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Adsorption Characteristics of Flue Gas Components on Zeolite 13X and Effects of Impurity (제올라이트 13X에 의한 배가스 성분의 흡착 특성 및 불순물의 영향)

  • Suh, Sung-Sup;Lee, Ho-Jin
    • Korean Chemical Engineering Research
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    • v.54 no.6
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    • pp.838-846
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    • 2016
  • Most of combustion processess used in industries require recovering or removing flue gas components. Recently a new MBA (moving bed adsorption) process for recovering $CO_2$ using zeolite 13X was developed. In this study, adsorption experiments for carbon dioxide, nitrogen, sulfur dioxide, and water vapor on zeolite 13X were carried out. Adsorption equilibrium and adsorption rate into solid particle were investigated. Langmuir, Toth, and Freundlich isotherm parameters were calculated from the experiment data at various temperatures. Experimental results were consistent with the theoretically predicted values. Also $CO_2$ adsorption amount was measured under the conditions with impurities such as $SO_2$ and $H_2O$. Binary adsorption data were well fitted to the extended Langmuir isotherm using parameters obtained from pure component experiment. However, $H_2O$ impurity less than, roughly, ${\sim}10^{-5}H_2O\;mol/g$ zeolite 13X enhanced slightly $CO_2$ adsorption. Spherical particle diffusion model well described experimentally measured adsorption rate. Diffusion coefficients and activation energies of $CO_2$, $SO_2$, $N_2$, $H_2O$ were obtained. Diffusion coefficients of $CO_2$ and $SO_2$ decreased with small amount of preadsorbed impurity. Parameter values from this study will be helpful to design of real commercial adsorption process.

Bit-Rate Control Using Histogram Based Rate-Distortion Characteristics (히스토그램 기반의 비트율-왜곡 특성을 이용한 비트율 제어)

  • 홍성훈;유상조;박수열;김성대
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.24 no.9B
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    • pp.1742-1754
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    • 1999
  • In this paper, we propose a rate control scheme, using histogram based rate-distortion (R-D) estimation, which produces a consistent picture quality between consecutive frames. The histogram based R-D estimation used in our rate control scheme offers a closed-form mathematical model that enable us to predict the bits and the distortion generated from an encoded frame at a given quantization parameter (QP) and vice versa. The most attractive feature of the R-D estimation is low complexity of computing the R-D data because its major operation is just to obtain a histogram or weighted histogram of DCT coefficients from an input picture. Furthermore, it is accurate enough to be applied to the practical video coding. Therefore, the proposed rate control scheme using this R-D estimation model is appropriate for the applications requiring low delay and low complexity, and controls the output bit-rate ad quality accurately. Our rate control scheme ensures that the video buffer do not underflow and overflow by satisfying the buffer constraint and, additionally, prevents quality difference between consecutive frames from exceeding certain level by adopting the distortion constraint. In addition, a consistent considering the maximum tolerance BER of the voice service. Also in Rician fading channel of K=6 and K=10, considering CLP=$10^{-3}$ as a criterion, it is observed that the performance improment of about 3.5 dB and 1.5 dB is obtained, respectively, in terms of $E_b$/$N_o$ by employing the concatenated FEC code with pilot symbols.

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Performance of Radio Communication DS/CDMA System with Diversity Technique and BCH Coding under Impulsive Noise and Nakagami Fading (임펄스 잡음과 나카가미 페이딩이 존재할 때 다이버시티 기법과 오류정정 부호를 이용한 무선통신 DS/CDMA 시스템의 오율 특성)

