial properties in sediment showed that organic matter was related positively to the sediment silt-clay content. Also, in the case of heavy metals contamination in surface sediments, Stn. C was higher than Stn. A and B. Particularly, at the Stn. C, high organic matter concentration and C/N ratio value( >10) indicated that the sediment was composed highly of land-derived organic matter. From these results, it considered that the correlation analysis among to silt-clay, organic matter and heavy metal was found to have a good interrelationship.

The Origin and Biogeochemistry of Organic Matter in Surface Sediments of Lake Shihwa and Lake Hwaong

  • Won, Eun-Ji;Cho, Hyen-Goo;Shin, Kyung-Hoon
    • Ocean Science Journal
    • /
    • v.42 no.4
    • /
    • pp.223-230
    • /
    • 2007
  • To understand the origin and biogeochemistry of the organic matter in surface sediments of Lake Shihwa and Lake Hwaong, organic nitrogen, inorganic nitrogen, labile organic carbon, and residual organic carbon contents as well as stable isotope ratios for carbon and nitrogen were determined by KOBr-KOH treatment. Ratios of organic carbon to organic nitrogen $(C_{org}/N_{org})$ (mean = 24) were much higher than ratios of organic carbon to total nitrogen $(C_{org}/N_{tot})$ (mean= 12), indicating the presence of significant amounts of inorganic nitrogen in the surface sediments of both lakes. Stable isotope ratios for organic nitrogen were, on average, $5.2\%_{\circ}$ heavier than ratios of inorganic nitrogen in Lake Shihwa, but those same ratios were comparable in Lake Hwaong. This might be due to differences in the origin or the degree of degradation of sedimentary organic matter between the two lakes. In addition, stable isotope ratios for labile organic carbon were, on average, $1.4\%_{\circ}$ heavier than those for residual organic carbon, reflecting the preferential oxidation of $^{13}C$-enriched organic matter. The present study demonstrates that KOBr-KOH treatment of sedimentary organic matter can provide valuable information for understanding the origin and degradation state of organic matter in marine and brackish sediments. This also suggests that the ratio of $(C_{org}/N_{org})$ and stable isotope ratios for organic nitrogen can be used as indexes of the degree of degradation of organic matter.

Chemical Budgets in Intensive Carp Ponds

  • Peng Lei;Oh Sung-Yong;Jo Jae-Yoon
    • Fisheries and Aquatic Sciences
    • /
    • v.6 no.4
    • /
    • pp.194-202
    • /
    • 2003
  • Budgets for water, nitrogen, and chemical oxygen demand (COD) were determined in two 0.012 ha earthy-bottom ponds stocked with Israeli strain common carp at an initial stocking density of $20\;fish/m^3$. Total ammonia nitrogen (TAN) concentrations increased continuously but later decreased in pond A as a consequence of high nitrification. COD concentrations increased during the experimental period due to the accumulation of feed input. Nutrient budgets showed that feed represented $94-95\%$ of nitrogen input and about 99% of organic matter input. Fish harvest accounted for $40\%$ of nitrogen and organic matter input. Seepage and water exchange removed $15-17\%$ of nitrogen input but only $1-2\%$ of organic matter. Draining of the ponds removed $20-26\%$ of input nitrogen, mostly in inorganic forms, but removed only minus organic matter. Fish and water column respiration accounted for $39\%$ of organic matter input, and benthic respiration accounted for $7-12\%$ of organic matter input. No significant change of nitrogen and organic matter in both pond bottoms were found during the three-month growth period. The unrecovered input nitrogen, about $6.3-13\%$, was lost through denitrification and ammonia volatilization. On a dry matter basis, fish growth removed $31\%$ of total feed input and left $69\%$ as metabolic wastes.

A Study on the Removal Characteristics of Organic matter and Bacteria with the Use of Ozone (오존을 이용한 유기물 및 세균의 제거 특성에 관한 연구)

  • Lee, Kwan-Young;Park, Sang-Hyun
    • Journal of the Korean Society of Industry Convergence
    • /
    • v.10 no.1
    • /
    • pp.15-20
    • /
    • 2007
  • The aim of this study is to measure the removal characteristics of organic matter and bacteria with the use of ozone to reduce the problems caused by bacteria and organic matter which appear in sea-water is summer season. When the total input of ozone was $1.4mg/{\ell}O_3$, the removal rate of bacteria and E-coli from sea-water proved to be 100%. With the same input of ozone, on the other hand, the removal rate of COD turned to be relatively low, 50%, which was to the fact that sea-water consists of salt matter which is a kind of COD matter. This result supports the idea that we can keep using ozone steadily in the future to remove organic matters and bacteria from sea-water because ozone destructs relatively less salt matter in sea-water. Also, the treatment effect rate of SS, turbidity and organic matters such as $NH_3$-N, $NO_3$-N etc, was very high. As a result, we assume that the treatment of organic matter in sea-water with ozone is very effective

