• Title/Summary/Keyword: Residual ammonia

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Ammonia-nitrogen Removal in Sea Water by Using Electrolysis (전기분해법에 의한 해수내의 암모니아성 질소 제거)

  • 이병헌;이제근;길대수;곽순열
    • Journal of Aquaculture
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    • v.10 no.4
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    • pp.435-438
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    • 1997
  • Biological ammonia removal system have been used conventionally for the seawater fish farming. But this process requires long hydraulic retention times and large area. Also it has a trouble of NO3-N accumulation in the system. Therefore, this study was conducted to find out the feasibility of effective nitrogen removal efficiency in the sea water fish farming system by electolysis. As the result, electrolysis system showed a good ammonia and nitrate nitrogen removal and E. coli sterilization efficiencies. Because of the high salinities in the seawater for electron transfer, electrolysis is an effictive water treatment process for seawater fish farming. The relation among ammonia removal efficiency, hydraulic retention time (HRT) and electric wattage (watt) with 10 mm electrod distance isas follow ; log [$NH_4^$+-N(%)]=0.431log(HRT(sec)$\times$Watt)+0.88(r=0.950) And the relation between ammonia removal efficiency and residual chlorine concentration in the seawater is as follow; $$NH_4^+-N(%)=48\cdotlog[Residual\;chlorine(mg/\ell)+28(r=0.892)$$

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Effect of Changes in Condition of Ammonia Gas Addition on the Surface Layer Microstructure and Porosity during Austenitic Nitriding of Low Carbon Steels (저 탄소강의 오스테나이트 질화 시 암모니아 가스첨가 조건변화가 표면층 조직 및 기공변화에 미치는 영향)

  • Lee, Jewon;Roh, Y.S.;Sung, J.H.;Lim, S.G.
    • Journal of the Korean Society for Heat Treatment
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    • v.32 no.5
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    • pp.201-211
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    • 2019
  • Low carbon steel (S20C steel) and SPCC steel sheet have been austenitic nitrided at $700^{\circ}C$ in a closed pit type furnace by changing the flow rate of ammonia gas and heat treating time. When the flow rate of ammonia gas was low, the concentration of residual ammonia appeared low and the hardness value of transformed surface layer was high. The depth of the surface layer, however, was shallow. With increasing the concentration of residual ammonia by raising up the ammonia gas flow, both the depth of the surface layer and the pore depth increased, while the maximum hardness of the surface layer decreased. By introducing a large amount of ammonia gas in a short time, a deep surface layer with minimal pores on the outermost surface was obtained. In this experiment, while maintaining 10~12% of residual ammonia, the flow rate of inlet ammonia gas, 7 liter/min, was introduced at $700^{\circ}C$ for 1 hour. In this condition, the thickness of the surface layer without pores appeared about $60{\mu}m$ in S20C steel and $30{\mu}m$ in SPCC steel plate. Injecting additional methane gas (carburizing gas) to this condition played a deteriorating effect due to promoting the formation of vertical pores in the surface layer. For $1^{st}$ transformed surface layer for S20C steel, maintaining 10~12% residual ammonia condition via austenitic nitriding process resulted in ${\varepsilon}$ phase with relatively high nitrogen concentration (just below 4.23 wt.%N) among the mixed phases of ${\varepsilon}+{\gamma}$. The ${\varepsilon}$ phase was formed a specific orientation perpendicular to the surface. For $2^{nd}$ transformed layer for S20C steel, ${\gamma}$ phase was rather dominant (just above 2.63 wt.%N). For SPCC steel sheet, there appeared three phases, ${\gamma}$, ${\alpha}(M)$ and weak ${\varepsilon}$ phase. The nitrogen concentration would be approximately 2.6 wt.% in these phases condition.

Estimation of Residual Biomass, PHB, and Nutrient Concentrations by Supplied Amount of Ammonia Solution in Fermentation of Alcaligenes latus

  • Lee, Yong-Woo;Tsuneo Yamane
    • Journal of Microbiology and Biotechnology
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    • v.9 no.5
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    • pp.554-561
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    • 1999
  • A novel estimation method was investigated for determining the concentrations of residual biomass, poly-3-hydroxybutyrate (PHB), and main nutrients including carbon and nitrogen sources, phosphate, and mineral ions from the supplied amount of ammonia solution used for a pH-control solution and nitrogen source in a PHB fermentation. The estimation equations for a batch culture and a fed-batch culture were derived from the relationship between the growth rate of residual biomass and the feed rate of the pH-control solution, and then were applied to the batch culture and the fed-batch cultures of Alcaligenes latus. This method was successfully applied to estimate the concentrations of residual biomass, PHB, and nutrients.