  • 김지웅;강희조;이권현
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.10 no.4
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    • pp.539-549
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    • 1999
  • In this paper, the bit error rare (BER) performance of DS/CDMA DQPSK communication system in the presence of multi access interference, impulsive noise and Nakagami fading is investigated. The DS/CDMA DQPSK communication system adopts Maximum Ratio Combining (MRC) diversity reception and error correcting BCH code technique to enhance system performance. Using the derived error probability equation, the error rate performance of DS/CDMA DQPSK communication system has been evaluated and shown in figures to discuss as a function of impulsive index(A), Gaussian noise to impulsive noise power ratio($\Gamma$'), multi access interference(Κ), Nakagami fading parameter(m), the number of diversity branch (L), the number of error correction symbol (t), PN code sequence length(N) and $E_b/N_0$. The error performance of DS/CDMA-MDPSK signals improve by adopting MRC diversity and BCH(15,7) coding technique in the environment of impulsive noise plus Nagakami fading. From the results, we known that proposed system is affected by multi access interference, impulsive noise and Nakagami fading in radio communication system environment. Also, BER performance of DS/CDMA DQPSK communication system cam be improved increasing either the power of desired signal or the value of Gaussian noise to impulsive noise power ratio. And BCH(15,7) code technique is more effective to restrain the affection of multi access, interference, impulsive noise and Nakagami fading in DS/CDMA DQPSK communication system than MRC diversity reception technique.

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QoS and Multi-Class Service Provisioning with Distributed Call Admission Control in Wireless ATM Networks (무선 ATM망에서 QoS와 다중 서비스를 지원하는 분산된 호 수락 제어 알고리즘과 성능 분석)

  • Jeong, Da-Ip;Jo, Yeong-Jong
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.37 no.2
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    • pp.45-53
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    • 2000
  • In wireless environment, due to the limited capacity of radio channels it is not easy to guarantee QoS provisioning to mobile users. Therefore, one of the key problems to support broadband multimedia multi-services in wireless ATM networks is to study an effective call admission control(CAC). The purpose of this paper is to propose a distributed CAC scheme that guarantees multi QoS and multi-class service. Control parameters of the proposed scheme are QoS threshold and channel overload probability. With these parameter control, we show that the scheme can guarantee the requested QoS to both new and handover calls. In the scheme, channels are allocated dynamically, and QoS measurements are made in a distributed manner. We show that by providing variable data rate to calls it can effectively prohibit the QoS degradation even if there are severe fluctuations of network traffic. We compare the proposed CAC scheme to the well-known schemes such as guard band call admission control scheme. Through numerical examples and simulations, the proposed scheme is shown to improve the performance by lowering the probability of handover call dropping

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A Design of a 5 GHz Low Phase Noise Voltage Tuned Dielectric Resonator Oscillator Using Loop Group Delay (루프 군지연을 이용한 저위상 잡음 5 GHz 전압제어 유전체 공진기 발진기 설계)

  • Son, Beom-Ik;Jeong, Hae-Chang;Yeom, Kyung-Whan
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.25 no.3
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    • pp.269-281
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    • 2014
  • In this paper, a systematic design of a low phase noise voltage-tuned dielectric resonator oscillator(VTDRO) using loop group delay is proposed. Designed VTDRO is closed-loop type and consists of a cascade connection of a resonator, phase shifter, and amplifier. Firstly, a reference VTDRO is fabricated and its phase noise and electrical frequency tuning range are measured. Both the phase noise and electrical frequency tuning range depend on the loop group delay. Then, a required value of loop group delay for a new VTDRO with a low phase noise can be systematically computed. In addition, its phase noise and electrical frequency tuning range can be theoretically estimated using those obtained from the measurement of the reference VTDRO. When the loop group delay increases, the phase noise decreases and the electrical frequency tuning range also decreases. The former predominantly depends on the resonator structure. Therefore we propose a systematic design procedure of a resonator with high group delay characteristics. The measured loop group delay of the new VTDRO is about 700 nsec. The measured phase noise of the new VTDRO show a state-of-the-art performance of 154.5 dBc/Hz at 100 kHz frequency offset and electrical frequency tuning range of 448 kHz for a voltage change of 0~10V. The oscillation power is about 4.39 dBm.

