• Biotechnology and Bioprocess Engineering:BBE
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• v.11 no.1
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• pp.61-66
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• 2006

The simple Langmuir isotherm is frequently employed to describe the equilibrium behavior of protein adsorption on a wide variety of adsorbents. The two adjustable parameters of the Langmuir isotherm - the saturation capacity, or $q_m$, and the dissociation constant, $K_d$ - are usually estimated by fitting the isotherm equation to the equilibrium data acquired from batch equilibration experiments. In this study, we have evaluated the possibility of estimating $q_m$ and $K_d$ for the adsorption of bovine serum albumin to a cation exchanger using batch kinetic data. A rate model predicated on the kinetic form of the Langmuir isotherm, with three adjustable parameters ($q_m,\;K_d$, and a rate constant), was fitted to a single kinetic profile. The value of $q_m$ determined as the result of this approach was quantitatively consistent with the $q_m$ value derived from the traditional batch equilibrium data. However, the $K_d$ value could not be retrieved from the kinetic profile, as the model fit proved insensitive to this parameter. Sensitivity analysis provided significant insight into the identifiability of the three model parameters.

• Proceedings of the IEEK Conference
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• 2006.06a
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• pp.291-292
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• 2006

This paper presents rate-distortion optimization that is considered sequence statistics(complexity) to choose the best macroblock mode decision in H.264. In previous work, Lagrange multiplier is derived by the function of constant value 0.85 and QP so that is not the proper Lagrange multilplier for any image sequence. The proposed algorithm solves the problem by changing constant value 0.85 into adaptive value which is influenced by image complexity, and by reducing the encoder complexity to estimate the image statistics with the multiplication of transformed, quantized rate and distortion. Proposed algorithm is achieved the bit-rate saving up to 5% better than previous method.

• Transactions of the Korean Society of Mechanical Engineers
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• v.9 no.5
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• pp.548-554
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• 1985

This research is to find a means of reducing diesel engine combustion noise with none or minimum sacrifice of engine performance by investigating the influence of Cylinder Pressure Level(CPL). For this purpose, modified Wiebe's combustion function, considering the heat release curve as a combustion of both premixed and diffusive combustion portion, was exclusively used to obtain the indicator diagram and computer coeds were developed for the numerical analysis. Following are the results of this research. (1) CPL increases almostly with lag of ignition timing increasing .alpha. and decreasing. theta.$_{d}$, but at the crank angle with the maximal efficiency, CPL is independent of .alpha. and .theta.$_{d}$ with constant value of 200 dB especially at the low frequency. (2) For the constant ignition timing, the effects of .alpha. and .theta.$_{d}$ on CPL were the most significant at the frequency of about 1KHz and 300Hz respectively. (3) For the constant value of .alpha. and .theta.$_{d}$, CPL increases linearly with load but thermal efficiency increase very rapidly with maximum value of load Q$_{T}$=30-40 MJ/Kmol, then starts to decrease slowly. (4) The most effective way of reducing combustion noise without sacrificing thermal efficiency, is to decrease .alpha.. In the case of constant .alpha., there always exists a optimum value of .theta.$_{d}$ with respect to the various compression ratio.o..atio.o..

• Journal of Korean Society on Water Environment
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• v.24 no.3
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• pp.311-316
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• 2008

This study aimed to obtain equilibrium concentration on adsorption removal of ammonia nitrogen by activated carbon, to express the adsorption characteristics following Freundlich isotherm and also, based on the value obtained, to investigate the relationship between physical characteristics of activated carbon and dynamics of ammonia nitrogen removal by obtaining rate constant and effective pore diffusivity. The results summarized from this study are as follows. It was noted that powdered activated carbon showed better adsorption ability than granular activated carbon. The value of constant (f) of Freundlich isotherm of powered activated carbon was $4.6{\times}10^{-8}$ which is bigger than that of granular activated carbon. The adsorption rate constant on ammonia nitrogen of powered activated carbon with high porosity and low effective diameter was highest as 0.416 hr-1 and the effective pore diffusivity ($D_e$) was lowest as $1.17{\times}10^{-6}cm^2/hr$, and the value of ammonia nitrogen adsorption rate constant of granular activated carbon was $0.149{\sim}0.195hr^{-1}$. It was revealed that, with the same amount of dosage, the adsorptive power of activated carbon with lower effective diameter and bigger porosity was better and its rate constant was also high. With a little adsorbent dosage of 2 g, there was no difference removal ability of ammonia nitrogen as change of adsorption properties.

• Journal of Korean Society on Water Environment
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• v.26 no.3
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• pp.491-496
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• 2010

This study aimed to obtain equilibrium concentration on adsorption removal of phosphorus by activated carbon, to express the adsorption characteristics following Freundlich isotherm and also, based on the value obtained, to investigate the relationship between physical properties of activated carbon and dynamics of phosphorus removal by obtaining rate constant and effective pore diffusivity. The results summarized from this study are as follows. Phosphorus adsorption equilibrium reaching time of powdered activated carbon was reduced as the dosage of activated carbon increases, while granular activated carbon despite increased dosage did not have influence on adsorption equilibrium reaching times of phosphorus as well, taking more than 10 hours. It was also noted that powdered activated carbon showed better adsorption ability than granular activated carbon. The value of constant (f) of Freundlich isotherm of powered activated carbon on phosphorus was 4.26 which is bigger than those of granular activated carbon. The adsorption rate constant on phosphorus of powered activated carbon with low effective diameter and iodine number was highest as $8.888hr^{-1}$ and the effective pore diffusivity ($D_e$) was lowest as $2.45{\times}10^{-5}cm^2/hr$, and the value of phosphorus adsorption rate constant of granular activated carbon was $0.174{\sim}0.372hr^{-1}$, It was revealed that, with the same amount of dosage, the adsorptive power of activated carbon with lower effective diameter was better and its rate constant was also high.

