• Journal of Environmental Impact Assessment
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• v.21 no.3
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• pp.409-415
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• 2012

Post-kyoto regime has been discussing with the GHG reduction commitment. GHG energy target management system also has been applied for the domestic measures in the country. Universities are major emission sources for GHG. It is very important for campus to built the GHG inventory system and estimate the potential GHG emission reduction. In general, GHG inventory on the campus was taken by the IPCC guidance with the classification of scope 1, 2, and 3. Electricity was the highest portion of GHG emission on the campus as 5,053.90 $tonsCO_2eq/yr$ in 2009. Manufacturing sector was the second high emission and meant GHG in laboratory. Potential GHG reduction was planned by several assumptions such as installation of occupancy sensor, exchanging LED lamp and photovoltaic power generation. These reduction scenarios was simulated by LEAP model. In 2020, outlook of GHG emission was estimated by 17,435.98 tons of $CO_2$ without any plans of reduction. If the reduction scenarios was applied in 2020, GHG emission would be 16,507.60 tons of $CO_2$ as 5.3% potential reduction.

• Biotechnology and Bioprocess Engineering:BBE
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• v.10 no.1
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• pp.47-51
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• 2005

The bioelectrochemical reduction of nitrate in the presence of various mediators including methyl viologen and azure A was studied using a 3-electrode voltammetric system. The catalytic potential for the reduction of the mediators was observed in the reactor, which for methyl viologen and azure A were -0.74 V and -0.32 V, respectively, with respect to the potential of Ag/AgCl reference electrode. This potential was then applied to a working electrode to reduce each mediator for enzymatic nitrate reduction. Nitrite, the product of the reaction, was measured to observe the enzymatic nitrate reduction in the reaction media. Methyl viologen was observed as the most efficient mediator among those tested, while azure A showed the highest electron efficiency at the intrinsic reduction potential when the mediated enzyme reactions were carried out with the freely solubilized mediator. The electron transfer of azure A with respect to time was due to the adhesion of azure A to the hydrophilic surface during the reduction. In addition, the use of the adsorbed mediator on conductive activated carbon was proposed to inhibit the change in the electron transfer rate during the reaction by maintaining a constant mediator concentration and active surface area of the electrode. Azure A showed better than nitrite formation than methyl viologen when used with activated carbon.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3835-3839
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• 2013

A new synthesis route for Pt nanoparticles by direct electrochemical reduction of a solid-state Pt ion precursor ($K_2PtCl_6$) is demonstrated. Solid $K_2PtCl_6$-supported polyethyleneimine (PEI) coatings on the surface of glassy carbon electrode were prepared by simple mixing of solid $K_2PtCl_6$ into a 1.0% PEI solution. The potential cycling or a constant potential in a PBS (pH 7.4) medium were applied to reduce the solid $K_2PtCl_6$ precursor. The reduction of Pt(IV) began at around -0.2 V and the reduction potential was ca. -0.4 V. A steady state current was achieved after 10 potential cycling scans, indicating that continuous formation of Pt nanoparticles by electrochemical reduction occurred for up to 10 cycles. After applying the reduction potential of -0.6 V for 300 s, Pt nanoparticles with diameters ranging from $0.02-0.5{\mu}m$ were observed, with an even distribution over the entire glassy carbon electrode surface. Characteristics of the Pt nanoparticles, including their performance in electrochemical reduction of $H_2O_2$ are examined. A distinct reduction peak observed at about -0.20 V was due to the electrocatalytic reduction of $H_2O_2$ by Pt nanoparticles. From the calibration plot, the linear range for $H_2O_2$ detection was 0.1-2.0 mM and the detection limit for $H_2O_2$ was found to be 0.05 mM.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.24 no.9
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• pp.136-141
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• 2010

In this paper, after the third electrode type oxidant generator which could format non-uniform electric field in water had been manufactured and installed, by direct electrolysis, the effects of the hydrogen potential and oxidation reduction potential characteristics attendant upon electric field change on a higher concentration oxidant generation characteristics were investigated. Consequently, as the third electrode was installed in the middle of two slit electrodes and the polarity of applied power was changed, it was observed that the third electrode system with the positive electrode can generate a higher concentration oxidant, hydrogen potential and oxidation reduction potential as compared with that of the negative electrode. It is because the positive electrode was bombarded mostly energetic electrons and the negative electrode was bombarded mainly by less energetic positive ions.

