• 한국환경보건학회지
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• 제41권1호
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• pp.49-60
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• 2015

Objectives: Pine needles were used as a passive air sampler (PAS) of atmospheric persistent organic pollutants (POPs). This study was performed to investigate concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) deposited on pine needles near a waste incinerator and PCDD/Fs source contributions using principal component analysis (PCA). Methods: Two-year-old pine needles were sampled at 11 points with respect to distance and wind direction from the incinerator. PCDD/Fs deposited on pine needles were analyzed with HRGC/HRMS. The source contribution of PCA was calculated with SPSS. Results: The average concentration of PCDD/Fs deposited on pine needle was 0.79 (0.27-1.76) pg TEQ/g dry, PCDDs with 0.24 (0.01-0.95) pg TEQ/g dry and PCDFs with 0.56 (0.27-0.82) pg TEQ/g dry, respectively. The average concentration fraction of PCDDs was 29.7%, that of PCDFs was 70.3%, and PCDFs were more prevalent than PCDDs. The contributions of PCDD/Fs sources were estimated as incineration at 58.3% and automobiles at 28.4%. However, a relation and regulation between PCDD/Fs concentrations deposited on pine needles and distance from incinerator or wind direction was not shown. Conclusion: It was concluded that atmospheric PCDD/Fs concentrations near an industrial complex with a waste incinerator were affected by multiple sources. However, PCDD/Fs concentrations were lower than in other inland cities with the exception of background area.