• Title/Summary/Keyword: Polyamide 6 fiber

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Flame Retardant Synergistic Performance between Cyclic Diphosphonate Ester and Melamine in Polyamide 6 (Polymide 6에서 Cyclic Diphosphonate Ester와 Melamine의 난연 효과)

  • Wang, Xueli;Jiang, Jianming;Yang, Shenglin;Jin, Junhong;Li, Guang
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.125-130
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    • 2008
  • A commercial cyclic diphosphonate ester (TPMP) and melamine (MA) was combined and added to polyamide 6 (PA6) to prepare the fire retardant PA6. An increase of the oxygen index to 28.6 as well as an improvement of the UL-94 classification to V-0 rating was observed. Cone measurements explained the rate of heat release (RHR) decreased and TGA showed the early decomposition and high solid residue due to co-addition of TPMP and MA, suggesting the occurrence of synergistic effect of TPMP and MA on fire resistance of PA6. The morphology of the char developed during combust ion showed the appearance of thick, intumescent cells on the surface of retardant PA6, which protects the underlying material from the action of the heat flux or flame and limits the diffusion of combustible volatile products towards the flame and oxygen.

EVALUATION OF SEISMIC SHEAR CAPACITY OF PRESTRESSED CONCRETE CONTAINMENT VESSELS WITH FIBER REINFORCEMENT

  • CHOUN, YOUNG-SUN;PARK, JUNHEE
    • Nuclear Engineering and Technology
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    • v.47 no.6
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    • pp.756-765
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    • 2015
  • Background: Fibers have been used in cement mixture to improve its toughness, ductility, and tensile strength, and to enhance the cracking and deformation characteristics of concrete structural members. The addition of fibers into conventional reinforced concrete can enhance the structural and functional performances of safety-related concrete structures in nuclear power plants. Methods: The effects of steel and polyamide fibers on the shear resisting capacity of a prestressed concrete containment vessel (PCCV) were investigated in this study. For a comparative evaluation between the shear performances of structural walls constructed with conventional concrete, steel fiber reinforced concrete, and polyamide fiber reinforced concrete, cyclic tests for wall specimens were conducted and hysteretic models were derived. Results: The shear resisting capacity of a PCCV constructed with fiber reinforced concrete can be improved considerably. When steel fiber reinforced concrete contains hooked steel fibers in a volume fraction of 1.0%, the maximum lateral displacement of a PCCV can be improved by > 50%, in comparison with that of a conventional PCCV. When polyamide fiber reinforced concrete contains polyamide fibers in a volume fraction of 1.5%, the maximum lateral displacement of a PCCV can be enhanced by ~40%. In particular, the energy dissipation capacity in a fiber reinforced PCCV can be enhanced by > 200%. Conclusion: The addition of fibers into conventional concrete increases the ductility and energy dissipation of wall structures significantly. Fibers can be effectively used to improve the structural performance of a PCCV subjected to strong ground motions. Steel fibers are more effective in enhancing the shear performance of a PCCV than polyamide fibers.

The effect of blending condition on the ester-amide exchange reactions and their rheological properties of Poly(trimethylene terephthalate)/Polyamide 6 or 6,6 Blends (Poly(trimethylene terephthalate)/Polyamide 6 및 6,6의 용융블렌드시 블렌드조건에 따른 에스테르-아미드 교환반응 정도와 유변특성)

  • 이현주;김학성;임경율;김병철
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.183-186
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    • 2001
  • 폴리에스테르/폴리아미드의 블렌드는 두 고분자의 단점을 상호 보완할 수 있을 뿐만 아니라 조성비에 의해 원하는 물성을 부여할 수 있는 장점이 있다. 이들 블렌드 중에서 폴리(에틸렌 테레프탈레이트)(PET)/폴리아미드(PA)의 블렌드의 경우 일반적인 폴리에스테르계의 블렌드에서 일어나는 에스테르 교환반응과 마찬가지로 에스테르-아미드 교환반응이 일어나며 이를 이용하여 두 고분자간의 상용성을 향상시키려는 연구가 보고된 바 있다. (중략)

