• Bulletin of the Korean Chemical Society
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• 제33권10호
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• pp.3391-3396
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• 2012

Two-dimensional infrared (2D-IR) spectroscopy can probe the fast structural evolution of molecules under thermal equilibrium. Vibrational frequency fluctuation caused by structural evolution produced the time-dependent line shape change in 2D-IR spectrum. A variety of methods has been used to connect the evolution of 2D-IR spectrum with Frequency-Frequency Correlation Function (FFCF), which connects the experimental observables to a molecular level description. Here, a new method to extract FFCF from 2D-IR spectra is described. The experimental observable is the time-dependent frequency shift of maximum peak position in the slice spectrum of 2D-IR, which is taken along the excitation frequency axis. The direct relation between the 2D-IR peak shift and FFCF is proved analytically. Observing the 2D-IR peak shift does not need the full 2D-IR spectrum which covers 0-1 and 1-2 bands. Thus data collection time to determine FFCF can be reduced significantly, which helps the detection of transient species.

• 한국초전도ㆍ저온공학회논문지
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• 제5권1호
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• pp.111-117
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• 2003

In the design of the split type free displacer Stilting cryocooler the motion of the displacer is very important to decide the cooling capacity, which depends upon the working gas pressure, the swept volume in the compression space and the expansion space, operating frequency, the phase shift between piston and displacer, etc. In this study, Stirling cryocooler actuated by the electric farce of the dual linear motor is designed and manufactured. Cool down characteristics of the cold end with laser displacement sensor in the expander of the Stilting cryocooler is evaluated. The charging pressure was 15kg$_{f}$/$\textrm{cm}^2$ and operating frequency was 50Hz. Input power and the lowest temperature were about 32W and 67K, respectively. And, displacement of the piston is measured by LVDTs (Linear Variable Differential Transformers), displacement of thedisplacer is measured by laser optic method, and phase shift between piston and displacer is discussed. As the peak-to-peak pressure of the compressor was increased, peak-to-peak displacement of the displacer was increased. The peak-to-peak displacement of the displacer increases in the range of 0 - 64.5Hz(resonant frequency of the displacer), but decreases steeply when the operating frequency is bigger than the resonant frequency. Finally when the phase shift between displacements of the Piston and displacer is 45。, operating frequency is optimum and is decided by resonant frequency of the expander, mass and cross section area of the displacer and constant by friction and flow resistance.e.

• 한국항공우주학회지
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• 제38권5호
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• pp.456-466
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• 2010

전형적인 하이브리드 모터의 연소 불안정 현상인 DC-Shift는 비선형적 특성을 갖는다. DC-Shift는 두 가지 형태로 나타나게 되는데, 압력이 급격하게 상승하는 양의 DC-shift와 연소 도중에 압력이 갑자기 감소하는 음의 DC-shift로 구분된다. 이 논문에서는 산화제 공급 유동 조건을 다양하게 변화시켜 음의 DC-shift 현상을 유도하고 산화제 공급 유동조건과 하이브리드 로켓이 갖고 있는 기본적인 주파수와 Helmholtz 주파수, 음향모드와의 공진을 유도하여 음의 DC-shift 현상의 발생 조건과 특징에 대하여 알아보았다. 실험 결과 연소 중 수백 Hz 대역의 압력 주파수 이동을 확인하였으며, 음의 DC-Shift가 연소로 발생하는 주파수와 유동의 흐름으로 인한 주파수간 위상이 상호 감쇠되어 발생한 것으로 나타났다. 향후 연소 중 나타나는 주파수의 변화에 따른 DC-Shift 현상에 대해서는 계속 연구되어야 한다.

• 지구물리와물리탐사
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• 제21권1호
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• pp.54-60
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• 2018

탄성파 탐사를 통해 취득된 자료는 적절한 자료처리 및 해석 과정을 거쳐 석유, 가스 자원의 부존여부를 파악하는데 활용할 수 있다. 자원의 부존여부를 지시하는 탄성파 속성은 진폭 정보로부터 도출되며, 이 때 탄성파 고유 감쇠를 표현하는 Q 값은 탄화수소 지시자로서 유용하게 사용된다. 따라서, Q 값을 산출하는 기법의 정확성이 자원 부존여부를 파악하는데 매우 중요한 역할을 한다. 본 연구에서는 수치모형실험을 통해 탄성파 감쇠를 표현하는 Q 값을 산출하고 오차율을 분석하였다. 실제 현장자료를 모사하기 위해 무작위 잡음을 추가한 자료에 대하여 스펙트럼 진폭 비교법과 최대 주파수 이동법을 이용하여 Q 값을 산출하고 오차율을 분석하였다. Q 값을 산출한 결과 무작위 잡음을 추가하여 신호대 잡음비가 90 dB 일 때는 두 가지 방법 모두 비교적 정확한 값을 산출하였으나, 무작위 잡음의 크기가 증가할 경우 최대 주파수 이동법이 스펙트럼 진폭 비교법 보다 정확한 결과를 도출함을 알 수 있었다.

