• Title/Summary/Keyword: Phosphorus Removal

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The Removal of Phosphorus by Spent Foundry Sand (폐주물사를 이요한 인제거)

  • 윤철종;진양오;박승조
    • Resources Recycling
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    • v.8 no.3
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    • pp.26-30
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    • 1999
  • The removal of phosphorus was investigated from sewage waste water (SWW) using the used foundry sand (UFS). The optimal pH occurred at pH 2 for adsorption of phosphorus species in batch test. Phosphorus could be recovered with 99.9% from SWW in two hours at pH 2 using 100 g of UFS per liler of SWW. The adsorption of phosphorus species on UFS obeyed Langmuir isotherm, whose equation could be expressed by 1= 0.00059/(1+2.49878). Continuous column test for adsorption showed that breakthrough point appeared In 25 hours on the condition of breakthrough concentration of 8 mg/l

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Change in Influent Concentration of Domestic Wastewater from Separated Sewer and Biological Nitrogen and Phosphorus Removal of a Full Scale Air-vent SBR (분류식 하수관거로의 전환시 유입하수의 성상 변화 및 선회와류식 SBR공법의 처리 특성)

  • Lee, Jang-Hee;Kang, Ho
    • Journal of Korean Society on Water Environment
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    • v.28 no.1
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    • pp.63-70
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    • 2012
  • This study was carried out to investigate change in influent concentration of domestic wastewater flowed from a newly constructed separate sewer system (SSS) and biological nutrients removal efficiency of a full scale Air-vent sequential batch reactor (SBR, $600m^3/d$). The average concentration of $BOD_5$, SS, T-N and T-P from SSS were 246.5 mg/L, 231.6 mg/L, 42.974 mg/L, 5.360 mg/L, respectively which corresponds to 2.2times, 1.2times, 1.8times and 2.1times higher than those from the conventional combined sewer system (CSS). The removal efficiency of $BOD_5$, SS, T-N, and T-P for the Air-vent SBR operated with influent from SSS averaged 99.1%, 99.0%, 91.2%, and 93.5%, respectively. Especially the respective nitrogen and phosphorus removal was 15% greater than that of the SBR operated with influent from CSS. Simultaneous nitrification and denitrification (SND) was observed in an aerobic reactor(II) as a result of DO concentration gradient developed along the depth by the Air-vent system. In order to achieve T-N removal greater than 90%, the C/N ratio should be over 6.0 and the difference between $BOD_5$ loading and nitrogen loading rate be over 100 kg/day (0.130 kg $T-N/m^3{\cdot}d$). Even with high influent T-P concentration of 5.360 mg/L from SSS (compared with 2.465 mg/L from CSS) T-P removal achieved 93.5% which was 15.5% higher than that of the SBR with influent from CSS. This is probably due to high influent $BOD_5$ concentration from SSS that could provide soluble carbon source to release phosphorus at anaerobic condition. In order to achieve T-P removal greater than 90%, the difference between $BOD_5$ loading and phosphorus loading rate should be over 100 kg /day (0.130 kg $T-N/m^3{\cdot}d$).

Phosphorus Removal from Municipal Wastewater Using Ti-based Coagulants (티타늄계열응집제를 이용한 하수 내 인 제거)

  • Shin, So-Yeon;Kim, Jong-Ho;Ahn, Johng-Hwa
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.8
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    • pp.428-434
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    • 2016
  • This study evaluated the efficacy of Ti-based coagulants on phosphorus (P) removal from municipal wastewater and compared them with Al-based coagulants. Jar test experiments were performed at various chemical doses and OH/Ti molar ratio (B value). The higher the intial phosphate ($PO_4-P$) concentration, the lower the [Ti]/[P] to reach a residual concentration below 0.2 mg P/L. Removal efficiencies of total phosphorus increased with an increased coagulant dose but decreased after the efficiencies reached their maximum value regardless of coagulant or B value. On the other hand, $PO_4-P$ removal showed an increasing trend with an increased coagulant dose, reaching the plateau value under large coagulant dose conditions for both Ti- and Al-based coagulants regardless of B value. The chemical dose of Ti-based coagulants was approximately twice higher than that of Al-based coagulants with the same P-removal efficiency. The coagulation efficiency was influenced by different B values.