• Bulletin of the Korean Chemical Society
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• v.20 no.11
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• pp.1303-1308
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• 1999

Conducting poly(3,4-ethylenedioxythiophene) (PEDT) films with metalloporphyrins incorporated as the counter ions were prepared by electropolymerization of the monomer in the presence of metal-tetra(sulfonatophenyl) porphyrin anions. Cathodic reduction of oxygen on the resulting conducting polymer films was studied. The overpotential for O2 reduction on electrodes with cobalt-porphyrin complex was significantly smaller in acidic solutions than on gold. In basic solutions, the overpotential at low current densities was close to those on platinum and gold. Polymer electrode with Co-complex yielded higher limiting currents than with Fe-complex, although the Co-complex polymer electrode was a poorer electrocatalyst for O2 reduction in the activation range of potential than the Fe counterpart. From the rotating ring-disk electrode experiments, oxygen reduction was shown to proceed through either a 4-electron pathway or a 2-electron pathway. In contrast to the polypyr-role-based electrodes, the PEDT-based metalloporphyrin electrodes were stable with wider potential windows, including the oxygen reduction potential. Their electrocatalytic properties were maintained at temperatures up to 80℃ in KOH solutions.

• Journal of Institute of Convergence Technology
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• v.4 no.1
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• pp.15-20
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• 2014

Recently, the development of renewable energy sources in Korea has been needed due to climate change. One of powerful alternative energy resources to mitigate emission is to switch conventional fuels to renewable energy, such as bioenergy. In this study, current status of bioenergy conversion technology and its supply in Korea was investigate. Based on theoretical, technical and realizable potential of biomass in Korea, the amount of reduction of green house gases was estimated. The results shown that the contribution of biomass on 2020 reduction target of green house gases emission in power generation was $513,000\;tCO_2/yr$ and utilization ratio of technical potential of biomass was 6.4%. For the effective supply of bioenergy in Korea, more exact estimation of realizable potential of biomass in Korea and stable supply sources are needed.

• Advances in environmental research
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• v.1 no.1
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• pp.37-55
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• 2012

Here we show that perchlorate reduction during pitting corrosion of zero-valent titanium (ZVT) is likely caused by dissolved titanium species, especially Ti(II). Several possible mechanisms were suggested based on the literature and were evaluated based on experimental observations. Direct reduction of perchlorate on the bare metal of the ZVT electrode was thermodynamically infeasible due to the high anodic potential that was applied. Other potential mechanisms were considered such as reduction by small ZVT metal particles released from the electrode and direct reduction on the oxide layer of the electrode where potential was sufficiently reduced by a high ohmic potential drop. However, these mechanisms were not supported by experimental results. The most likely mechanism for perchlorate reduction was that during pitting corrosion, in which ZVT is partially oxidized to form dissolved ions such as Ti(II), which diffuse from the electrode surface and react with perchlorate in solution. This mechanism is supported by measurements of the dissolution valence and the molar ratio of ZVT consumed to perchlorate reduced (${\Delta}Ti(0)/{\Delta}ClO_4{^-}$). The results shown in this study demonstrate that ZVT undergoing pitting corrosion has the capability to chemically reduce perchlorate by producing dissolved Ti(II) and therefore, it has the potential to be applied in treatment systems. On the other hand, the results of this research imply that the application of ZVT undergoing pitting corrosion in treatment systems may not be feasible now due to several factors, including material and electricity costs and possible chloride oxidation.

