• Title/Summary/Keyword: Post-reforming

Search Result 19, Processing Time 0.036 seconds

Activity test of post-reforming catalyst for removing the ethylene in diesel ATR reformate (디젤 자열개질 가스 내 포함된 $C_2H_4$ 제거를 위한 후개질기 촉매 활성 실험)

  • Yoon, Sang-Ho;Bae, Joong-Myeon;Lee, Sang-Ho
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2009.11a
    • /
    • pp.218-221
    • /
    • 2009
  • Solid oxide fuel cells (SOFCs), as high-temperature fuel cells, have various advantages. In some merits of SOFCs, high temperature operation can lead to the capability for internal reforming, providing fuel flexibility. SOFCs can directly use CH4 and CO as fuels with sufficient steam feeds. However, hydrocarbons heavier than CH4, such as ethylene, ethane, and propane, induce carbon deposition on the Ni-based anodes of SOFCs. In the case of the ethylene steam reforming reaction on a Ni-based catalyst, the rate of carbon deposition is faster than among other hydrocarbons, even aromatics. In the reformates of heavy hydrocarbons (diesel, gasoline, kerosene and JP-8), the concentration of ethylene is usually higher than other low hydrocarbons such as methane, propane and butane. It is importatnt that ethylene in the reformate is removed for stlable operation of SOFCs. A new methodology, termed post-reforming was introduced for removing low hydrocarbons from the reformate gas stream. In this work, activity tests of some post-reforming catalysts, such as CGO-Ru, CGO-Ni, and CGO-Pt, are investigated. CGO-Pt catalyst is not good for removing ethylene due to low conversion of ethylene and low selectivity of ethylene dehydrogenation. The other hand, CGO-Ru and CGO-Ni catalysts show good ethylene conversion, and CGO-Ni catalyst shows the best reaction selectivity of ethylene dehydrogenation.

  • PDF

Methodology for removing unreacted low-hydrocarbons in diesel reformate for stable operation of solid oxide fuel cells (안정적인 SOFC 운전을 위한 디젤 개질기 내 미반응 저탄화수소 제거법)

  • Yoon, Sang-Ho;Bae, Joong-Myeon;Lee, Sang-Ho
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2009.06a
    • /
    • pp.773-776
    • /
    • 2009
  • In this paper, new concept of the diesel fuel processing is introduced for the stable operation of solid oxide fuel cells (SOFCs). Heavier hydrocarbons than $CH_4$, such as ethylene, ethane, propane, and etc., induce the carbon deposition on anode of SOFCs. In the reformate of heavy hydrocarbons (diesel, gasoline, kerosene, and JP-8), concentration of ethylene is usually higher than low hydrocarbons such as ethane, propane, and butane. So, removal of low hydrocarbons (over C1-hydrocarbons), especially ethylene, at the reformate gases is important for stable operation of SOFCs. New methodology as named "post-reformer" is introduced for removing the low hydrocarbons at the reformate gas stream. Catalyst of the NECS-PR4 is selected for post-reforming catalyst because the catalyst of NECS-PR4 shows the high selectivity for removing low hydrocarbons and achieving the high reforming efficiency. The diesel reformer and post-reformer are continuously operated for about 200 hours as integrated mode. The reforming performance is not degraded and low hydrocarbons in the diesel reformate are completely removed.

  • PDF

The developments of heavy hydrocarbon reformer for SOFC

  • Bae, Jung-Myeon
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2012.05a
    • /
    • pp.58.2-58.2
    • /
    • 2012
  • Heavy hydrocarbon reforming is a core technology for "Dirty energy smart". Heavy hydrocarbons are components of fossil fuels, biomass, coke oven gas and etc. Heavy hydrocarbon reforming converts the fuels into $H_2$-rich syngas. And then $H_2$-rich syngas is used for the production of electricity, synthetic fuels and petrochemicals. Energy can be used efficiently and obtained from various sources by using $H_2$-rich syngas from heavy hydrocarbon reforming. Especially, the key point of "Dirty energy smart" is using "dirty fuel" which is wasted in an inefficient way. New energy conversion laboratory of KAIST has been researched diesel reforming for solid oxide fuel cell (SOFC) as a part of "Dirty energy smart". Diesel is heavy hydrocarbon fuels which has higher carbon number than natural gas, kerosene and gasoline. Diesel reforming has difficulties due to the evaporation of fuels and coke formation. Nevertheless, diesel reforming technology is directly applied to "Dirty fuel" because diesel has the similar chemical properties with "Dirty fuel". On the other hand, SOFC has advantages on high efficiency and wasted heat recovery. Nippon oil Co. of Japan recently commercializes 700We class SOFC system using city gas. Considering the market situation, the development of diesel reformer has a great ripple effect. SOFC system can be applied to auxiliary power unit and distributed power generation. In addition, "Dirty energy smart" can be realized by applying diesel reforming technology to "Dirty fuel". As well as material developments, multidirectional approaches are required to reform heavy hydrocarbon fuels and use $H_2$-rich gas in SOFC. Gd doped ceria (CGO, $Ce_{1-x}Gd_xO_{2-y}$) has been researched for not only electrolyte materials but also catalysts supports. In addition, catalysts infiltrated electrode over porous $La_{0.8}Sr_{0.2}Ga_{0.8}Mg_{0.2}O_3-{\delta}$ and catalyst deposition at three phase boundary are being investigated to improve the performance of SOFC. On the other hand, nozzle for diesel atomization and post-reforming for light-hydrocarbons removal are examples of solving material problems in multidirectional approaches. Likewise, multidirectional approaches are necessary to realize "Dirty energy smart" like reforming "Dirty fuel" for SOFC.

