• 대한기계학회논문집
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• 제19권12호
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• pp.3372-3381
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• 1995

An equilibrium analysis was carried out to determine principal species of heavy metals in waste incineration and their behaviors with variation of temperature, chlorine concentration, excess air ratio, and C/H ratio. The waste was assumed as a compound of hydrocarbon fuel, chlorine, and metals. Calculated results showed that the most important parameter to determine the principal species was temperature. Chlorine concentration also affected on mole fractions of the principal species. Generally principal species at high temperature were chlorides while there were some metals of which principal species were oxides. At low temperature mole fractions of the principal species increased, but at high temperature mole fractions of some metal species decreased. C/H ratio of the hydrocarbon fuel and excess air ratio had little effect on mole fractions of the metal species, compared to the temperature and chlorine concentration.

• 한국연소학회지
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• 제1권1호
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• pp.31-39
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• 1996

An equilibrium analysis was carried out to determine principal species in the incineration of hazardous waste, which was assumed as a compound of hydrocarbon fuel, chlorine, sulfur, and heavy metals, and their behaviors with variation of temperature, chlorine and sulfur concentrations. Calculated results showed that the most important parameter influencing the principal species was temperature. Chlorine concentration affected on mole fractions of the species, especially at high temperature. Existence of sulfur had a significant effect on the species at low temperature, regardless of surfur concentration. Generally, principal species at high temperature were chlorides and oxides, while the principal species at low temperature were sulfides. As temperature increased, mole fractions of the principal species increased at low temperature, however, mole fractions of some metal species decreased at high temperature.

• 대한토목학회논문집
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• 제28권4D호
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• pp.569-577
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• 2008

본 연구의 목적은 위성영상으로부터 보다 정확한 토지정보를 취득하기 위해 다중시기데이터의 혼합과 특정 영상강조기법 및 영상분류알고리즘을 병합하여 적용하는 응용분류체계의 개발이다. 즉, 본 연구에서는 혼합된 다중시기데이터를 주성분분석한 후 정준상관분류기법을 적용하는 분류과정을 제안한다. 이 분류과정의 결과를 단일영상별 정준상관분류결과, 다중시기혼합영상의 정준상관분류결과, 시기별 주성분분석 후 정준상관분류결과와 비교한다. 사용된 위성영상은 1994년 7월 26일과 1996년 9월 1일에 취득된 Landsat 5 TM 영상이다. 정확도평가를 위한 지상실제데이터는 지형도 및 항공사진으로부터 취득되었으며, 연구대상영역 전체가 정확도평가 대상으로 사용되었다. 제안된 응용분류체계는 단일영상만을 사용하여 정준상관분류를 수행한 경우보다 분류정확도면에서 약 8.2% 상승되는 우수한 효과를 보여주었다. 특히, 복잡한 토지특성이 혼합되어 있는 도시역을 정확히 분류하는데 유효하였다. 결론적으로 Landsat TM 영상을 사용한 토지피복정보 추출시 분류정확도를 높이기 위해서, 다중시기영상을 사전에 주성분분석 후 정준상관분류기법을 적용하면 매우 효과적임을 확인하였다.

• 한국운동역학회지
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• 제34권1호
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• pp.34-44
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• 2024

