• Proceedings of the Korean Society of Precision Engineering Conference
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• 2008.06a
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• pp.61-62
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• 2008

• Polymer(Korea)
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• v.24 no.3
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• pp.333-341
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• 2000

Blends consisting of linear shape polylactic acid and star shape polylactic acid (L-PLLA/S-PLLA) have been prepared by melt and solution blending. The effect of blending method on the thermal properties and crystallization behavior of L-PLLA/S-PLLA blends has been investigated. The molecular weight decrease was revealed both in melt and solution blending. S-PLLA was found to be more stable than L-PLLA in the reduction of molecular weight during the course of blending due to its star shape structure. As a result, broad molecular weight distribution was obtained in solution blending. It was found that melting temperature and glass transition temperature decrease with increasing S-PLLA content. Blending method had large influence on the glass transition temperature of PLLA blends, while less effect on melting temperature. From DSC results, it can be noticed that solution blending is more effective blending method to obtain higher crystallinity than melt blending for S-PLLA and blend with higher S-PLLA content.

• Journal of the Korean Society of Clothing and Textiles
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• v.30 no.4 s.152
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• pp.607-614
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• 2006

This study was carried out to suggest the optimal spinning process condition which provides a proper range of tenacity and biodegradability as textile fibers. The effects of the melt spinning speed and heat treatment on the mechanical property and biodegradability of polylactic acid fiber were investigated. Polylactic acid(PLA) was spun in a high spinning speed of $2000{\sim}4000m/min$. Each specimen was heat-treated at $100^{\circ}C$ during 30min. Mechanical properties such as breaking stress and the degree of crystallinity were evaluated using WAXS. Biodegradability was estimated from the decrease of breaking stress, weight loss, and the degree of crystallinity after soil burial. Experimental results revealed that heat treated specimens showed higher breaking stress than untreated specimens, but the increase was not so high as was expected from the remarkable change of crystallinity by heat treatment. It was concluded that breaking stress was more influenced by spinning speed than heat treatment. In the soil burial test, however biodegradability calculated from weight loss was more influenced by heat treatment than spinning speed.

• Polymer(Korea)
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• v.39 no.2
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• pp.261-267
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• 2015

The inclusion complexes (ICs) between polylactic acid (PLA) and ${\beta}$-cyclodextrin (CD) were prepared by co-precipitation method in this work. The orthogonal experiments were designed to investigate the influence of different factors on the formation of inclusion complexes. The results suggested that the optimum scheme of inclusion compounds could be obtained when the feeding ratio of CD to PLA (wt%) was 20:1, stirring speed was 6 kr/min and the stirring time was 30 min. The structures and properties of the inclusion complexes were characterized by $^1H$ NMR, FTIR, DSC, FT-Raman, XRD and TGA. The DSC results demonstrated that the crystallization behavior of the inclusion complexes nearly disappeared. It was found that ${\beta}$-CD-PLA inclusion complex had a better thermal stability compared with the neat PLA. The model of the inclusion complexes was proposed on the basis of XRD, $^1H$ NMR and DSC results.

• Korean Chemical Engineering Research
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• v.47 no.1
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• pp.59-64
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• 2009

This study investigated the surface characteristics of polylactic acid (PLA) film after one atmospheric pressure plasma treatment. We used de-ionized water and diiodomethane as polar and non-polar solvents, respectively, for measuring contact angles, and subsequently calculated the surface free energy of PLA film. The contact angle and free energy of PLA surface were optimized at the treatment time of 30 sec, RF-power of 70 W, Ar gas flow rate of 6 lpm and air exposure time of 5 min. We analyzed the change of chemical functional groups on the surface of PLA film through XPS and were able to observe the change of polar functional groups such as -C=O, -CO, -COO on the surface of PLA film after one atmospheric pressure plasma treatment.