  • PDF

Degradation Comparison of Hydrogen and Internally Reformed Methane-Fueled Solid Oxide Fuel Cells

  • Kim, Young Jin;Lee, Hyun Mi;Lim, Hyung-Tae
    • Journal of the Korean Ceramic Society
    • /
    • v.53 no.5
    • /
    • pp.483-488
    • /
    • 2016
  • Anode supported solid oxide fuel cells (SOFCs), consisting of Ni+YSZ anode, YSZ electrolyte, and LSM+YSZ cathode, were fabricated and constant current tested with direct internal reforming of methane (steam to carbon ratio ~ 2) as well as hydrogen fuel at $800^{\circ}C$. The cell, operated under direct internal reforming conditions, showed relatively rapid degradation (~ 1.6 % voltage drop) for 95 h; the cells with hydrogen fuel operated stably for 170 h. Power density and impedance spectra were also measured before and after the tests, and post-test analyses were conducted on the anode parts using SEM / EDS. The results indicate that the performance degradation of the cell operated with internal reforming can be attributed to carbon depositions on the anode, which increase the resistance against anode gas transport and deactivate the Ni catalyst. Thus, the present study shows that direct internal reforming SOFCs cannot be stably operated even under the condition of S/C ratio of ~ 2, probably due to non-uniform mixture (methane and steam) gas flow.

R&D Trends and Unit Processes of Hydrogen Station (수소 스테이션의 연구개발 동향 및 단위공정 기술)

  • Moon, Dong Ju;Lee, Byoung Gwon
    • Korean Chemical Engineering Research
    • /
    • v.43 no.3
    • /
    • pp.331-343
    • /
    • 2005
  • Development of hydrogen station system is an important technology to commercialize fuel cells and fuel cell powered vehicles. Generally, hydrogen station consists of hydrogen production process including desulfurizer, reformer, water gas shift (WGS) reactor and pressure swing adsorption (PSA) apparatus, and post-treatment process including compressor, storage and distributer. In this review, we investigate the R&D trends and prospects of hydrogen station in domestic and foreign countries for opening the hydrogen economy society. Indeed, the reforming of fossil fuels for hydrogen production will be essential technology until the ultimate process that may be water hydrolysis using renewable energy source such as solar energy, wind force etc, will be commercialized in the future. Hence, we also review the research trends on unit technologies such as the desulfurization, reforming reaction of fossil fuels, water gas shift reaction and hydrogen separation for hydrogen station applications.

A Study on the Organizational Improvement of Local Educational Officials in Technical Post (교육청(敎育廳) 기술직(技術職) 공무원(公務員) 조직(組織) 개선(改善)에 대한 조사(調査) 연구(硏究) - 3개 교육청(敎育廳) 기술직(技術職) 공무원(公務員) 설문조사(設問調査)를 토대로 -)

  • Lee, Hwa-Ryong
    • Journal of the Korean Institute of Educational Facilities
    • /
    • v.11 no.3
    • /
    • pp.5-15
    • /
    • 2004
  • This study aims to review the reality of local educational officials in technical post, to investigate their needs and awareness for newly changing social environment, and to inspire them with alternatives and strategies for reforming and restructuring their organization. It examines and analyses the strong points and weak points of the organization, the methods for improving the operation systems and organizational structures and the problems in the personnel management in officialdom, especially unfairness between the executive and the technical officials through a questionnaire and interview. This study ascertains that most of the technical officials consider expert knowledge and experience as their strong point and think the negative image against its group as their weak point for the organizational development. Specially this article indicates that they are not satisfied with the job conditions and want to shift to the official in executive post.

Analysis of Post Cleaning Solution After Wet Cleaning of Shadow Mask Used in OLED Process (OLED공정에서 사용되는 섀도마스크의 습식 세정 후 세정표면 및 세정용액 분석에 관한 연구)

  • Cui, Yinhua;Pyo, Sung Gyu
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.23 no.4
    • /
    • pp.7-10
    • /
    • 2016
  • The post cleaning method for clean the shadow mask using in OLED (organic light emitting diode) emitter layer is always reforming. The cleaning solution and analysis method of shadow mask is still lack and not optimized. We use the simple and useful analytical method to determine the quantity and quality of organic and inorganic residue on surface of shadow mask. Finally analyze the cleaning solution using Raman spectroscopy efficiently.

