• Journal of the Korean GEO-environmental Society
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• v.12 no.7
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• pp.31-37
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• 2011

Only a few studies have been conducted using reduced slag as recycled material. The reduced slag in electric furnace is produced as a by-product in making a steel and a few applications of the reduced slag as expensive additives and bonding materials or as the stabilized soils was reported. The purpose of this study is to present the feasibility of the reduced slag as recycled material, especially, in a field of civil engineering. In order to achieve the purpose experiments such as SEM and XRF analysis was conducted for the reduced slag in electric furnace. Based on the results various geotechnical experiments were conducted to know engineering properties of slag-soil mixtures. Weathered soils and clay are mixed with reduced slag for various ratios. As the ratio of reduced slag to weathered soil increases, the maximum dry unit weight of the mixture decreased with increasing optimum moisture content. The results indicates that there is no effect on a reduced slag by compaction efforts. The shear strengths of the weathered soil-slag mixtures are slightly higher or similar to those of weathered soils. The permeability of the weathered soil-slag mixtures is similar to that of silty or sandy soils. Therefore, it is possible to use the mixtures as embankment or backfill materials in the fields. The unconfined strength of the mixtures of reduced slag and clay is higher than that of clay and it tends to increase with the curing time. Therefore it can be used to improve the soft ground.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.542-546
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• 2001

Converter slag has some compositional similarities to portland cement. But it has no hydration properties due to it's quite high concentrations of FeO(20-35%), MnO(4-6.5%). So it is needed to reduce the concentrations of iron and manganese of converter slag to use as cement additives by enhancing it's hydration properties. In this study, converter slag was modified it's composition by mixing of silica, alumina and quenched BF slag and reduced in induction furnace and quenched in running water. The hydraulic properties and structures of modified and quenched converter slag are significantly changed depend on the amount and kinds of additives. The addition of alumina up to 10% and BFQ slag up to 20% by weight on converter slag was effective to enhance the hydraulic properties of modified and quenched slag. The addition of reduced and quenched converter slag up to 20% by weight in replacement of portland cement in mixing of concrete mortar were shown higher compressive strength than 100% cement concrete mortar.

• Journal of the Korean GEO-environmental Society
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• v.13 no.6
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• pp.33-39
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• 2012

With the increase of steel production research interest on the recycling of slag as a by-product also increases steadily. Currently in Korea a lot of researches on blast-furnace slag have been made. However, the researches on the steel slag have been rarely made. Also, a research of steel slag, especially the use of oxidation furnace slag as aggregates for concrete progress, is performing actively, but the research results on the furnace slag are almost nothing. Recently, the research about the furnace slag as backfill material and embankment material confirmed the possibility of the clay soil amendment. Therefore, the object of this study is to review the possibility as civil engineering materials for soil improvement and to find the optimum mixture ratio of furnace slag. This research analyzed the ingredient component of the reduced slag by SEM, XRF, XRD tests and examined the strength increase using unconfined compression tests when the clay and reduced slag are mixed each other. Through this test, the definite strength increase is confirmed according to the mixture of the reduced slag and the possibility of soil improvement is also confirmed based on this result. The object of the study is both utilizing the by-product for civil engineering purpose and effective recycling by the application of the furnace slag for soil improvement.

• Journal of the Korean Ceramic Society
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• v.18 no.3
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• pp.157-162
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• 1981

A converter slag has been heat-treated above melting point at reduced condition by cokes. As the result, most iron was separated. To make hydraulic compounds, calcium oxide was added to the reduced converter slag and the mixtures were sintered. This modified converter slag clinker mainly contained tricalcium silicate and calcium aluminates, and have a great potential to be a good hydraulic cement. The hydrates of the hydraulic compounds and gypsum with and without granulated slags, were mainly C-S-H, ettringite, calcium monosulfoaluminate hydrate, calcium aluminate hydrate, and $Ca(OH)_2$

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.61-62
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• 2023

In this study, the steel slag was immersed in CO₂ nano-bubble water by Electric arc funace it was accelerated aging was reviewed through XRD analysis. The main minerals of the electric furnace oxidized slag were spinel and gehlenite, and there was no change with the number of CO₂ nano-bubbles. Minerals such as larnite, calcio-olivine, agnetite, calcite, and spinel were distributed in electrically reduced slag, and the content of calcite more than doubled with CO₂ nano-bubble immersion. Therefore, it is judged that the acceleration aging of Electric arc funace reduced slag is effective according to the immersion of CO₂ nano-bubble.