The Extreme Value Analysis of Deepwater Design Wave Height and Wind Velocity off the Southwest Coast (남서 해역 심해 설계 파고 및 풍속의 극치분석)

  • Kim, Kamg-Min;Lee, Joong-Woo;Lee, Hun;Yang, Sang-Yong;Jeong, Young-Hwan
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.29 no.1
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    • pp.245-251
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    • 2005
  • When we design coastal and harbol facilities deepwater design wave and wind speed are the important design parameters. Especially, the analysis of these informations is a vital step for the point of disaster prevention. In this study, we made and an extreme value analysis using a series of deep water significant wave data arranged in the 16 direction and supplied by KORDI real-time wave information system ,and the wind data gained from Wan-Do whether Station 1978-2003. The probability distributions considered in this characteristic analysis were the Weibull, the Gumbel, the Log-Pearson Type III, the Normal, the Lognormal, and the Gamma distribution. The parameter for each distribution was estimated by three methods, i.e. the method of moments, the maximum likelihood, and the method of probability weight moments. Furthermore, probability distributions for the extreme data had been selected by using Chi-square and Kolmogorov-Smirnov test within significant level of 5%, i,e. 95% reliance level. From this study we found that Gumbel distribution is the most proper model for the deep water design wave height off the southwest coast of Korea. However the result shows that the proper distribution made for the selected site is varied in each extreme data set.

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Plume Rise and Initial Dilution Determination Reflecting the Density Profile over Entire Water Column (해수 전체 컬럼에서 밀도 분포를 반영한 플룸 상승과 초기 희석도 결정)

    • Journal of Korean Port Research
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    • v.11 no.2
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    • pp.215-230
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    • 1997
  • A number of ocean outfalls are located around coastal area over the United States and discharge primary treated effluent into deep water for efficient wastewater treatment. Two of them, the Sand Island and Honouliuli municipal wastewater outfalls, are located on the south coast of Oahu. There have been growing interests about the plume dynamics around the ocean outfalls since plume discharged from the multiport diffuser may have significant impacts on coastal communities and immediate consequence on public health. Among the studies of plume dynamics performed in the vicinity of both outfalls, Project MB-4 in the Mamala Bay Study recently made with the funding in the $ 9 million amount statistically dealt with the near-field behavior of the plumes at the Sand Island and Honouliuli outfalls. However, Project MB-4 predicted much higher surfacing frequency than the realistic value obtained by model studies by Oceanit Laboratories, Inc.. It is suggested that improvements should be made in the application of the plume model to more simulate the actual discharge characteristics and ocean conditions. In this study, it has been recommended that input parameters in plume models reflect realistic density profile over the entire water column since. in the previous Mamala Bay Study, the density profiles were measured at 5m depth increments extending from 13 to 63 m depth (the density profile on the upper portion of water column was not included, Roberts 1995). It is proved that the density stratification is the important parameter for the submergence of the plume. In this study, as one of the important parameters, plume rise and initial dilution reflecting the density profile over the entire water column have been taken into account for more reliable plume behavior description.

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Total Management System for Earth Retaining Structures Using Observational Method (지반굴착 흙막이공의 정보화시공 종합관리 시스템)

  • 오정환;조철현;김기웅;백영식
    • Journal of the Korean Geotechnical Society
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    • v.18 no.2
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    • pp.51-64
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    • 2002
  • Observational results of ground movement during the construction were very different from those predicted during the analysis of design step because of the uncertainty of the numerical analysis modelling, the soil parameter, and the condition of a construction field, etc., however accurately numerical analysis method was applied for prediction of ground movement per the excavation step. Therefore, the management system through the construction field measurement should be achieved for grasping the situation during the excavation. Until now, the measurement system restricted by 'Absolute Value Management system'analyzing only the stability of present step has been executed. So, it was difficult to expect the prediction of ground movement fur the next excavation step. In this situation, this study developed 'The Management system TOMAS-EXCAV'consisted of 'Absolute value management system'analyzing the stability of present step and 'Prediction management system'expecting the ground movement of next excavation step and analyzing the stability of next excavation step by 'Back Analysis'. TOMAS-EXCAV could be applied to all the uncertainty of earth retaining structures analysis by connecting 'Forward analysis program'and 'Back analysis program'and optimizing the main design variables using SQP-MMFD optimization method through measurement results. The applicability of TOMAS-EXCAV was confirmed by back analysis selecting two earth retains construction fields.