The Task of World Literature and the Problem of Universality (세계문학의 과제와 보편의 문제)

  • Park, Sang jin
    • Cross-Cultural Studies
    • /
    • v.23
    • /
    • pp.81-100
    • /
    • 2011
  • The term of world literature is now becoming an issue and lens through which we need to rethink the value of literature on a more universal dimension so as to imagine newly the location of the local or regional literature that has been alienated from the field of world literature. This kind of recognition leads us to consider the term world literature in relation to globalization and universality and to locate it on a problematical territory rather than to understand it in the traditional and Western way. Therefore the concept of world literature is now given to us as a task to resolve from our particular, or more precisely, peripheral context. The peripheral context could best operate as a possibility of reforming the West-centered order of world literature particularly in the way in which world literature obtains a more universal value. When we discuss world literature we need to consider the way of practice to re-highlight the possibility of periphery and pre-modernity without neglecting the 'light' of modernity and center. In this respect, the discourse of 'East Asia' may be useful for a transnational approach to world literature which focuses on the criticism of all kinds of centrism by foregrounding the concepts of othering and de-homogenization. For this I emphasize the attitude and methodology of 'post' which includes the power of othering and de-homogenization. The 'posty' theories such as post-colonialism, post-structuralism, post-nationalism and post-humanism allow us to indicate properly and acutely our aim by means of freer play of thought and at the same time more just definition and practice of our thought; that is, only by embracing both indication and play can we maintain the universal value of world literature. Here we can say that the global and local enterprise of ethics is the fundamental basis of world literature.

Experimental study on the behavior of reinforced concrete beam boosted by a post-tensioned concrete layer

  • Mirzaee, Alireza;Torabi, Ashkan;Totonchi, Arash
    • Computers and Concrete
    • /
    • v.28 no.6
    • /
    • pp.549-557
    • /
    • 2021
  • Nowadays, strengthening of buildings is an inclusive and effective field in civil engineering that is not only applicable to the buildings but also it can be developed for the bridges. Rehabilitation and strengthening of structures are highly recommended for the existing structures due to the alter in codes and provisions as well as buildings' use change. Extensive surveys have been conducted in this field in the world that propose wide variety of methods for strengthening of structures. In recent years, more specific researches have been carried out that present novel materials for rehabilitation beside proposing methods and performing techniques. In the current study, a novel technique for developing the bending capacity of reinforced concrete beams to enhance their performance as well as rehabilitating and reforming the performance of reinforced concrete beams with nonstandard lap splices, has been proposed. In this method, a post-tensioned concrete layer is added to the side face of the concrete beams built in 1:1 scale. Results reveals that addition of the post-tensioned layer enhances the beams' performance and covers their weaknesses. In this method, 18 reinforced concrete beams were prepared for the bending test which were subjected to the four-point pushover test after they were reinforced. The testing process ended when the samples reached complete failure status. Results show that the performance and flexural capacity of reinforced beams without lap splice is improved 22.7% compared to the samples without the post-tensioned layer, while it is enhanced up to at least 80% compared to the reinforced beams with nonstandard lap splice. Furthermore, the location of plastic hinges formation was transformed from the beam's mid-span to the 1/3 of span's end and the beam's cracking pattern was significantly improved.

Main Trends for Reforming the Law of Insurance Contract in England - Focused on the Insured's Post-Contract Duty of Good Faith in relation to Claims - (영국 보험계약법의 주요 개혁동향 - 보험금청구와 관련한 피보험자의 계약체결 후 선의의무를 중심으로 -)

  • Shin, Gun-Hoon
    • THE INTERNATIONAL COMMERCE & LAW REVIEW
    • /
    • v.53
    • /
    • pp.207-229
    • /
    • 2012
  • In IP 7 and LCCP 201, Law Commission considers the insured's duty of good faith after the formation of the contract. This article intends to review and analyse the legal implications of proposals in IP 7 and LCCP 201. The results of analysis are following. First, Law Commission propose to end the remedy of avoidance under MIA 1906 section 17, because avoidance of past claims is unprincipled, impractical and unnecessarily harsh. Secondly, LC proposes that an insured who makes a fraudulent claim should forfeit the whole claim which the fraud relates, but that the fraud should not invalidate previous and legitimate claims. Thirdly, LC proposes to introduce a statutory right for the insurer to claim damages for the reasonable, foreseeable costs of investigate a fraudulent claim in specific circumstances and that damages would be limited to those cases where the insurer can show an actual, net loss. Finally, LC provisionally propose that an express fraud clause should be upheld in business insurance, whereas in consumer insurance, any term which purports to give the insurer greater rights in relation to fraudulent claims that those set out in statute would be of no effect.

  • PDF