Optimization of Nitrogen and Phosphorus Removal of Temporal and Spatial Isolation Process by Model Simulation System (시공간 동시분할 공정 시뮬레이션을 통한 질소 및 인 제거 최적화 방안)

  • Ryu, Dongjin;Chang, Duk;Shin, Hyungsoo;Park, Sangmin;Hong, Kiho;Kim, Sooyoung;Kim, Myoungjun
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.206-215
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    • 2007
  • The objective of this study was to establish the optimal system operating strategies for nitrogen and phosphorus removal through model simulation system built for advanced wastewater treatment targeting on simultaneous temporal/special phase isolation BNR process. The simulation system was built with unit process modules using object modules in GPS-X code. The system was well verified by field experiment data. Simulation study was carried out to investigate performance response to design and operation parameters, i.e. hydraulic retention time (HRT), solids retention time (SRT), and cycle time. The process operated at HRTs of 10~15 hours, longer SRTs, and cycle time of 2 hours showed optimal removal of nitrogen. The HRTs of 10~15 hours, SRTs of 20~25 days, and longer cycle time was optimal for phosphorus removal. Both simulation and field studies showed that optimal operating strategies satisfying both the best nitrogen and phosphorus removals include HRTs ranged 10~15 hours, SRTs ranged 20~25 days, and cycle times of 4~8 hours. The simulation system with modularization of generalized components in BNR processes was, therefore, believed to be a powerful tool for establishing optimal strategies of advanced wastewater treatment.

A Study on Wastewater Treatment by Electrochemical Treatment with Various Electrode Interval (전극 간격에 따른 전기화학적 처리를 통한 폐수처리에 관한 연구)

  • Song, Ju Yeong
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.2
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    • pp.417-423
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    • 2019
  • A new wastewater treatment system was developed to remove nitrate nitrogen and phosphorus in synthetic wastewater through electrochemical treatment. Higher removal efficiencies of nitrate nitrogen were obtained as the current density increased. Higher nitrate removal efficiencies were obtained when the switching interval was 1 min. The total phosphorus removal rate according to the current density was found to be over 90% without being greatly affected by the change in current density and interval, and the total removal rate increased with increasing switching time (1 min interval). On the other hand, COD was not treated by electrochemical treatment, but rather increased as the electrode eluted. Also, the consumption rate of the electrode was smaller as the switching interval was shorter. Finally, removal efficiencies of 98.1% of nitrate and 90% of phosphorus were obtained through electrochemical treatment (current density $50mA/cm^2$, switching interval 1 min, flow rate 540 mL/min).

Nitrogen and Phosphorus Removal from Plating Wastewater Using the Soil Reactor (토양 반응조를 이용한 도금폐수 중의 질소 및 인 제거)