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The Effects of Total Nitrogen and Residual Ammonia Contents of Compost on the Yield of Cultivated Mushroom, Agaricus Bisporus (퇴비(堆肥)의 전질소(全窒素)와 암모니아 함량(含量)이 양송이 수량(收量)에 미치는 영향(影響))

  • Shin, Gwan-Chul;Oh, Byoung-Youl;Kim, Dong-Soo
    • The Korean Journal of Mycology
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    • v.1 no.2
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    • pp.1-7
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    • 1973
  • Among the factors which affect the mushroom yield, this investigation was aimed to confim the relationship between nitrogen content of rice straw compost and crop yield, residual ammonia content and yield. In this investigation the nitrogen content in dry weight of compost ranged from 1.10 to 2.06% and the residual ammonia content between 0.01 and 0.8% at spawning according to the sources of organic or inorganic nitrogen and the formulas of compost materials. The results obtained are summarized as follows: 1. The relationship between nitrogen content of rice straw compost and mushroom yield was represented by the formula: y=13.95+0.048$(r=0.68^{**})$. 2. Nitrogen content and mushroom yield of compost supplemented with organic nitrogen sources were increased as compared with control or inorganic treatments. 3. The relationship between the residual ammonia content and mushroom yield is represented by the formula: $y=0.38086-0.011948+0.00012x^2(r=-0.75^{**})$. In order to obtain high cropping yield the residual ammonia content at spawning should be below 0.03% (expressed as nitrogen content). 4. Application of ammonium sulfate increased the nitrogen content of compost slightly, but the residual ammonia content was increased considerably and yield decreased. On the other hand, the residual ammonia content of urea treatment was low and increased mushroom yield remarkably.

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Failure of Ammonia Synthesis Converter Due to Hydrogen Attack and Its On-Stream Assessment Using ToFD Method

  • Albiruni, Farabirazy;Lee, Joon-Hyun
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.132-137
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    • 2008
  • A failure analysis of ammonia converter which suffered hydrogen attack in two years since its initial operating time was presented. It is constructed from 2.25 Cr.1 Mo steel. Analysis showed that the failure on closing seam weld joint was due to local improper post weld heat treatment (PWHT). Improper PWHT can introduce high residual stresses in thick-walled pressure vessel. High residual stress level in weld joint is very prone to hydrogen attack for any components which are operating in hydrogen gas environment. The repair procedures based on the principle to decrease the residual stress then proposed. The repair was controlled very carefully by applying several nondestructive tests in the each stage of repair. To assure the successful of the proposed repair, after one year since repair time, high temperature ultrasonic and TOFD methods were applied on-stream to this equipment in order to evaluate its post repair condition. The two methods showed good results on the repaired area.

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Vertical Diffusion of Ammonia Into Amorphous Ice Sturcture

  • Kim, Yeong-Sun;Mun, Ui-Seong;Gang, Heon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.280-280
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    • 2012
  • We examined ammonia diffusion on the surface of amorphous ice film through the measurement of decreasing residual quantity of $NH_3$ molecules compared to $H_2O$. The populations of $NH_3$ molecules on the surface of amorphous ice were monitored by using the techniques of temperature programmed reactive ion scattering (TPRIS) method. The ratio of intensity between ammonia and water was examined as a function of time at controlled temperature. When ammonia molecules were externally added onto an ice film at a temperature of 80 K, ammonia coverage with regard to ice was 0.12-0.16 ML. The intensity of ammonia molecules on the surface of ice decreased as time increased and the extent of decreased intensity of ammonia increased as controlled temperature increased. Moreover, energy barrier was estimated to be $51kJmol^{-1}$ on amorphous ice film. The results of the experiment indicate that ammonia molecules have a property of vertical diffusion into amorphous ice and the energy barrier of ammonia diffusion into bulk of ice is higher than that of hydrogen bonding.