• Journal of Forest and Environmental Science
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• v.34 no.6
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• pp.461-471
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• 2018

In this study, the deforestation and forest degradation areas have been obtained in Myanmar using a land cover lamp (LCM) and a tree cover map (TCM) to get the $CO_2$ potential reduction and the strength of occurrence was evaluated by using the geostatistical technique. By applying a multiple criteria decision-making method to the regions having high strength of occurrence for the $CO_2$ potential reduction for the deforestation and forest degradation areas, the priority was selected for candidate lands for REDD+ project. The areas of deforestation and forest degradation were 609,690ha and 43,515ha each from 2010 to 2015. By township, Mong Kung had the highest among the area of deforestation with 3,069ha while Thlangtlang had the highest in the area of forest degradation with 9,213 ha. The number of $CO_2$ potential reduction hotspot areas among the deforestation areas was 15, taking up the $CO_2$ potential reduction of 192,000 ton in average, which is 6 times higher than that of all target areas. Especially, the township of Hsipaw inside the Shan region had a $CO_2$ potential reduction of about 772,000 tons, the largest reduction potential among the hotpot areas. There were many $CO_2$ potential reduction hot spot areas among the forest degradation area in the eastern part of the target region and has the $CO_2$ potential reduction of 1,164,000 tons, which was 27 times higher than that of the total area. AHP importance analysis showed that the topographic characteristic was 0.41 (0.40 for height from surface, 0.29 for the slope and 0.31 for the distance from water area) while the geographical characteristic was 0.59 (0.56 for the distance from road, 0.56 for the distance from settlement area and 0.19 for the distance from Capital). Yawunghwe, Kalaw, and Hsi Hseng were selected as the preferred locations for the REDD+ candidate region for the deforestation area while Einme, Tiddim, and Falam were selected as the preferred locations for the forest degradation area.

• Resources Recycling
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• v.32 no.2
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• pp.43-51
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• 2023

In this research, through LCA analysis, the environmental impact of automotive engine manufacturing and re-manufacturing was analyzed from the perspective of the entire process, and the greenhouse gas reduction effect was calculated based on this. The amount of greenhouse gas emitted from the process of acquiring and manufacturing raw materials for automotive engines is about 3,473 kg for new manufacturing and 872 kg for re-manufacturing. Thus, the amount of greenhouse gas reduction by engaging in re-manufacturing is about 2,601 kg; the analysis shows a reduction effect in each part of the entire process except for the processing stage. As a result of the LCA weighted analysis, the environmental impact of new product manufacturing was found to be 1.07E+03 Eco-point, and it was 2.67E+02 Eco-point for re-manufacturing. The share of GWP(Global Warming Potential) among the six major impact categories(Abiotic Depletion Potential, Acidification Potential, Eutrophication Potential, Global Warming Potential, Ozone-layer Depletion Potential, Photochemical Oxidant Creation Potential) as high at 99.72%(new manufacturing) and 99.68%(re-manufacturing).

• 제어로봇시스템학회:학술대회논문집
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• 2005.06a
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• pp.1054-1059
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• 2005

The artificial potential method uses a potential field to guide a robot from a start to a goal configuration respectively. The potential field consists of attractive potential used to pull a robot toward a goal and repulsive potential to keep it away from obstacles. However, there are two problems concerning local minimum and computational cost to be resolved in conventional artificial potential methods. This study proposes a method utilizing a spline surface that interpolates arbitrary boundaries and a domain reduction method that reduces the unnecessary area. The proposed spline surface interpolates arbitrary shaped boundaries and is used as an artificial potential to guide a robot for global motion planning of a mobile robot. A reduced domain process reduces the unnecessary domain. We apply a distance-weighted function as such a function, which blends distances from each boundary with a reduction in computational time compared with other analytical methods. As a result, this paper shows that an arbitrary boundary spline surface provides global planning and a domain reduction method reduces local minimum with quick operation.