  • PDF

Separation of soil Organic Debris using Sucrose-ZnCl2 Density Gradient Centrifugation

  • Jung, Seok-Ho;Chung, Doug-Young;Han, Gwang-Hyun
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.45 no.1
    • /
    • pp.30-36
    • /
    • 2012
  • The active fraction of soil organic matter, which includes organic debris and light organic fraction, plays a major role in nutrient cycling. In addition, particulate organic matter is a valuable index of labile soil organic matter and can reflect differences in various soil behaviors. Since soil organic matter bound to soil mineral particles has its density lower than soil minerals, we partitioned soil organic matter into debris ($<1.5g\;cm^{-3}$), light fraction ($1.5-2.0g\;cm^{-3}$), and heavy fraction ($>2.0g\;cm^{-3}$), based on high density $ZnCl_{2-}$ sucrose solutions. Generally, partitioned organic bands were clearly separated, demonstrating that the $ZnCl_{2-}$ sucrose solutions are useful for such a density gradient centrifugation. The available gradient ranges from 1.2 to $2.0g\;cm^{-3}$. Although there was not a statistically meaningful difference in organic debris and organomineral fractions among the examined soils, there was a general trend that a higher content of organic debris resulted in a higher proportion of light organomineral fraction. In addition, high clay content was associated with increased fraction of light organomineals. Partitioning of soil organic carbon revealed that carbon content is reduced in the heavy fraction than in the light fraction, reflecting that the light fraction contains more fresh and abundant carbon than the passive resistant fraction. It was also found that carbon contents in the overall organic matter, debris, light fraction, and heavy fractions may differ considerably in response to different farming practices.

The Determination of Chemical Forms of Heavy Metals in Shooting Area Contaminated Soil Using Sequential Extraction Method (연속추출법을 이용한 사격장 오염토양 중 중금속의 화학적 형태 결정)

  • Moon, Gyeonghye;Park, Hongki;Yoo, Kyoungkeun;Manis Kumar, Jha;Richad Diaz, Alorro;Kim, Ju Yup
    • Journal of Soil and Groundwater Environment
    • /
    • v.20 no.6
    • /
    • pp.111-116
    • /
    • 2015
  • The soil sample obtained from shooting area contaminated with Pb, Cu, and Zn was investigated to determine the chemical forms of heavy metals with Tessier’s sequential extraction method, which is constituted of five fractions such as ‘exchangeable’, ‘bound to carbonate’, ‘bound to oxide’, ‘bound to organic matter’, and residual fractions. The amount of organic matter was measured by loss on ignition (LOI) and then the results of ‘bound to organic matter’ and LOI were compared. The sequential extraction results show that 4.7%-45% of Pb, 6.2%-25.9% of Cu and 3.9%-15.3% of Zn belong to the ‘bound to organic matter’ fraction, but LOI result shows that only 1.0%-2.8% of organic matter exists in the soil sample. In heavy medium separation tests, because Pb and Cu extracted in ‘bound to organic matter’ and residual fractions were removed, the heavy metals in the fractions would exist as heavier forms. These results suggest that the part of heavy metal extracted in ‘bound to organic matter’ fraction would result from the oxidation of metallic forms by hydrogen peroxide and nitric acid used in the fraction, and, consequently, that the ‘bound to organic matter’ fraction should be investigated in detail to determine the removal method and treatment capacity when the Tessier’s sequential extraction method is used to examine heavy metal contaminants resulted from elemental metal like bullets.

Weathering of coal and kerogen : implications on the geochmical carbon and oxygen cycle and the environmental geochemical reactions (탄질 유기물과 케로젠의 풍화 : 탄소와 산소의 지화학적 순환 및 환경화학적 반응에 미치는 영향)

