• Title/Summary/Keyword: Particle bound

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Concentration and Seasonal Variation of Particle PCBs in Air

  • Yeo Hyun-Gu;Chun Man-Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.E1
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    • pp.13-21
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    • 2005
  • Atmospheric concentrations of PCBs were monitored in Ansung-city, Kyonggi province during the 2001/2002 to characterize the concentration distribution and seasonal variation of particle polychlorinated biphenyls (PCBs). Average concentration of particle bound PCB showed maximum value for penta-CBs and minimum value for octa-CBs. Seasonal contributions $(%\)$ of total particle PCBs showed the highest value in winter months and lowest value in summer month, This result indicated that concentration of total particle PCBs increased with decreasing temperature in the atmosphere. Therefore, particle PCBs were easily formed by the condensation of gas phase PCBs in winter months. The total particle PCBs exhibited an inverse correlation with temperature (p<0.01) which suggested that particle PCBs were easily formed by condensation of gaseous PCBs in winter months.

ESTIMATION OF RAIN SCAVENGING RATIO FOR PARTICLE BOUND POLYCYCLIC AROMATIC HYDROCARBONS AND POLYCHLORINATED BIPHENYLS

  • Kim, Hyeon-Kook;Shin, Yong-Seung;Lee, Dong-Soo;Song, Byung-Joo;Kim, Jong-Guk
    • Environmental Engineering Research
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    • v.11 no.1
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    • pp.33-44
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    • 2006
  • The objective of this study was to develop and assess a method for estimating the rain scavenging ratios (RSRs) of particle-bound PAHs and PCBs using measured scavenging ratio of particulate matters (PM) and routinely available data of physico-chemical properties of PM. Paired atmospheric and rainwater sampling was conducted for a total of 4 rain events. Assuming equilibrium partitioning in rainwater-gas-PM system, an equation was derived for estimating the RSR of particle-bound chemicals as a function of RSR of PM and three equilibrium partition constants (i.e. dimensionless Henry's law constant, gas-particle partition coefficient, and water-particle partition coefficient). For all PAHs, the model significantly under-predicted the RSR while the model prediction for PCBs agreed with observation mostly within a factor of 5. The RSR model for the chemicals is of limited use as its accuracy critically depends on how close the observed partitioning of the chemicals in the gas-PM-rainwater system is to that estimated under the equilibrium assumption.

Ambient Fine and Ultrafine Particle Measurements and Their Correlations with Particulate PAHs at an Elementary School Near a Highway

  • Song, Sang-Hwan;Paek, Do-Myung;Lee, Young-Mee;Lee, Chul-Woo;Park, Chung-Hee;Yu, Seung-Do
    • Asian Journal of Atmospheric Environment
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    • v.6 no.2
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    • pp.96-103
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    • 2012
  • Ambient particulate matter (PM) and particle-bound polycyclic aromatic hydrocarbon (PAH) concentrations were measured continuously for 70 days at a Korean elementary school located near a highway. The $PM_{10}$, $PM_{2.5}$, and $PM_1$ values were measured with a light-scattering, multi-channel, aerosol spectrometer (Grimm, Model 1.107). The number concentrations of the particles were measured using a scanning mobility particle sizer and counter (SMPS+C) which counted particles from 11.1 to 1083.3 nm classified in 44 channels. Particle-bound PAHs were measured with a direct reading, photoelectric aerosol sensor. The daily $NO_2$, $SO_2$, and CO concentrations were obtained from a national air-monitoring station located near the school. The average concentrations of $PM_{10}$, $PM_{2.5}$, and $PM_1$ were 75.3, 59.3, and $52.1{\mu}g/m^3$, respectively. The average number concentration of the ultrafine particles (UFPs) was $46,307/cm^3$, and the averaged particle-bound PAHs concentration was $17.9ng/cm^3$ during the study period. The ambient UFP variation was strongly associated with traffic intensity, particularly peak concentrations during the traffic rush hours. Particles <100 nm corresponded to traffic-related pollutants, including PAHs. Additional longterm monitoring of ambient UFPs and high-resolution traffic measurements should be carried out in future studies. In addition, transient variations in the ambient particle concentration should be taken into consideration in epidemiology studies in order to examine the short-term health effects of urban UFPs.