• Journal of the Korean GEO-environmental Society
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• v.15 no.5
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• pp.67-74
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• 2014

In this study, a constant rate of strain test (CRS) and oedometer test was performed in order to study the consolidation characteristics to the liquid limit using a re-shaped clay which was preconsolidated at a constant pressure. Consolidation samples were made of kaolinite which was mixed with bentonite of 6 %, 9 %, 12 % and 15 % of it by weight and the test value of liquid limit of samples were appeared in 77 %, 84 %, 88 % and 91 % respectively. And then consolidation samples which were agitated sufficiently adding distilled water 2 times of liquid limit were preconsolidated in the condition of a constant pressure of 0.2 MPa. The oedometer test which is commonly used recently and the consolidation test of constant rate of strain which were applied in 0.001 %/min, 0.004 %/min, 0.01 %/min rate of strain according to ASTM, D4186-82 were performed and the preconsolidation pressures were compared and analyzed at 0.2 MPa preconsolidated pressure. As a result, in the case of low value of liquid limit, preconsolidation pressure was appeared same as 0.2 MPa preconsolidated pressure at the high speed strain rate, and in the case of high value of liquid limit, preconsolidation pressure was appeared same as 0.2 MPa preconsolidated pressure at the low speed strain rate.

• 한국연소학회:학술대회논문집
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• 2003.12a
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• pp.115-123
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• 2003

Simultaneous measurements of velocity and OH distribution were made using particle image velocimetry(PIV) and planar laser-induced fluorescence(PLIF) of OH radical in turbulent hydrogen nonpremixed flames with coaxial air. The OH radical was used as an approximate indicator of chemical reaction zone. The OH layer was correlated well with the stoichiometric velocity, $U_s$, instantaneously and on average. In addition, high strain-rate regions almost coincide with the OH distribution. The residence time in flame surface, calculated from the root-mean-square value of the radial velocity, is proportional to $(x/d_F)^{0.7}$. It is found that the mean value of principal strain rate on the OH layer can be scaled with $(x/d_F)^{-0.7}$ and therefore, the product of the residence time and the mean strain rate remains constant over all axial positions.

• Bulletin of the Korean Chemical Society
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• v.8 no.2
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• pp.79-83
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• 1987

The reduction of a series of 1-substituted benzyl-3-cyanoquinolinium ions (p-$cH_3$, H, p-Br, m-F, p-CN) by sodium borohydride has been investigated. In all cases the products from these reactions were found to be 1, 2-dihydroquinolines over 82% yields. Rates of reduction were measured in basic condition and in solvent system consisting of 4 parts of isopropyl alcohol and 1 part of water by volume. Second order rate constants were obtained for these reactions. When the ratio of [$OH^-$] to [$BH_4^-$] becomes large the observed rate constants ($K_{obs}$) decrease by a small factor. Reaction scheme and rate law are discussed. Bronsted ${\alpha}(=\frac{d\;In\;k}{d\;In\;K})$ obtained by using the value of equilibrium constant K, which was obtained previously, was not 0. Instead, a value of 0.36 was obtained which indicated that the reduction by borohydride was structure-dependent according to the Marcus formalism even though the reaction rate was close to the diffusion limit.

• Journal of the Korean Chemical Society
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• v.54 no.2
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• pp.208-214
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• 2010

In the presence of alcohol, phospholipase D (PLD) is known to perform transphosphatidylation activity, during which the overall reaction rate of PLD increased. To elucidate the reaction mechanism of transphosphatidylation further, we investigated rate constants of transphosphatidylation reaction of the purified ${\alpha}$-type PLD from cabbage in the presence of various alcohols. The second-oder rate constants of PLD transphosphatidylation showed a large increase with the primary alcohols examined as expected. In the case of butanol we observed the second-oder rate constant of $33.33{\pm}1.33M^{-1}sec^{-1}$. This second-order rate constant of transphosphatidylation was as 400 times greater as the second-order hydrolysis rate constant of $0.078M^{-1}sec^{-1}$ which was adjusted for the water concentration. A linear free energy relationship between the $pK_a$ of alcohol and transphosphatidylation rate gives a Br${\o}$nsted slope of ${\beta}_{nu}$ = 0.12 ${\pm}$ 0.03. This small ${\beta}_{nu}$ value implicates that the transition state of break down of phosphatidyl-enzyme intermediate (E-P) is likely dissociative. Finally, a reaction mechanism of cabbage PLD is suggested on the basis of our results presented here and the histidine residue known to be located in the active site of cabbage PLD.

• Transactions of Materials Processing
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• v.20 no.7
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• pp.498-503
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• 2011

The strain rate sensitivity index, m, plays an important role in plastic deformation at elevated temperatures. It is affected by strain rate, temperature, and the microstructure of the material. The strain rate sensitivity index has been used as a constant in numerical analysis of plastic forming at a specified strain rate and temperature. However, the value of m varies as deformation proceeds at an elevated temperature and a certain strain rate. Thus, in this present study, the value of m has been characterized as a function of strain by multiple tensile jump tests for AZ31 magnesium alloy sheet, and the variation of m has been discussed in conjunction with the microstructural observations before and after deformation. The experimental results show that the variation of m is dependent on the temperature and strain rate. Grain growth with dynamic recrystallization also affects the variation of m.