• Journal of the Korean Chemical Society
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• v.67 no.1
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• pp.54-63
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• 2023

In this study, six types of 2015 revised curriculum ChemistryII textbooks were analyzed for conditions, definitions, whether or not critical points were displayed, and real-life examples of phase diagram. In this study, it was confirmed that the problems pointed out in several previous studies were not reflected in the 2015 revised curriculum ChemistryII textbook. The same as the situation defining the phase diagram, the translation of the phase diagram into a phase equilibrium diagram, the distinction between phase and state being unclear, the critical point not being shown in the phase diagram, real life examples are very limited what is being presented as is suggested as a problem. Therefore, it is necessary to reflect the results of various previous studies in the revised curriculum ChemistryII textbook that will be made in the future, specify the conditions under which the phase diagram is drawn, newly model the situation defining the phase diagram, and translate the phase diagram as a 'phase diagram'. It is necessary to use the term, clarify the distinction between phase and state, mark the critical point in the phase diagram, and develop various real-life examples.

• Journal of the Korean Institute of Navigation
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• v.15 no.3
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• pp.99-106
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• 1991

In order to grow InGaAsP epitaxial layer on GaAs by LPE, an accurate phase diagram for In-Ga-As-P quarternary compounds is required. But the short wavelength InGaAsP/GaAs phase diagram for full wavelength range was not yet reported. In this study, therefore, a theoretical calculation has been carried out by using thermodynamic's equation for InGaAsP/GaAs in order to get the relation between the mole fraction of the sloute and solid phase compounds. And the calculation being compared with the dta of Kawanishi et. al, the result has been shown that his phase diagram obtained by the calculation can apply to growing InGaAsP/GaAs by LPE.

• Journal of the Korean Chemical Society
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• v.51 no.6
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• pp.577-584
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• 2007

The purpose of this study is to suggest how to use the phase diagram for water to explain the evaporation and sublimation in the atmospheric condition. In principle, the phase diagram for water represents a one component system so it cannot be applied to the water contact with the air. When the liquid or solid phase of water exists in the air, always water vapor also exists in the air. In this case, we cannot present this state as a single point on the phase diagram because the pressure of the liquid or solid is different from that of the vapor in the air. However, since the saturation vapor pressure of liquid or solid is altered by negligible amount due to the presence of air, the evaporation and sublimation in the atmospheric condition can be explained using the vapor pressure line and sublimation line on the phase diagram.

• Progress in Superconductivity
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• v.14 no.1
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• pp.24-29
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• 2012

$(TMTSF)_2BF_4$ containing non-centrosymmetric anions is well known to exhibit a metal insulator transition around 37 K by ordering of the anions with a $q_2$=(1/2, 1/2, 1/2) wave vector. We established pressure-temperature phase diagram of the $(TMTSF)_2BF_4$ compound and showed that it can belong to the general phase diagram of the $(TMTSF)_2X$ family. Application of hydrostatic pressure decreases the anion ordering transition temperature and the superconducting state is finally stabilized below 3.77 K under 7.7 kbar. Magnetoresistance measurement on the $(TMTSF)_2BF_4$ under 7.8 kbar is performed but neither the field-induced spin-density-wave state nor the rapid oscillation is observed up to 9 T.

• Journal of Power Electronics
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• v.16 no.4
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• pp.1396-1406
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• 2016

A novel controller design is presented for the recently proposed electric springs (ESs). The dynamic modeling is analyzed first, and the initial Bode diagram is derived from the s-domain transfer function in the open loop. The design objective is set according to the characteristics of a minimum phase system. Step-by-step optimizations of the Bode diagram are provided to illustrate the proposed controller, the design of which is different from the classical multistage leading/lagging design. The final controller is the accumulation of the transfer function at each step. With the controller and the recently proposed δ control, the critical load voltage can be regulated to follow the desired waveform precisely while the fluctuations and distortions of the input voltage are passed to the non-critical loads. Frequency responses at any point can be modified in the Bode diagram. The results of the modeling and controller design are validated via simulations. Hardware and software designs are provided. A digital phase locked loop is realized with the platform of a digital signal processor. The effectiveness of the proposed control is also validated by experimental results.

• Progress in Superconductivity and Cryogenics
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• v.14 no.4
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• pp.28-31
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• 2012

We report the solid-liquid phase equilibria on the $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) stability phase diagram in low oxygen pressures ($PO_2$) ranging from 1 to 100 mTorr. On the basis of the GdBCO stability phase diagram experimentally determined in low oxygen pressures, the isothermal sections of three different phase fields on log $PO_2$ vs. 1/T diagram were schematically constructed within the $Gd_2O_3-Ba_2CuO_y-Cu_2O$ ternary system, and the solid-liquid phase equilibria in each phase field were described. The invariant points on the phase boundaries include the following three reactions; a pseudobinary peritectic reaction of $GdBCO{\leftrightarrow}Gd_2O_3$ + liquid ($L_1$), a ternary peritectic reaction of $GdBCO{\leftrightarrow}Gd_2O_3+GdBa_6Cu_3O_y$ + liquid ($L_2$), and a monotectic reaction of $L_1{\leftrightarrow}GdBa_6Cu_3O_y+L_2$. A conspicuous feature of the solid-liquid phase equilibria in low $PO_2$ regime (1 - 100 mTorr) is that the GdBCO phase is decomposed into $Gd_2O_3+L_1$ or $Gd_2O_3+GdBa_6Cu_3O_y+L_2$ rather than $Gd_2BaCuO_5+L$ well-known in high $PO_2$ like air.