Effects of Inorganic Fillers on Mechanical Properties of Silicone Rubber

  • Kim, Gyu Tae;Lee, Young Seok;Ha, KiRyong
    • Elastomers and Composites
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    • v.54 no.2
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    • pp.142-148
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    • 2019
  • In this study, the effects of filler particle size and shape on the physical properties of silicone rubber composites were investigated using inorganic fillers (Minusil 5, Celite 219, and Nyad 400) except silica, which was already present as a reinforcing filler of silicone rubber. Fillers with small particle sizes are known to facilitate the formation of the bound rubber by increasing the contact area with the polymer. However, in this experiment, the bound rubber content of Celite 219-added silicone composite was higher than that of Minusil 5-added silicone composite. This was attributed to the porous structure of Celite 219, which led to an increase in the internal surface area of the filler. When the inorganic fillers were added, both thermal decomposition temperature and thermal stability were improved. The bound rubber formed between the silicone rubber and inorganic filler affected the degree of crosslinking of the silicone composite. It is well-known that as the size of the reinforcing filler decreases, the reinforcing effect increases. However, in this experiment, the hardness of the composite material filled with Celite 219 was the highest compared to the other three composites. Furthermore, the highest value of 2.19 MPa was observed for 100% modulus, and the fracture elongation was the lowest at 469%. This was a result of excellent interaction between Celite 219 filler and silicone rubber.

COSMOLOGY WITH MASSIVE NEUTRINOS: CHALLENGES TO THE STANDARD ΛCDM PARADIGM

  • ROSSI, GRAZIANO
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.321-325
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    • 2015
  • Determining the absolute neutrino mass scale and the neutrino mass hierarchy are central goals in particle physics, with important implications for the Standard Model. However, the final answer may come from cosmology, as laboratory experiments provide measurements for two of the squared mass differences and a stringent lower bound on the total neutrino mass - but the upper bound is still poorly constrained, even when considering forecasted results from future probes. Cosmological tracers are very sensitive to neutrino properties and their total mass, because massive neutrinos produce a specific redshift-and scale-dependent signature in the power spectrum of the matter and galaxy distributions. Stringent upper limits on ${\sum}m_v$ will be essential for understanding the neutrino sector, and will nicely complement particle physics results. To this end, we describe here a series of cosmological hydrodynamical simulations which include massive neutrinos, specifically designed to meet the requirements of the Baryon Acoustic Spectroscopic Survey (BOSS) and focused on the Lyman-${\alpha}$ ($Ly{\alpha}$) forest - also a useful theoretical ground for upcoming surveys such as SDSS-IV/eBOSS and DESI. We then briefly highlight the remarkable constraining power of the $Ly{\alpha}$ forest in terms of the total neutrino mass, when combined with other state-of-the-art cosmological probes, leaving to a stringent upper bound on ${\sum}m_v$.

The Critical Pigment Volume Concentration Concept for Paper Coatings: II. Later-Bound Clay; Ground Calcium Carbonate, and Clay- carbonate Pigment Coatings

  • Lee, Do-Ik
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.5
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    • pp.18-38
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    • 2002
  • A previous study on the model coatings based on latex-bound plastic pigment coatings (1) has been extended to latex-bound No. 1 clay, ultra-fine ground calcium carbonate (UFGCC), and clay-carbonate pigment mixture coatings, which are being widely used in the paper industry. The latex binder used was a good film-forming, monodisperse S/B latex or 0.15$\mu\textrm{m}$. No. 1 clay was representative of plate-like pigment particles, whereas UFGCC was of somewhat rounded rhombohedral pigment particlel. Both of them had negatively skewed triangular particle size distributions having the mean particle suet of 0.7${\mu}{\textrm}{m}$ and 0.6$\mu\textrm{m}$, respectively. Their packing volumes were found to be 62.5% and 657%, respectively. while their critical pigment volume concentrations (CPVC's) were determined to be 52.7% and 50.5% ( average of 45% caused by the incompatibility and 55.9% extrapolated) by coating porosity, respectively. Each pigment/latex coating system has shown its unique relationship between coating properties and pigment concentrations, especially above its CPVC. Notably, the clay/latex coating system hat shown higher coating porosity than the UFGCC/latex system at high pigment concentrations above their respective CPVC's. It was also found that their coating porosity and gloss were inter-related to each other above the CPVC's, as predicted by the theory. More interestingly, the blends of these two pigments have shown unique rheological and coating properties which may explain why such pigment blends are widely used in the industry. These findings have suggested that the unique structure of clay coatings and the unique high-shear rheology of ground calcium carbonate coatings can be judiciously combined to achieve superior coatings. Importantly, the low-shear viscosity of the blends was indicative of their unique packing and coating structure, whereas their high-shear rheology was represented by a common mixing rule, i.e., a viscosity-averaging. Transmission and scanning electron and atomic force microscopes were used to probe the state of pigment / latex dispersions, coating surfaces, freeze fractured coating cross-sections, and coating surface topography. These microscopic studies complemented the above observations. In addition, the ratio, R, of CPVC/(Pigment Packing Volume) has been proposed as a measure of the binder efficiency for a given pigment or pigment mixtures or as a measure of binder-pigment interactions. Also, a mathematical model has been proposed to estimate the packing volumes of clay and ground calcium carbonate pigments with their respective particle size distributions. As well known in the particle packing, the narrower the particle size distributions, the lower the packing volumes and the greater the coating porosity, regardless of particle shapes.

