• 세라미스트
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• 제14권2호
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• pp.7-14
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• 2011

This paper has investigated physicochemical properties and conventional and environmental-friendly treatment methods of paper mill sludge to emphasize the importance and necessity of the sludge recycling. The paper mill sludge generally shows high contents of calcium and water, and is mostly discharged by landfill after incineration process rather than being recycled due to technical or economical problems. In recent years, however, several possible methods for recycling the paper mill sludge have been suggested for its sustainable process as follows; compost, raw material for the construction and paper industry, new energy source for reducing fossil fuel use and raw material of activated carbon for treating paper mill wastewater. Thus the authors suggest that practical recycling technologies of the paper mill sludge must be developed for substantiality in the paper industry through comprehending physicochemical compositions and generation status of the sludge and actively performing various related studies. Furthermore, this investigation could be used as preliminary information for the study on recycled paper development using paper mill sludge incineration ash.

• Journal of Microbiology and Biotechnology
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• 제11권3호
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• pp.362-368
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• 2001

The effects of water soluble materials in paper mill sludge on cellulase and $\beta$-glucosidase activities were studied while the optimization of enzyme system for hydrolysis of the paper mill sludge for production of glucose was made. Water soluble materials in the paper mill sludge showed stimulatory effect on carboxymethyl cellulose (CMC) activity, inhibitory effect on filter paper (FP) activity, and no effect on avicelase and $\beta$-glucosidase activities. CMC and ${\beta}$-glucosidase activities at 5 and 10, 5 or 10 and 10, and 10 and 10 U/ml were optimal for hydrolysis of 5, 10, and 20% of the paper mill sludge, respectively.

• 펄프종이기술
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• 제39권4호
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• pp.61-67
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• 2007

Paper sludges collected from three different paper mills were physico-chemically analyzed in order to use them as raw materials for making bed soils and seedling pots. The sludge from a fine paper mill contained lots of inorganic pigment particles used for coating, as those from a newsprint mill and a tissue mill had not. It was clearly through XRD analysis confirmed that all sludges included calcium carbonate. The paper sludge from the tissue mill contained the greatest amount of particles, which would contribute to water absorption and nutrient storage. The sludge from the fine paper mill had the highest density due to many inorganic elements. While the ash content and the total nitrogen content were the highest in the sludge from the fine paper mill, the C/N ratio was the lowest in the fine paper mill sludge. All sludges seemed to have insufficient contents of potassium. The sludges from the newsprint mill and the tissue mill showed more silicon contents than that from the fine paper mill. It was concluded that the sludge from the fine paper mill would be able to be the most efficient raw materials for making bed soils and seedling pots and the other two sludges would be more efficient for intensive culture for crops such as rice and grain with additional supplement of nitrogen and other nutrients.

• 한국지하수토양환경학회지:지하수토양환경
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• 제19권1호
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• pp.46-53
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• 2014

The purpose of this study is to promote utilization of paper mill sludge as an adsorbent for stabilizing heavy metals in contaminated water by measuring the adsorption capacity of paper mill sludge for cadmium and arsenic. To measure adsorption capacity of paper mill sludge, sorption isotherm experiments were analyzed by Langmuir and Freundlich isotherm models. Also, two methods of chemical modifications were applied to improve the adsorption capacities of paper-mill-sludge: the first method used sodium hydroxide (NaOH), called PMS-1, and the second method used the NaOH and tartaric acid ($C_4H_6O_6$) together, called PMS-2. For Cd adsorption, PMS-1 presented the increase of reactivity while PMS-2 presented the decline of reactivity compared to that of untreated paper-mill-sludge. In case of As adsorption, both PMS-1 and PMS-2 showed the decrease of adsorption capacities. This is because zeta-potential of paper mill sludge was changed to more negative values during chemical modification process due to the hydroxyl group in NaOH and the carboxyl group in $C_4H_6O_6$, respectively. Therefore, we may conclude that the chemical treatment process increases adsorption capacity of paper mill sludge for cation heavy metals such as Cd but not for As.

• Journal of Forest and Environmental Science
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• 제23권2호
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• pp.119-122
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• 2007

Actually, about 45% of total costs for wastewater treatment in a papermaking mill is spent for sludge disposal and the cost of chemicals used to improve the dewaterability of sludge takes much part of it. In order to reduce sludge disposal cost and to improve the efficiency of sludge treatment, it is necessary to minimize the amount of water contained within the sludge and hence to improve the dewaterability of the sludge. The objective of this study was to elucidate the way of improving the dewaterability of sludge. Three types of wastewater from a tissue paper mill, a printing paper mill and a newsprint mill were used and two types of high molecular weight flocculants (anionic PAM and cationic PAM) were used to treat the wastewater. Dewaterability of sludge was evaluated by measuring floc strength.

• 자원리싸이클링
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• 제17권4호
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• pp.10-20
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• 2008

본 연구는 아직까지 활용실적이 적은 제지슬러지소각재를 대량으로 활용할 수 있는 방법을 도출하기 위하여 제지슬러지소각재를 시멘트의 대체재로 사용하고자 하였다. 또한 제지슬러지소각재 대체 시 나타나는 단점인 수화열 및 흡수율의 증가로 인한 수축균열을 폴리프로필렌섬유 및 셀룰로오스섬유를 혼입하여 이에 대한 제어효과를 고찰하여 제지슬러지소각재의 시멘트 대체재로써의 활용가능성을 규명하였다.