  • Cheong, Kyung-Hoon;Choi, Hyung-Il;Shin, Dae-Yun;Im, Byung-Gab;Jeon, Gee-Seok
    • Journal of Environmental Science International
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    • v.18 no.2
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    • pp.205-213
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    • 2009
  • A laboratory experiment was conducted to investigate nitrogen removal from plating wastewater by a soil reactor. A combination of soil, waste oyster shell and activated sludge were used as a loading media in a soil reactor. The addition of 20% waste oyster shell and activated sludge to the soil accelerated nitrification (88.6% ${NH_4}^{+}-N$ removal efficiency) and denitrification (84.3% ${NO_3}^{-}-N$ removal) in the soil reactor, respectively. In continuous removal, the influent ${NH_4}^{+}-N$ was mostly converted to nitrate nitrogen in the nitrification soil reactor and only a small amount of ${NH_4}^{+}-N$ was found in the effluent. When methanol was added as a carbon source to the denitrification soil reactor, the average removal efficiency of ${NO_3}^{-}-N$ significantly increased. The ${NO_3}^{-}-N$ removal by methanol addition in the denitrification soil reactor was mainly due to denitrification. The phosphorus was removed by the waste oyster shell media in the nitrification soil reactor. Moreover, the phosphorus removal in the denitrification soil reactor was achieved by synthesis of bacteria and the denitrification under anaerobic conditions. The approximate number of nitrifiers and denitrifiers was $3.3{\times}10^5\;MPN/g$ soil at a depth of $1{\sim}10\;cm$ and $3.3{\times}10^6\;MPN/g$ soil at a depth of $10{\sim}20\;cm$, respectively, in the soil reactor mixed with a waste oyster shell media and activated sludge.

Dissolved organic matter characteristics and bacteriological changes during phosphorus removal using ladle furnace slag

  • Noh, Jin H.;Lee, Sang-Hyup;Choi, Jae-Woo;Maeng, Sung Kyu
    • Membrane and Water Treatment
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    • v.9 no.3
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    • pp.181-188
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    • 2018
  • A sidestream contains the filtrate or concentrate from the belt filter press, filter backwash and supernatant from sludge digesters. The sidestream flow, which heads back into the sewage treatment train, is about 1-3% less than the influent flow. However, the sidestream can increase the nutrient load since it contains high concentrations of phosphorus and nitrogen. In this study, the removal of PO4-P with organic matter characteristics and bacteriological changes during the sidestream treatment via ladle furnace (LF) slag was investigated. The sidestream used in this study consisted of 11-14% PO4-P and 3.2-3.6% soluble chemical oxygen demand in influent loading rates. LF slag, which had a relatively high $Ca^{2+}$ release compared to other slags, was used to remove $PO_4-P$ from the sidestream. The phosphate removal rates increased as the slag particle size decreased 19.1% (2.0-4.0 mm, 25.2% (1.0-2.0 mm) and 79.9% (0.5-1.0 mm). The removal rates of dissolved organic carbon, soluble chemical oxygen demand, color and aromatic organic matter ($UV_{254}$) were 17.6, 41.7, 90.2 and 77.3%, respectively. Fluorescence excitation-emission matrices and liquid chromatography-organic carbon detection demonstrated that the sidestream treatment via LF slag was effective in the removal of biopolymers. However, the removal of dissolved organic matter was not significant during the treatment. The intact bacterial biomass decreased from $1.64{\times}10^8cells/mL$ to $1.05{\times}10^8cells/mL$. The use of LF slag was effective for the removal of phosphate and the removal efficiency of phosphate was greater than 80% for up to 100 bed volumes.

Development of Constructed Wetland using Sand and Oyster shell for Sewage Treatment (모래와 굴패각을 이용한 인공습지 오수처리장치 개발)

  • Park, Hyun-Geoun;Lee, Chun-Sik;Lee, Hong-Jae;Seo, Dong-Cheol;Heo, Jong-Soo
    • Journal of Korean Society on Water Environment
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    • v.20 no.5
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    • pp.437-446
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    • 2004
  • To develop sewage treatment apparatus by natural purification method, the sewage treatment plant that consisted of aerobic and anaerobic plot was constructed. And then, the effects of treatment conditions on the removal of pollutants in the relation to sewage loading, sewage injection method and season according to the pebble kind. Removal rate of BOD and COD according to the sewage loading in effluent were over 95 and 77%, respectively. Removal rate of nitrogen in treated water by aerobic plot and effluent using sand were about 22~40 and 49~75%, respectively. Those of effluent using sand 75%+ oyster shell 25% and sand 50%+ oyster shell 50% as filter media in comparison with using sand were about 7~25 and 16~23%, respectively. Removal rate of phosphorus in treated water by aerobic plot and effluent using sand as filter media were about 30~36 and 52~56%, respectively. Those of effluent using sand 75%+ oyster shell 25% and sand 50%+ oyster shell 50% in comparison with using sand as filter media were about 11~40 and 12~45%, respectively. Removal efficiency of BOD and COD according to the intermittent injection method of sewage were slightly decreased, but those of nitrogen and phosphorus were little varied in comparison with continuous injection method. Removal efficiency of BOD and COD in winter in comparison with the others were little varied, but those of nitrogen and phosphorus slightly decreased.