• Journal of the Korean GEO-environmental Society
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• v.12 no.7
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• pp.23-29
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• 2011

The oxidation slag has been widely used in civil engineering project, whereas the reduced slag from electric furnace has yet to be applied. Consequently in order to find out the recycling method in civil engineering field, the mineral compositions of the reduced slag were analyzed and some tests on water quality were performed to estimate the potential release of toxic compounds. Slag-soil mixtures of 0, 10, 20 and 30%(dry weight) soil were prepared in lysimeter columns and the effluents were collected with the period of one, two and four week options in closed system, respectively. The result from qualitative and quantitative analysis using X-ray Diffraction(XRD) and X-ray Fluorescence(XRF) indicates that the main mineral of the reduced slag is $Ca_2(SiO_4)$, a kind of calcium silicate. Also, the leaching medium analyzed by Inductively Coupled Plasma Optical Emission Spectroscopy(ICP-OES) showed that main heavy metals such as Al, Fe and Mn are included in the reduced slag due to the effect of steel production process. It can be seen that the leachate does not violate the regulation guide line of waste material of heavy metal. Also the pH levels were increased from pH 6.9 for 0% soil to pH 10 for 30% soil. However the influence on leachate circulation period of one through four weeks was negligible.

• Resources Recycling
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• v.11 no.6
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• pp.24-30
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• 2002

Reduced and modified converter slag was ball milled and sieved to -200/+325 mesh. CaO,$SiO_2$, $Fe_2$$O_3$ was added to slag powder and mixed to make it similar to the composition of normal portlant cement. The pellet made of this powder was heated from $1250^{\circ}C$ to $1450^{\circ}C$ for 15 min～45 min. Most feasible condition for making slag cement clinker is the heating more than 20 min at $1450^{\circ}C$. The compressive strength of the mortar made of this slag cement clinker was better than that of normal port-lant cement in long time curing.

• Journal of the Korea Institute of Building Construction
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• v.17 no.3
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• pp.279-285
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• 2017

In this study, the development of concrete preventing initial frost damage and durability about that were evaluated by using anti-aging agent and admixture(reduced slag). As a result of experiment, initial hydration heat was increased by $C_{12}A_7$ of reduced slag components but it was not effective to development of strength. Also fluidity decreased with increasing replacement of reduced slag. This suggested that fluidity was low by rapid setting due to absent of gypsum in reduced slag components. In case of CR2G specimen that added 4% gypsum, the flow ability was higher than plain. It is considered that concrete developed using reduced slag should use $SO_3$. Result of durability experiments, the durability decreased with increasing replacement amount of reduced slag.

• Applied Chemistry for Engineering
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• v.23 no.4
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• pp.409-415
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• 2012

To recycle the steel slag as manufactured composite materials of polymer concretes, we used the atomizing method to make round aggregates from steel slag, which is treated as industrial wastes. A round rapid-cooled steel slag was used to replace fine aggregate (river sand) or coarse aggregate (crushed aggregate), depending on the grain size. To examine general physical properties of polymer concrete composites manufactured from rapid-cooled steel slag, the polymer concrete specimen with various proportions depending on the addition ratio of polymer binder and replacement ratio of rapid-cooled steel slag were manufactured. In the result of the tests, the mechanical strength of the specimen made by replacing the optimum amount of rapid-cooled steel slag increased notably (maximum compressive strength 117.1 MPa), and the use of polymer binder, which had the most impact on the production cost of polymer concrete composites, could be remarkably reduced. However, the mechanical strength of the specimen was markedly reduced in hot water resistance test of polymer concrete composite.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10c
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• pp.19-24
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• 1998

In this study, blended cement with low blaine(2000, 3000$\textrm{cm}^2$/g) blast-furnace slag power by 10-70wt.% was investigated through the measurement hydration heat, physical properties. The experiment results indicated compressive strength was decreased as low blaine slag blended, but hydration heat was reduced significantly and flow of the cement paste was increased.