Objective: This study aimed to investigate how the movements occurring during the follow-through phase after releasing an arrow among elite compound archers, are associated with the arrow impact points on the target. Method: Nine elite archers performed consecutive compound archery shooting under conditions identical to actual competitions using their own bows and equipment. Motion capture system and force platform were utilized to record the changes in joint positions and center of pressure, respectively. Principal component analysis was employed to identify the patterns in which multidimensional joint positions and COP changes were organized with horizontal and vertical coordinates of arrow impact points. Subsequently, correlation analysis quantified the relationship between individual variables and the coordinates of arrow impacts on the target. Results: We found a common organizational pattern in which the two axes of the impact point coordinates were grouped into the first two principal components. The movements of the upper and lower limbs following release exhibited opposite patterns in the anterior-posterior axis, with significant correlations observed between the arrow impact points of the horizontal axis and the left shoulder, right elbow, left hip, and both knees. Additionally, the lateral movements induced by the reaction force upon arrow release showed significant associations with the vertical coordinates of the impact points. Particularly, the correlations between the movements of the left shoulder and elbow, as well as the bilateral hip and right knee, were consistently observed among all participants. Conclusion: These findings implied that the post-release movements could significantly influence the trajectory and impact points of the arrows in compound archery. We suggest that a consistent and controlled movement during the follow-through phase may be more beneficial for optimizing shooting accuracy and precision rather than minimizing movements.

• Journal of Applied Biological Chemistry
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• 제63권1호
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• pp.23-28
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• 2020

In this study, the marker compound contents of both the taproot and lateral root of Danshen (Salvia miltiorrhiza Radix), which is cultivated in Korea, were investigated. The salvianolic acid B content was the highest in the taproot (5.17-6.75%) and lateral root (3.99-5.69%). The cryptotanshinone, tanshinone I, and tanshinone IIA contents were higher in the lateral root than in the taproot of Danshen (p <0.05). Principal component analysis results revealed that the taproot was correlated to the salvianic acid A, rosmarinic acid, salvianolic acid B, and salvianolic acid A contents, whereas the lateral root was correlated to the cryptotanshinone, tanshinone I, and tanshinone IIA contents. The total phenolic content and total flavonoid content of the taproot were higher than those of the lateral root (p <0.05); however, the antioxidant activities of the taproot and lateral root of Danshen were similar. The salvianolic acid B content was correlated to the TPC of the taproot (r=0.748) and the 2,2-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid radical scavenging activity of the lateral root (r=0.847). This study could provide useful information for the classification of Danshen as a herbal medicinal product.

• 한국연초학회지
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• 제35권1호
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• pp.20-27
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• 2013

An Electronic Nose(E-Nose) and Gas Chromatography/Mass Spectroscopy (GC/MS) are meanwhile conventional technique to analyze volatile materials in many industries (e.g., food, medicine, environment) and have broad acceptance in the analysis of tobacco products. In this study, an experiment where tin oxide gas sensor array responses and GC/MS profiles are used to characterize the volatile compounds of different cigarettes at the same time is performed and the measurements of two instruments are compared for cigarette samples with a known chemical information. E-Nose and GC/MS were employed to differentiate and match flavored cigarettes with commercial tobacco flavoring agents (lavender, vanilla, peppermint, orange, star anise). For verifying reliability of two systems, the analyses were conducted in terms of amount of flavors in each cigarettes using partial least squares (PLS) and with the principal components analysis (PCA). Various chemical sensors and GC/MS data was reduced into two principal factors (PC1, PC2) for being distinguished with visualized regions. Both systems provided adequate results for odor characteristics of cigarettes in this study with each instrument having its own advantages and disadvantages.

• 보존과학회지
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• 제37권6호
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• pp.738-747
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• 2021

제철원료별 직접제련법 복원실험으로 생산된 단조박편의 재료과학적 분석을 통해 금속학적 특성을 규명하였다. 제련을 위해 경주감포사철과 양양철광석을 이용하며, 각각 4개의 그룹을 설정하였다. 분석은 주성분, 광물 동정, 미세조직 관찰을 하였다. 주성분 분석 결과 정련·단접이 진행될수록 Fe의 함량은 증가하고 비금속개재물의 함량은 감소하였다. 광물을 동정한 결과 산화철 계열의 광물이 확인되었다. 미세조직 관찰 결과 Wüstite, Fayalite가 관찰되었으며, 일부에는 응집된 Wüstite가 관찰되었다. 일부 다각형, 장주상의 Magnetite도 확인되었다. 또한, 공극 및 불순물, 비금속개재물은 점차 감소하였다. 차후 다양한 제철원료를 이용한 복원실험을 통해 생산된 단조박편의 재료과학적 분석을 통해 금속학적 특성을 규명하고, 이를 유적에서 출토된 단조박편과 비교·검토하는 것이 필요하다.