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Reuse of Rice-Hull and Application Technology Development in Waste Water Treatment (왕겨의 재활용 및 하수처리 활용기술 개발)

  • Shin, Ho-Sang;Ahn, Hye-Sil;Jung, Dong-Gyun
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2003.10a
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    • pp.170-173
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    • 2003
  • Activated Rice-Hull carbon was developed to remove ammonia compounds in water matrix. Isotherm adsorption tests of ammonia were conducted using a bottle-point technique and column test. Residual ammonia after Jar-Test or passing through the column was determined by Indophenol method, and assessed the removal efficiency for ammonia of the adsorbent. As a result, the adsorption capacity for ammonia of activated racehull carbon was very larger than that of coconut shell carbon, because the rice hull carbon had the higher BET surface area of silicate. The activated racehull carbon is under the development as adsorbent to remove ammonia in drinking water and waste water.

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Enhancement of L-Threonine Production by Controlling Sequential Carbon-Nitrogen Ratios during Fermentation

  • Lee, Hyeok-Won;Lee, Hee-Suk;Kim, Chun-Suk;Lee, Jin-Gyeom;Kim, Won-Kyo;Lee, Eun-Gyo;Lee, Hong-Weon
    • Journal of Microbiology and Biotechnology
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    • v.28 no.2
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    • pp.293-297
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    • 2018
  • Controlling the residual glucose concentration is important for improving productivity in $\text\tiny{L}$-threonine fermentation. In this study, we developed a procedure to automatically control the feeding quantity of glucose solution as a function of ammonia-water consumption rate. The feeding ratio ($R_{C/N}$) of glucose and ammonia water was predetermined via a stoichiometric approach, on the basis of glucose-ammonia water consumption rates. In a 5-L fermenter, 102 g/l $\text\tiny{L}$-threonine was obtained using our glucose-ammonia water combined feeding strategy, which was then successfully applied in a 500-L fermenter (89 g/l). Therefore, we conclude that an automatic combination feeding strategy is suitable for improving $\text\tiny{L}$-threonine production.

The Study on the Removal of Odor Emitting Environmental Fundamental Facility (환경기초시설에서 발생하는 악취가스 제거에 관한 연구)

  • Lee, Byung-Kwan;Lee, Sang-Hun;Tak, Sung-Je;Lee, Byung-Ki
    • Journal of Climate Change Research
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    • v.8 no.1
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    • pp.51-56
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    • 2017
  • The objective of the research project is to develop the hybrid deodorizer for the removal of residual harmful gases generating during pretreatment process of biogas. This hybrid deodorizer is capable of treating harmful gases that contains hydrogen sulfide ($H_2S$), ammonia ($NH_3$) and other odor substances. This hybrid deodorizer reduced the hydrogen sulfide content from approximately 150~200 ppm to less than 16 ppm. These residual harmful gases were effectively removed in the effluent, achieving up to 97% removal of $H_2S$ and 94% removal of $NH_3$ after treatment using hybrid deodorizer.

Effect of Operating Condition of Stripping Process on Ammonia Removal for Pre-treatment of Swine Wastewater (축산폐수 전처리를 위한 암모니아 탈기공정의 운전조건이 암모니아 제거에 미치는 영향)

  • Whang, Gye-Dae;Cho, Young-Moo
    • Journal of Korean Society on Water Environment
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    • v.20 no.1
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    • pp.86-92
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    • 2004
  • Lab-scale experiments have been carried out to investigate ammonia stripping with a modified spray tower for removing ammonia nitrogen from swine wastewater. The operating conditions such as initial pH, temperature, air flow, hole size of distributor determining the diameter of water drops, and influent solids concentration were closely examined focusing on removal efficiency of ammonia. As a result of the experiment, in order to achieve high rate of ammonia removal by the air stripping system, the air flow rate must be supplied at high rate with sufficiently high initial pH, temperature. The optimum operating condition to meet the residual ammonia concentration of 300 mg/L was the initial pH of 11.0 at $35^{\circ}C$ with the air flow rate of 20 L/min. It also showed that the smaller hole size is, the higher removal rate of ammonia is expected. However, when used a small sized distributor (2 mm), the flooding problem at the upper column occurred due to clogging of the hole. With regard to the influent solids concentration, it was showed that the lower concentration of solids, the higher removal rate of ammonia. The removal of particulate materials in influent led to improve the removal efficiency of ammonia, rather than to control the operating condition including initial pH, temperature, and air flow. The empirical correlation between KLa and operating parameters would be driven as, $K_{La}=(0.0003T-0.0047){\cdot}G^{0.3926}{\cdot}L^{-0.5169}{\cdot}C^{-0. 1849}$. The calculated $K_{La}$ from proposed formula can be used effectively to estimate the optimum reaction time and to calculate the volume of modified spray tower system.