• Textile Coloration and Finishing
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• v.29 no.4
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• pp.181-194
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• 2017

The biodegradability of polylactic acid(PLA) fabrics was evaluated by two methods: enzyme and soil degradation. Three different enzymes were selected to evaluate. Degradation times were measured at optimal enzyme treatment conditions. Biodegradation by enzymatic hydrolysis was compared with soil degradation. As a result, biodegradation created cracks on the fiber surface, which led to fiber thickening and shortening. In addition, new peak was observed at $18.5^{\circ}$ by degradation. Moreover, cracks indicating biofragmentation were confirmed by enzyme and soil degradation. By enzyme and soil degradation, the weight loss of PLA fabrics was occurred, there through, the tensile strength decreased about 25% by enzyme hydrolysis when 21 days after, and 21.67% by soil degradation when 60 days after. Furthermore, the biodegradability of PLA fabrics by enzymatic and soil degradation was investigated and enzymatic degradation was found to be superior to soil degradation of PLA fabrics. Among the three enzymes evaluated for enzymatic degradation, alcalase was the most efficient enzymes. This study established the mechanism of biodegradation of PLA nonwovens, which might prove useful in the textile industry.

• Journal of the Korean Society of Clothing and Textiles
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• v.35 no.6
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• pp.670-677
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• 2011

This study is to optimize the enzymatic processing conditions of Polylactic Acid (PLA) fiber using lipase from Porcine pancreas as an environmental technology. Hydrolytic activity dependent on pH, temperature, enzyme concentration, and treatment time, and structural change of PLA fiber were evaluated. The PLA fiber hydrolysis by lipase was maximized at 50% (o.w.f) lipase concentration $50^{\circ}C$ for 120 minutes under pH 8.5. There was a change of the protein absorbance in the treatment solution before and after the lipase treatment. In addition, there was no substantial change in the molecular and crystalline structures of PLA by lipase treatment as confirmed by DSC, XRD, and FT-IR.

• Journal of the Korean Society of Industry Convergence
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• v.16 no.2
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• pp.47-52
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• 2013

Aim of this study is to investigate the dimensional and shrinkage characteristics of the weft knitted fabrics with Polylactic acid(PLA) knitted yarn. This PLA knitted yarn was made of the biodegradability fiber. The structure of weft knitted fabrics that was utilized for this study is the plain stitch, which is the most basic structure among all weft knitted fabrics. As the stitch length is shorter, the stitch density, courses density, and wales density are more increasing. The stitch density increased as pre-treatment process and dyeing process progressed. On the contrary, the heat setting process made it decreasing. The MR(Machine Relaxation) and DR(Dry Relaxation) standard area shrinkage were increasing as wet process progressed and as the stitch lengths are long.

• Proceedings of the PSK Conference
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• 2002.10a
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• pp.425.1-425.1
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• 2002

Nanoparticles of polylactic acid (PLA) and polyethylenimine (PEI) as an effective gene delivery agent were prepared and characterized. As a model plamid DNA. PME185/$\beta$-gal. a mammalian expression vector. and fluorescence enhancing protein (pEGHP) were used. The effects of PEI type on the physical properties of nanoparticles and transfection efficiency were examined. (omitted)

• Food Science of Animal Resources
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• v.36 no.3
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• pp.421-426
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• 2016

Polylactic acid (PLA) is a biodegradable and renewable polymer, which represents a valuable alternative to plastic packaging films, often associated with environmental problems. In this study, we tested the suitability of PLA as a biodegradable packaging film and assessed the antimicrobial activity of lemongrass oil (LO), incorporated into the PLA film in different concentrations. To obtain the optimal physical properties for PLA films, tensile strength, elongation at break, and water vapor permeability were measured under different preparation conditions. In addition, the antimicrobial activity of the LO contained in the PLA film against Listeria monocytogenes was investigated by disc diffusion and viable cell count. Among all concentrations tested, 2% LO was the most suitable in terms of antimicrobial activity and physical properties of the PLA film. Based on these results, we used the PLA film containing 2% LO to pack pork sausages; after 12 d of storage at 4℃, the population of inoculated L. monocytogenes in the sausage samples wrapped with the PLA film containing 2% LO was reduced by 1.47 Log CFU/g compared with the control samples. Our data indicate that PLA films containing 2% LO represent a valuable means for antimicrobial sausage packaging.