• 말소리와 음성과학
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• 제4권3호
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• pp.43-49
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• 2012

This paper describes the categorical effects of pitch accent contrasts in a mimicry task. It focuses, specifically, on examining how fundamental frequency (f0) variation reflects phonological contrasts from speakers of two distinct varieties of Korean (i.e., North Kyungsang and South Cholla). The results showed that, in a mimicry task using synthetic speech continua, there was a categorical effect in f0 peak timing for North Kyungsang speakers, but the timing of f0 peaks and valleys in the responses of South Cholla speakers was more variable, presenting a gradient or non-categorical effect. Evidence of categorical effects was represented as the shift of f0 peak times along an acoustic continuum for North Kyungsang speakers. The range for the shift of f0 valley times was much narrower, compared to that of f0 peak times. The degree of a shift near the middle of the continuum showed variability across individual mimicry responses. However, the categorical structure in mimicry responses regarding the clustering of f0 peak points was more significant for North Kyungsang speakers than for South Cholla speakers. Additionally, the finding of the current study implies that the location of f0 peak times depends on individuals' imitative (or cognitive) abilities.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2003년도 하계학술연구발표회 및 한.일 공동심포지엄
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• pp.60-61
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• 2003

Theoretical considerations on a giant magneto-impedance (GMI) effect in amorphous ribbons (i.e., thin films) have been made in terms of the expressions of effective permeability and impedance derived in the frame of classical electrodynamics and ferromagnetism. The dependence of GMI effect on the external do magnetic field (H$\_$ext/) and the frequency of alternating current are simulated and discussed in the knowledge of energy conversion consisting of the current energy loss, the ferromagnetic energy consumption, and the magnetic energy storage in the film. The obtained results are summarized as follow: (a) As frequency f< 20 ㎒, the real part of effective permeability (${\mu}$′) changes slightly. The peak of the ${\mu}$′curve always locates at H$\_$ext/=H$\_$ani/ - the anisotropy field. However, the peak value of ${\mu}$′ tends to increase with increasing frequency in the frequency range of 11-20 ㎒. (b) In the frequency range, f= 21-23 ㎒, a negative peak additionally appears. Meanwhile, both the positive and negative peak values rapidly increase with increasing frequency and their peak positions shift towards a high H$\_$ext/. (c) The positive peak value of ${\mu}$′ starts to decrease at f= 29 ㎒ and its negative peak does so at about 35 ㎒. Then, both peaks keep such a tendency and their peak positions move to high H$\_$ext/, as increasing frequency. (d) The dependence of the imaginary part of effective permeability (${\mu}$") on the external dc magnetic field and the frequency of the alternating field indicates that there is only one peak involved in ${\mu}$" for the whole frequency range. (e) The impedance vs. magnetic field curves at various frequencies show that there is a critical value of frequency around f= 18-19 ㎒ where the transition between two frequency regimes occurs; the one (low frequency) in which ${\mu}$′ predominantly contributes to the GMI effect and the other (high frequency) in which ${\mu}$" determines the GMI effect.

• Bulletin of the Korean Chemical Society
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• 제32권11호
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• pp.4011-4015
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• 2011

We explored the interpretation of the well-accepted correlation between the apparent peak maximum position shift and extent of molecular interactions, like hydrogen bonding and dipole-dipole interactions, based on the overlapped multiple band model. The simulation of two overlapped Lorentzian bands was carried out to interpret how the maximum position of a composite peak relates to the relative contributions of two species representing the different levels of molecular interactions, i.e., free (or very weekly bound) vs. strongly bound. To demonstrate the validity of our interpretation of the origin of the peak position shift, the temperaturedependent IR spectra of ethylene glycol were also analyzed. It was found through the analysis of simulated and experimental spectra that the apparent peak shift in certain case can be safely interpreted as the measure of the strength of hydrogen bonding. The result of this study gives a new insight to interpret molecular interactions probed by vibrational spectroscopy.

• 방송공학회논문지
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• 제19권6호
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• pp.967-970
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• 2014

이 논문에서는 M-FSK(frequency shift keying) 변조신호를 자동으로 분류하는데 필요한 효율적인 첨두 검출 방법을 제안하였다. 다른 디지털 변조신호와 FSK 신호는 진폭 스펙트럼의 특성을 이용하여 분류할 수 있다. FSK 신호의 진폭 스펙트럼은 다른 디지털 변조신호와 다르게 변조차수와 동일한 수의 첨두를 나타낸다. 일반적으로 신호의 첨두를 검출하기 위해서는 임계치가 필요한데, 변조인식과 같이 사전에 신호에 대한 정보가 없는 경우 임계치를 정하기 어려운 점이 있다. 이 논문에서는 진폭 스펙트럼의 히스토그램을 이용하여 자동으로 간단하게 임계치를 결정하는 방법을 제시하였다. 모의실험 결과 적은 수의 표본과 잡음이 많은 환경에서도 매우 우수한 분류확률을 나타내었다.

• ETRI Journal
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• 제28권2호
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• pp.235-238
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• 2006

In this letter, a block code that minimizes the peak-to-average power ratio (PAPR) of orthogonal frequency division multiplexing (OFDM) signals is proposed. It is shown that peak envelope power is invariant to cyclic shift and codeword inversion. The systematic encoding rule for the proposed code is composed of searching for a seed codeword, shifting the register elements, and determining codeword inversion. This eliminates the look-up table for one-to-one correspondence between the source and the coded data. Computer simulation confirms that OFDM systems with the proposed code always have the minimum PAPR.

• 조명전기설비학회논문지
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• 제21권4호
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• pp.61-72
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• 2007

This study proposed a high efficiency DC-DC converter with a new current doubler rectifier for fuel-cell systems for use with the Nexa(310-0027) PEMFC from the Ballard Co. The proposed high efficiency DC-DC converter for the fuel-cell system generated ZVS by applying partial resonance and using a phase shift PWM control method. Constantly switching frequency, loss of switching, peak current, and peak voltage were reduced by this system. In addition to this system, two inductors were attached to a rectifier circuit allowing it to be able to provide the direct current(DC) and DC voltage safely to a load with reduced ripple components. Also, by using the newly proposed current doubler rectifier, the high frequency DC-DC converter for the fuel cell system was capable of reaching a highest efficiency of 92[%] as compared to 88.3[%] efficiency in previous results, which means that efficiency increased 3.7[%]. The overall results were confirmed by a simulation and laboratory experiment.