Effects of Contamination Source and Particle Size on Arsenic Speciation and Bioaccessibility in Soils (오염원에 따른 토양 입경 별 비소의 오염특성 및 생물학적 접근성 평가)

  • Kwon, Ye-Seul;Kim, Eun Jung
    • Journal of Soil and Groundwater Environment
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    • v.22 no.5
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    • pp.89-97
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    • 2017
  • In this study, we evaluated effect of particle size on arsenic solid-state speciation and bioaccessibility in soils highly contaminated with arsenic from smelting and mining. Soils were partitioned into six particle size fractions ($2000-500{\mu}m$, $500-250{\mu}m$, $250-150{\mu}m$, $150-75{\mu}m$, $75-38{\mu}m$, <$38{\mu}m$), and arsenic solid-state speciation and bioaccessibility were characterized in each particle size fraction. Arsenic solid-state speciation was characterized via sequential extraction and XRD analysis, and arsenic bioaccessibility was evaluated by SBRC (Solubility Bioaccessibility Research Consortium) method. In smelter site soil, arsenic was mainly present as arsenic bound to amorphous iron oxides. Fine particle size fractions showed higher arsenic concentration, but lower arsenic bioaccessibility. On the other hand, arsenic in mine site soil showed highest concentration in largest particle size fraction ($2000-500{\mu}m$), while higher bioaccessibility was observed in smaller particle size fractions. Arsenic in mine site soil was mainly present as arsenolite ($As_2O_3$) phase, which seemed to affect the distribution of arsenic and arsenic bioaccessibility in different particle size fractions of the mine soil.

Object Tracking in 3-D Space with Passive Acoustic Sensors using Particle Filter

  • Lee, Jin-Seok;Cho, Shung-Han;Hong, Sang-Jin;Lim, Jae-Chan;Oh, Seong-Jun
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.5 no.9
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    • pp.1632-1652
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    • 2011
  • This paper considers the object tracking problem in three dimensional (3-D) space when the azimuth and elevation of the object are available from the passive acoustic sensor. The particle filtering technique can be directly applied to estimate the 3-D object location, but we propose to decompose the 3-D particle filter into the three planes' particle filters, which are individually designed for the 2-D bearings-only tracking problems. 2-D bearing information is derived from the azimuth and elevation of the object to be used for the 2-D particle filter. Two estimates of three planes' particle filters are selected based on the characterization of the acoustic sensor operation in a noisy environment. The Cramer-Rao Lower Bound of the proposed 2-D particle filter-based algorithm is derived and compared against the algorithm that is based on the direct 3-D particle filter.

Tidal Disruption Flares from Stars on Bound Orbits

  • Hayasaki, Kimitake;Stone, Nicholas;Loeb, Abraham
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.60.1-60.1
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    • 2013
  • We study tidal disruption and subsequent mass fallback process for stars approaching supermassive black holes on bound orbits, by performing three dimensional Smoothed Particle Hydrodynamics simulations with a pseudo-Newtonian potential. We find that the mass fallback rate decays with the expected -5/3 power of time for parabolic orbits, albeit with a slight deviation due to the self-gravity of the stellar debris. For eccentric orbits, however, there is a critical value of the orbital eccentricity, significantly below which all of the stellar debris is bound to the supermassive black hole. All the mass therefore falls back to the supermassive black hole in a much shorter time than in the standard, parabolic case. The resultant mass fallback rate considerably exceeds the Eddington accretion rate and substantially differs from the -5/3 power of time. We also show that general relativistic precession is crucial for accretion disk formation via circularization of stellar debris from stars on moderately eccentric orbits.

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