  • 장수범
    • Economic and Environmental Geology
    • /
    • v.32 no.1
    • /
    • pp.101-111
    • /
    • 1999
  • Sedimentary organic matter, exposed to continental surficial environment, reacts with oxygen supplied from the atmosphee and forms carbon-containing oxidation products. Knowledge of the rate and mechanisms of sedimentary organic matter weathering is important because it is one of the major controls on atmospheric oxygen level through geologic time. Under the abiological conditions, the oxidation rate of coal organic matter by molecular oxygen is enhanced by the increase of oxygen concentration and temperature. At ambient temperature and pressure, aqueous coal oxidation results in the formation of dissolved $CO_2$ dissolved organic carbon and solid oxidation products which are all quantitatively significant reaction products. The effects of pH, ultraviolet light, and microbial activity on the weathering of sedimentary organic matter are poorly contrained. Based on the results of geochmical and environmental studies, it is believed that the photochemical reaction should play an important role in the decomposition and oxidation of sedimentary organic matter removed from the weathering profile. At higher pH conditions, the production rate of DOC can be accelerated due to base catalysis. These high molecular weight oranic matter can react with man-made pollutants such as heavy metal ions via adsorption/desorption or ion exchange reactions. The effect of microbial activity on the oxidative weathering of sedimentary organic matter is poorly understood and remains to be studied.

  • PDF

Measurement of Soil Organic Matter Using Near Infra-Red Reflectance (근적외선 반사도를 이용한 토양 유기물 함량 측정)

  • 조성인;배영민;양희성;최상현
    • Journal of Biosystems Engineering
    • /
    • v.26 no.5
    • /
    • pp.475-480
    • /
    • 2001
  • Sensing soil organic matter is crucial for precision farming and environment friendly agriculture. Near infra-red(NIR) was utilized to measure the soil organic matter. Multivariate calibration methods, including stepwise multiple linear regression(MLR), principal components recession(PCR) and partial least squares regression(PLS), were applied to soil spectral reflectance data to predict the organic matter content. The effect of soil particle size and water content was studied. The range of soil organic matter contents was from 0.5 to 11%. Near infrared (NIR) region from 700 to 2,500nm was applied. For uniform soil particle size, result had good correlation (R$\^$2/ = 0.984, standard error of prediction= 0.596). The effect of soil particle size could be eliminated with 1st order derivative of the NIR signal. However. moist soil had a little lower correlation. R$\^$2/ was 0.95 and standard error of prediction was 0.94% using the PLS method. The results showed the possibility of soil organic matter measurement using NIR reflectance on the field.

  • PDF

C:N:P stoichiometry of particulate and dissolved organic matter in river waters and changes during decomposition

  • Islam, Mohammad Jahidul;Jang, Changwon;Eum, Jaesung;Jung, Sung-min;Shin, Myoung-Sun;Lee, Yunkyoung;Choi, Youngsoon;Kim, Bomchul
    • Journal of Ecology and Environment
    • /
    • v.43 no.1
    • /
    • pp.14-21
    • /
    • 2019
  • Background: Stoichiometry plays an important role in understanding nutrient composition and cycling processes in aquatic ecosystems. Previous studies have considered C:N:P ratios constant for both DOM (dissolved organic matter) and POM (particulate organic matter). In this study, water samples were collected in the six major rivers in Korea and were incubated for 20 days. C:N:P ratios were determined during the time course of the incubations. This allowed us to examine the changes in N and P contents of organic matter during decomposition. Results: POM and DOM showed significant differences in N and P content and the elemental ratios changed during the course of decomposition; DOM showed higher C:N and C:P ratios than POM, and the C:N and C:P ratios increased during decomposition, indicating the preferential mineralization of P over N and N over C. Conclusions: The N and P contents of organic matter in aquatic ecosystem are far from constant and vary significantly during decomposition. More detailed information on the changes in C:N:P ratios will provide improved understanding of decomposition processes and improved modeling of aquatic ecosystems.

Evaluation of the Applicability of Livestock Wastewater Treatment using Boron-Doped Diamond (BDD) Electrodes (BDD 전극을 이용한 축산폐수 처리의 적용성 평가)

  • Hyun-Gu Kim;Dae-Hee Ahn
    • Journal of Environmental Science International
    • /
    • v.32 no.6
    • /
    • pp.465-475
    • /
    • 2023
  • In this study, we evaluated the treatment efficiency of livestock wastewater by altering the current density using boron-doped diamond (BDD) electrodes. As the current density was adjusted from 10 to 35 mA/cm2, the removal efficiency of organic matter increased from 22.2 to 71.5%. Similar to that of organic matter, the removal efficiency of color increased with increasing current density up to 85.7%, indicating a higher removal efficiency for color than that of organic matter. The removal efficiency of ammonia nitrogen increased from 14.6 to 53.3% as the current density increased, but it was lower than that of organic matter. In addition, the removal of organic matter, color, and ammonia nitrogen followed first-order reactions, according to the reaction rate analysis. The energy consumption ranged from 4.87 to 8.33 kWh/kg COD, and it was found that the organic matter removal efficiency was more efficient at high current densities. Based on various analyses, the optimal current density was 20 mA/cm2, and the corresponding energy consumption was 6.824 kWh/kg COD.