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A Study on the Three Phase Glass Fiber/Nylon 6/Polyproylene Composites (나일론 6과 폴리프로필렌 수지에 유리섬유가 보강된삼상 복합재료에 관한 연구)

  • 서문호
    • The Korean Journal of Rheology
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    • v.10 no.2
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    • pp.57-64
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    • 1998
  • A pultrusion resin impregnation (PRI) die, which has been developed recently in our laboratory, was used to pre-pare various composite system. The continuous fiber reinforced composites of glass fiber/polypropylene(GFPP) and glass fiber/polyamide 6 (GFPA) were first manufactured by means of the PRI die and then cut into chopped pellets of predet-ermined length. These pellets and either virgin or modified thermoplastic resin were melt-mixed by a twin screw extruder to prepare GF/PA/PP and GF/PA/PPMA system. The mechanical properties of these blends were investigated and discussed in terms of their morphological observations. These preliminary results revealed that this new impregnation die could be suc-cessfully applied to produce prepregs suitavle for the final shaping process.

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A study on the physical properties of polyamide 6/ silica nanocomposites (Polyamide 6와 실리카 나노 복합체의 물리적 특성에 대한 연구)

  • 지병화;채동욱;임경률;김병철
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.313-316
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    • 2002
  • 고분자 물질과 유리섬유, 운모, 탄산 칼슘 그리고 점토 광물과 같은 다양한 무기물과의 복합체는 기계적 성질, 열적 성질과 같은 물리적 특성의 향상을 가져올 뿐만 아니라 이와 같은 특성들을 적은 비용으로 향상시킬 수 있는 장점을 가지고 있기 때문에 다양한 방면에서 널리 사용된다[1]. 이에 대해서, 최근 많은 발전을 이루고 있는 나노기술을 고분자와 무기 나노 입자의 복합체에 적용시키는 연구가 활발히 진행되고 있다. (중략)

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In-situ Synthesis of Polyamide-6/POSS Nanocomposites

  • Ramasundaram Subramaniya Pillai;Kim Kap-Jin
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.303-303
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    • 2006
  • In-situ ring opening polymerization of ${\varepsilon}-caprolactum$ was carried out in the presence of aminoethylaminopropylisobutyl POSS and stoichiometric amount of adipic acid. The covalent bond formation of POSS on the polyamide was confirmed by the appearance of FT-IR peak at $1123\;cm^{-1}$ that corresponds to the Si-O stretching of POSS structures. Gradual decrease in melting endotherm peak was observed on loading POSS in PA6/POSS nanocomposites. Sharp increase in intrinsic viscosity was observed upto 2.5 wt % loading POSS in the polyamide 6 nanocomposites. These nanocomposites were further characterized using nuclear magnetic resonance, melt viscosity and X-ray diffraction.

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Workability and Strength Properties of Hybrid Fiber Reinforced Concrete Using Amorphous Steel Fiber and Organic Fiber (비정질 강섬유와 유기섬유를 이용한 하이브리드 섬유보강 콘크리트의 작업성 및 강도 특성)

  • Kwon, Soon-Oh;Bae, Su-Ho;Lee, Hyun-Jin;Kim, Jin-Oo;Lee, Jun-Cheol
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.6 no.4
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    • pp.58-63
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    • 2015
  • The purpose of this experimental research is to evaluate the workability and strength properties of hybrid fiber reinforced concrete containing amorphous steel fiber and organic fiber. For this purpose, the hybrid fiber reinforced concrete containing amorphous steel fiber(ASF) with polyamide(PA) and polyvinyl alcohol(PVA) fiber, respectively were made according to their total volume fraction of 0.5% for water-binder ratio of 33%, and then the characteristics such as the workability, compressive strength, and flexural strength of those were investigated. It was observed from the test results that the workability and compressive strength at 7 and 28 days were decreased and the flexural strength at 7 and 28 days was increased with increasing ASF and decreasing organic fiber.