Nutrient Removal in an Advanced Treatment Process using BIO-CLOD (BIO-CLOD를 이용한 고도처리공정에서의 영양염류 제거)

  • Park, Wan-Cheol;Lee, Mi-Ae;Sung, Il-Wha
    • Journal of Environmental Health Sciences
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    • v.40 no.4
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    • pp.322-329
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    • 2014
  • Objectives: The purpose of this study was to investigate the effect of BIO-CLOD on advanced wastewater treatment for enhanced removal efficiency and meeting the stringent discharge water requirements of wastewater treatment plants. Methods: Two experimental apparatuses consisting of anaerobic, anoxic and aeration tanks were operated. One included a BIO-CLOD cultivation tank. Organic and nutrient parameters and removal efficiency were analyzed by pH, BOD, CODcr, SS, T-N and T-P. Results: The average removal efficiencies of BOD, COD and SS from the apparatus with BIO-CLOD tank installation were 95.5%, 88.6% and 92.9%, respectively, and these were higher than the results from the apparatus without BIO-CLOD. The average TP removal efficiency with BIO-CLOD tank marked 56.0%, higher than the 47.3% from the apparatus without one. BIO-CLOD showed a higher performance for TN removal at 49.6%, compared to the result without BIO-CLOD of 34.3% Conclusion: By reaction with BIO-CLOD, ammonia removal was effective in the aeration tank, as was phosphorus release in the anaerobic tank. Phosphorus luxury uptake and nitrification in aeration tank proceeded smoothly. The application of BIO-CLOD can improve the decrease of odor and settleability of activated sludge in a wastewater treatment plant, as well as increase the removal efficiency of organic and nutrient materials in water.

Phosphorus Removal by DPAOs (Denitrifying Phosphorus Accumulating Organisms) in Aerobic Condition (호기 조건에서 DPAOs (Denitrifying Phosphorus Accumulation Organisms)에 의한 인 제거)

  • Jeong, No-Sung;Park, Young-Seek;Kim, Dong-Seog
    • KSBB Journal
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    • v.25 no.1
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    • pp.62-66
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    • 2010
  • This study was carried out to get phosphorus uptake rate in aerobic condition with nitrate and nitrite. Nitrate and nitrite inhibited phosphorus accumulating organisms' (PAOs') luxury uptake in aerobic condition. Nitrite awfully decreased the phosphorus uptake rate in aerobic condition. At the influent of 10 mg ${NO_3}^-$-NL, the phosphorus uptake was decreased to 52% comparing that at no influent of nitrate. And at the influent of 10 mg ${NO_2}^-$-NL, the phosphorus uptake was decreased to 28% comparing that at no influent of nitrite. At the influent of 20 mg ${NO_3}^-$-NL, nitrite and nitrate were co-existed and the phosphorus uptake rate was decreased to 16% comparing that at no influent of nitrite and nitrate. Also, the denitrification was occurred by denitrifying glycogen accumulating organisms (DGAOs)/denitrifying phosphorus accumulating organisms (OPAOs) in spite of aerobic condition, and the phosphorus uptake rate was increased by the decrease of influent nitrate concentration at the aerobic condition. The inflection point in the phosphorus uptake rate was shown at the nitrite concentration of 1.5~2 mg/L.