• 대한본초학회지
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• 제28권5호
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• pp.95-101
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• 2013

Objectives : A quantitative method using high performance liquid chromatography with a photodiode array detector(HPLC-PDA) was established for the quantitative analysis of the four main compound and pattern analysis to classification Piiellia ternate, P. pedatisecta and Typhonium flagelliforme. Methods : The analytical procedure for the determination of P. ternata, together with the known main compounds uracil, uridine, guanosine and adenosine was established. Optimum HPLC-PDA separation of these P. ternata was possible on Luna C18(2) column material, using water and acetonitrile as mobile phase. The method was validated according to regulatory guidelines. In addition, this assay method were analyzed for the content of four main compound in P. ternata, P. pedatisecta and T. flagelliforme and by data obtained from the HPLC-PDA analysis was performed principal component analysis(PCA). Results : Validation results indicated that the HPLC method is well suited for the determination of the roots of P. ternata with a good linearity ($r^2$ > 0.999), precision and recovery rates. Analysis of HPLC-PDA, the average content of uracil, uridine, guanosine and adenosine was significantly higher in P. ternate>P. pedatisecta> T. flagelliforme order. The application of PCA to main compound data by HPLC-PDA permitted the effective discrimination among the three species. Conclusions : Analysis of both HPLC-PDA and PCA confirmed the fact that four main compound and pattern profiles of P. ternata, P. pedatisecta and T. flagelliforme were different from each other.

• Mass Spectrometry Letters
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• 제13권4호
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• pp.125-132
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• 2022

There are many types of spring blossoms on the Daedeok campus of Chungnam National University (CNU) at the area of 1,600,000 square meters. As an assignment for the class of Analytical Chemistry I for second-year undergraduate students, 2021, flower petals collected from various floral groups (Korean azalea, Korean forsythia, Dilatata lilac, Lilytree, Lily magnolia, and Prunus yedoensis) were analyzed using headspace extraction coupled to gas chromatography-mass spectrometry (HS-GC-MS) to study the aromatic profiles and fragrance compounds of each sample group. Various types of compounds associated with the aroma profiles were detected, including saturated alcohols and aldehydes (ethanol, 1-hexanol, and nonanal), terpenes (limonene, pinene, and ocimene), and aromatic compounds (benzyl alcohol, benzaldehyde). The different contribution of these compounds for each floral type was visualized using statistical tools and classification models based on principal component analysis with high reliability (R² = 0.824, Q² = 0.616). These results showed that HS-GC-MS with statistical analysis is a powerful method to characterize the volatile aromatic profile of biological specimens.

• Journal of Ginseng Research
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• 제34권4호
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• pp.288-295
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• 2010

Ginsenosides are the principal components responsible for the pharmacological and biological activities of ginseng. Ginsenoside Rd was transformed into compound K using cell-free extracts of food microorganisms, with Lactobacillus pentosus DC101 isolated from kimchi (traditional Korean fermented food) used for this conversion. The optimum time for the conversion was about 72 h at a constant pH of 7.0 and an optimum temperature of about $30^{\circ}C$. The transformation products were identified by thin-layer chromatography and high-performance liquid chromatography, and their structures were assigned using nuclear magnetic resonance analysis. Generally, ginsenoside Rd was converted into ginsenoside F2 by 36 h post-reaction. Consequently, over 97% of ginsenoside Rd was decomposed and converted into compound K by 72 h post-reaction. The bioconversion pathway to produce compound K is as follows: ginsenoside Rd$\rightarrow$ginsenoside F2$\rightarrow$compound K.