• 한국양봉학회지
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• 제34권4호
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• pp.315-323
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• 2019

Large amounts of sludge produced by paper mill industries represent one of the most serious environmental problems in the world. Recently, beekeepers living in the neighborhood of the paper mill in Hwasan County, Youngcheon city, GB, Korea, became alarmed that honey bee colonies were dying off suddenly across the neighborhood. A preliminary study was conducted to evaluate the toxicity (oral, fumigation, repellent) of recycled solid paper mill sludge (SPMS) and leachate paper mill sludge (LPMS) to honey bee workers under laboratory conditions, and to analyze the volatile organic compounds(VOC). The SPMS and LPMS were separately subjected to a liquid-liquid extraction (LLE) at three temperatures to extract VOC(highest VOC yields: 1.52% SPMS and 0.34% LPMS). A total of 70 chemicals were detected in the VOC of paper mill sludges, of which 49 and 21 volatile organic compounds from SPMS and LPMS, respectively. The SPMS was dominated by high degree presence of stanols (saturated sterols), such as cholestanol, cholestan-3-ol and also saturated hydrocarbons. However, LPMS was characterized by the absence of sterols. Both SPMS and LPMS showed an influence on the olfactory behavior of honey bee on Y-tube assay, with repulsion rates of 72 and 68%, respectively. Both SPMS and LPMS at concentration of 100mg/mL caused higher honey bee oral mortality than the untreated controls at 48, 72, 96 and 120 hours after treatment(highest oral mortality at 120 hr: 85.74%(SPMS); 93.51 % (LPMS)). A similar pattern was observed when honey bees were tested to fumigant toxicity. Both SPMS and LPMS caused significant higher mortality than the untreated control 24 hour after the exposure (highest fumigation mortality at 120 hr: 69.4% (SPMS); 56.8% (LPMS)). These preliminary results indicated that paper mill sludge could be partly responsible for sudden death and disappearance of honey bees, especially in hot humid summer days. With climate change, the risk of environmental chemical exposure to honey bee would pose greater attention.

• 펄프종이기술
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• 제46권4호
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• pp.85-92
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• 2014

The disposal of the paper mill sludge and the paper mill sludge ash become more important issue, because the environment regulation becomes more strict. In this study, the new mulching system was developed by using the paper sludge ash. The soil surface hardening mechanism for mulching with paper sludge ash, red clay and coal ash was evaluated. Since the CaO in the paper sludge ash provided the harden structure with water, the surface hardening mulching structure could cover the field surface and prevent the germination of weeds. More than 50 w.t.% of red clay and 10 w.t.% of paper sludge ash were required to create the solid soil surface structure for mulching. The field test with the new soil surface hardening mulching system for three months showed the generation of weeds could successfully be inhibited by the system.

• Journal of Microbiology and Biotechnology
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• 제15권1호
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• pp.40-47
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• 2005

Modeling and simulation for simultaneous saccharification and fermentation (SSF) process in bioconversion of paper mill sludge to lactic acid was carried out. The SSF process combined the enzymatic hydrolysis of paper mill sludge into glucose and the fermentation of glucose into lactic acid in one reactor. A mathematical modeling for cellulose hydrolysis was developed, based on the proposed mechanism of cellulase adsorption deactivation. Another model for simple lactic acid fermentation was also made. A whole mathematical model for SSF was developed by combining the above two models for cellulose hydrolysis and lactic acid fermentation. The characteristics of the SSF process were investigated using the mathematical model.

• 한국농공학회지
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• 제34권3호
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• pp.75-84
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• 1992

The paper manufactories in Sangpyeong Industrial Estates, Chinju, produce more than 80 tons of paper-mill sludge cakes every day, which costs about 840 million won for dump per year. Since the paper-mill sludge is biodegradable, the sludge can he utilized as an organic fertilizer if it is properly decomposed. This may lead to not only dramatic cut of the treatment cost but prevention from secondary environmental contamination due to dump. The primary objective of the study was to explore the quantitative range of major enviromental parameters influencing early composting of paper-mill cakes, naturally pretreated in warn and cold weather. The automatically-controlled reactor was designed, manufactured, and operated for nine days to decompose about 2201 of raw sludge cakes. Four tests(Test 1-Test 4) were implemented for the study of Phase I. Treatments of two levels of initial temperature (40˚C and 28˚C) and two levels of water content + C/N ratio (35% + 40 and 63% + 80) were made to test the significance of their parameters for decomposition of raw sludge cakes pretreated in warm weather. Another four tests (Test 5- Test 8) were implemented for the study of Phase II. Treatments of initial temperature and water content(W/C) + C/N ratio of raw sludge pretreated in cold weather were made to 16˚C and 13% +58 for Test 5, 6˚C and 53% +55 for Test 6, 7˚C and 36% +81 for Test 7, 31˚C and 30% +81 for Test 8. Natural weater condition(pretreatment condition) revealed the importance m composting of the paper-mill sludge cakes. Combination of water content adjustment to about 30% with C/N ratio amendment of about 20 and initial temperature of 30~40˚C was concluded to be the best for early composting of paper-mill sludge cakes with aeration rate and pH fixed. Temperature and C/N ratio were adapted as judging variables for composting degree. In addition, tests for microbial activity were performed to validate the experimental results. Since the temperature and C/N ratio did not coincide in some tests as judging variables for the maturity of the composting sludges, taking one of these parameters could mislead the concept of the maturity (composting conceptually new criterion to provide more reliable information for early composting of paper-mill sludge cakes.