• Asia pacific journal of information systems
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• v.7 no.1
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• pp.99-111
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• 1997

This paper presents an application of an artificial neural net to the implementation of decision class analysis (DCA), together with the generation of a decision model influence diagram. The diagram is well-known as a good tool for knowledge representation of complex decision problems. Generating influence diagram model is known to in practice require much time and effort, and the resulting model can be generally applicable to only a specific decision problem. In order to reduce the burden of modeling decision problems, the concept of DCA is introduced. DCA treats a set of decision problems having some degree of similarityz as a single unit. We propose a method utilizing a feedforward neural net with supervised learning rule to develop DCA based on influence diagram, which method consists of two phases: Phase l is to search for relevant chance and value nodes of an individual influence diagram from given decision and specific situations and Phase II elicits arcs among the nodes in the diagram. We also examine the results of neural net simulation with an example of a class of decision problems.

• Journal of Advanced Marine Engineering and Technology
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• v.23 no.6
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• pp.770-777
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• 1999

In this study a phase diagram has been used to investigate the unsteadiness of two-dimensional lid-driven closed flows within a square cavity for twelve Reynolds numbers; $7.5{\times}10^3,\; 8{\times}10^3,\; 8.5{\times}10^3,\; 9{\times}10^3,\; 9.5{\times}10^3,\; 10^4,\;1.5{\times}10^4,\;2{\times}10^4,\; 3{\times}10^4,\; 7.5{\times}10^4$ and $10^5$. The results indicate that the first critical Reynolds number at which the flow unsteadiness of sinusoidal fluctuation appears from the temporal variation of total kinetic energy curves is assumed of sinusoidal fluctuation appears form the temporal variation of total kinetic energy curves is assumed to be in the neigh-bourhood of $Re=8.5{\times}10^3$ The second critical Reynolds number where the periodic amplitude and frequency collapse to random disturbance being existed around $Re=1.5{\times}10^4$ The exponentially decreasing vortices formed at the lower two corners are found commonly at the time-mean flow pattern of $Re=3{\times}10^4$.

• Nuclear Engineering and Technology
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• v.53 no.3
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• pp.833-841
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• 2021

During the postulated severe accident of nuclear reactor, eutectic reaction leads to low-temperature melting of fuel cladding and early failure of core structure. In order to model eutectic melting with the moving particle semi-implicit (MPS) method, the eutectic reaction model is developed to simulate the eutectic reaction phenomenon. The coupling of mass diffusion and phase diagram is applied to calculate the eutectic reaction with the uniform temperature. A heat transfer formula is proposed based on the phase diagram to handle the heat release or absorption during the process of eutectic reaction, and it can combine with mass diffusion and phase diagram to describe the eutectic reaction with temperature variation. The heat transfer formula is verified by the one-dimensional melting simulations and the predicted interface position agrees well with the theoretical solution. In order to verify the eutectic reaction models, the eutectic reaction of uranium and iron in two semi-infinite domains is simulated, and the profile of solid thickness decrease over time follows the parabolic law. The modified MPS method is applied to calculate Transient Reactor Test Facility (TREAT) experiment, the penetration rate in the simulations are agreeable with the experiment results. In addition, a hypothetical case based on the TREAT experiment is also conducted to validate the eutectic reaction with temperature variation, the results present continuity with the simulations of TREAT experiment. Thus the improved method is proved to be capable of simulating the eutectic reaction in the severe accident.

• Journal of Korea Foundry Society
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• v.29 no.6
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• pp.270-276
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• 2009

After casting button-type small ingots of ternary Fe-Mn-S alloys which had three different Mn/S ratios (1, 5 and 70) in a vacuum arc furnace, the effect of the ratio on the sulfide formation was investigated. In case of the Mn/S ratio of 1, if alloy composition was located in an iron-rich corner on a Fe-Mn-S ternary phase diagram, only duplex MnS-FeS sulfide films were observed in the grain boundary. If the alloy composition was located in the miscibility gap area of the phase diagram, primary globular dendritic sulfides and dendritic sulfide slags were generated within the grain and tubular monotectic sulfides were also detected in the grain boundary. When the Mn/S ratio was 5, if the alloy composition was in the iron-rich corner, only bead-like sulfides were generated. On the other hand, if the composition was in the miscibility gap area, globular dendritic sulfides and dendritic sulfide slags were generated in the form of primary sulfide inclusions and rod-like eutectic sulfides were observed in the grain boundary. Especially, if the contents of Mn and S increased more in the miscibility gap area of the phase diagram, primary globular sulfides containing iron intrusions were observed. In case of Mn/S ratio of 70, if the contents of Mn and S was decreased in the Fe corner of the phase diagram, only bead-like sulfides were observed in the grain boundary. Despite the composition was outside the miscibility gap area of the phase diagram, if the contents of Mn and S increased, clusters of fine sulfide particles as well as fine spherical primary monophase sulfides were observed in the grain boundary.