Assessment of Impact-echo Method for Cavity Detection in Dorsal Side of Sewer Pipe (하수관거 배면 공동 탐지를 위한 충격반향법의 적용성 평가)

  • Song, Seokmin;Kim, Hansup;Park, Duhee;Kang, Jaemo;Choi, Changho
    • Journal of the Korean Geotechnical Society
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    • v.32 no.8
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    • pp.5-14
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    • 2016
  • The leakage of water under sewer pipelines is one of main sources of sinkholes in urban areas. We performed laboratory model tests to investigate the presence of cavities using impact-echo method, which is a nondestructive test method. To simulate a concrete sewer pipe, a thin concrete plate was built and placed over container filled with sand. The cavity was modeled as an extruded polystyrene foam box. Two sets of tests were performed, one over sand and the other on cavity. A new impact device was developed to apply a consistent high frequency impact load on the concrete plate, thereby increasing the reliability of the test procedure. The frequency and transient characteristics of the measured reflected waveforms were analyzed via fast Fourier transform and short time Fourier spectrum. It was shown that the shapes of Fourier spectra are very similar to one another, and therefore cannot be used to predict the presence of cavity. A new index, termed resonance duration, is defined to record the time of vibration exceeding a prescribed intensity. The results showed that the resonance duration is a more effective parameter for predicting the presence of a cavity. A value of the resonance period was proposed to estimate the presence of cavity. Further studies using various soil types and field tests are warranted to validate the proposed approach.

Experimental Study on Adfreeze Bond Strength Between Frozen Sand and Aluminium with Varying Freezing Temperature and Vertical Confining Pressure (동결온도와 수직구속응력 변화에 따른 모래와 알루미늄 재료의 접촉면에서 작용하는 동착강도 실험 연구)

  • Ko, Sung-Gyu;Choi, Chang-Ho
    • Journal of the Korean Geotechnical Society
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    • v.27 no.9
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    • pp.67-76
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    • 2011
  • Bearing capacity of pile foundations in cold region is dominated by adfreeze bond strength between surrounding soil and pile perimeter. Adfreeze bond strength is considered to be the most important design parameter for foundations in cold region. Many studies in last 50 years have been conducted to analyze characteristics of adfreeze bond strength. However, most studies have been performed under constant temperature and normal stress conditions in order to analyze affecting factors like soil type, pile material, loading speed, etc. In this study, both freezing temperature and normal stress acting on pile surface were considered to be primary factors affecting adfreeze bond strength, while other factors such as soil type, pile material and loading speed were predefined. Direct shear box was used to measure adfreeze bond strength between Joomoonjin sand and aluminium because it is easy to work for various roughness. Test was performed with temperatures of > $0^{\circ}C$, $-1^{\circ}C$, $-2^{\circ}C$, $-5^{\circ}C$, and $-10^{\circ}C$ and vertical confining pressures of 1atm, 2atm, and 3atm. Based on the test results, the effects of temperature and vertical stress on adfreeze bond strength were analyzed. The test results showed that adfreeze bond strength increases with decreased temperature and increased vertical stress. It was also noted that two types of distinct sections exist, owing to the rate of increase of adfreeze bond strength along the change of freezing temperature: 1)rapidly increasing section and 2)gradually decreasing section. In addition, the results showed that a main factor affecting adfreeze bond strength switches from friction angle to adhesion as freezing temperature decreases.